Sanyo Electric Co., Ltd.

Toyoki Fujihara

Toshiyuki Nohma

Keisuke Minami

Naoya Nakanishi

Shingo Tode

Hiroyuki Fujimoto

Hideki Kitao

Yasuhiro Yamauchi

Masao Inoue

Maruo Kamino

Shigeki Matsuta

Tetsuya Okado

Masashi Muraoka

Masahiro Iyori

Tomoharu Arai

Takashi Okamoto

Yukari Kuratomi

Yohei Tao

Kazuhisa Takeda

Shin Fujitani

Naoki Ogawa

Tetsuya Matsuda

Yoshinori Kida

Yasuyuki Kusumoto

Daisuke Ikeda

Ikuro Nakane

Takaaki Ikemachi

Akira Kinoshita

Seiji Omura

Atsushi Yanai

Yasufumi Takahashi

Masahide Miyake

Shinichirou Yoshida

Yuu Takanashi

Takeshi Yoshida

Hirofusa Tanaka

Hiroko Sanda

Ken Kaneko

Shinichi Yamami

Toshiyuki Nouma

Naoki Terada

Mio Nosaka

Provided is a non-aqueous electrolyte secondary battery having excellent properties even at low temperatures. The non-aqueous electrolyte secondary battery comprises: an electrode assembly including a positive electrode plate and a negative electrode plate; a non-aqueous electrolyte; an exterior body having an opening, and accommodating the electrode assembly and the non-aqueous electrolyte; and a sealing plate for sealing the opening of the exterior body, wherein the negative electrode plate has a negative electrode core and a negative electrode active material layer formed on the negative electrode core, and the non-aqueous electrolyte contains a non-aqueous solvent, the non-aqueous solvent containing 50-80 vol % of a chain carbonate with respect to the non-aqueous solvent, and containing, as the chain carbonate, 30-40 vol % of dimethyl carbonate, 3-8 vol % of propylene carbonate, and 2-5 vol % of methyl propionate with respect to the non-aqueous solvent.

Non-aqueous electrolyte secondary battery

A non-aqueous electrolyte secondary battery including a positive electrode core; a positive electrode plate having a positive electrode active material layer formed on the positive electrode core; a negative electrode plate; a flat wound electrode assembly in which the positive electrode plate and the negative electrode plate are wound with a separator therebetween; and a non-aqueous electrolyte, wherein the positive electrode active material is a manganese-containing lithium transition metal composite oxide, the BET specific surface area of the positive electrode active material is 2.0-3.0 m/g, the total surface area of the positive electrode active material contained in the positive electrode active material layer is 70-90 m, and the value of A/B is 0.03-0.09 (μmol/m), where A (μmol) is the total amount of FSOcontained in the non-aqueous electrolyte, and B (m) is the total area of the positive electrode active material contained in the positive electrode active material layer.

Non-aqueous electrolyte secondary battery and method for manufacturing same

A method for manufacturing a nonaqueous electrolyte secondary battery which includes an electrode assembly, a housing with an opening and contains the electrode assembly, and a sealing member sealing the opening, the electrode assembly comprising a positive electrode and a negative electrode. The positive electrode includes a positive electrode active material, lithium carbonate, and lithium phosphate, the negative electrode comprising a negative electrode active material. The method includes placing the electrode assembly in the housing, and placing a nonaqueous electrolyte containing lithium fluorosulfonate in the housing.

Nonaqueous electrolyte secondary battery and method for manufacturing the same

A nonaqueous electrolyte secondary battery includes an electrode assembly including a negative plate and a positive plate including a positive electrode active material mix layer, a nonaqueous electrolyte, a battery case that houses the electrode assembly and the nonaqueous electrolyte, and a pressure-sensitive safety system that operates when the pressure in the battery case reaches a value greater than or equal to a predetermined value. The positive electrode active material mix layer contains lithium carbonate and lithium phosphate. The average particle size of lithium carbonate contained in the positive electrode active material mix layer is greater than the average particle size of lithium phosphate contained in the positive electrode active material mix layer. The number of particles of lithium carbonate contained in the positive electrode active material mix layer is less than the number of particles of lithium phosphate contained in the positive electrode active material mix layer.

Nonaqueous electrolyte secondary battery

A battery pack includes a plurality of prismatic secondary batteries with spacers each interposed therebetween. The prismatic secondary batteries each include a flat wound electrode body that is formed by winding a positive electrode plate and a negative electrode plate with a separator interposed therebetween; a prismatic outer body that houses the wound electrode body; and a sealing plate that seals an opening of the flat wound electrode body. The wound electrode body has a wound positive electrode core-exposed portion at one end portion and a wound negative electrode core-exposed portion at the other end portion. A positive electrode current collector is joined to the positive electrode core-exposed portion to form a positive electrode-joined portion, and a negative electrode current collector is joined to the negative electrode core-exposed portion to form a negative electrode-joined portion.

Battery pack

A nonaqueous electrolyte secondary battery including a positive electrode collector electrically connected to a positive electrode plate, a negative electrode collector electrically connected to a negative electrode plate. At least one of the collectors includes a first-side base portion disposed near the sealing plate, and a first-side lead portion connected to one end portion of the first-side base portion and extending towards an electrode body. The first-side lead portion includes a first-side power generating element joining portion joined to a lateral side of the electrode body, and a first-side inclined portion inclined with respect to a thickness direction of the electrode body from the first-side power generating element joining portion towards an outer side in the thickness direction. A total weight of the electrode body and nonaqueous electrolyte contained in the electrode body ranges from 200 g or more to 500 g or less.

A non-aqueous electrolyte secondary battery includes a pressure-sensitive current shut-off mechanism, wherein a positive electrode core body exposed portion is disposed at one end portion of a flat rolled electrode assembly, a negative electrode core body exposed portion is disposed at the other end portion, lithium carbonate is contained in a positive electrode mix layer, and a protective layer is disposed along the border with the positive electrode mix layer at the position opposite to a separator on the positive electrode core body exposed portion.

A nonaqueous electrolyte secondary battery includes a prismatic housing having an opening and a sealing member sealing the opening. The prismatic housing contains a flat-wound electrode assembly and a nonaqueous electrolyte. The flat-wound electrode assembly includes a positive electrode and a negative electrode. The positive electrode includes a positive electrode substrate and a positive electrode active material mixture layer formed on the positive electrode substrate. The positive electrode active material mixture layer contains lithium carbonate and lithium phosphate. The nonaqueous electrolyte contains lithium fluorosulfonate.

A prismatic secondary battery includes a first current collector and a second current collector. The first current collector includes a first base disposed along a sealing plate. The second current collector includes a second base disposed along the sealing plate. A distance between an end portion of a wound electrode body facing the sealing plate and a surface of the first base facing the wound electrode body at an end portion of the first base on a central side in the longitudinal direction of the sealing plate is shorter than a distance between the end portion of the wound electrode body facing the sealing plate and a surface of the second base facing the wound electrode body at an end portion of the second base on the central side. An insulating buffer is disposed between the wound electrode body and the above surface of the first base.

Prismatic secondary battery

A nonaqueous electrolyte secondary battery includes a pressure-sensitive current interrupt mechanism, and a flat wound electrode body that is inserted in an outer casing with a winding axis of the flat wound electrode body arranged to extend in a horizontal direction. A positive electrode plate, a negative electrode plate, and a separator in a winding end portion of the flat wound electrode body are all directed toward a top side.

Disclosed is a non-aqueous electrolyte secondary cell excellent in capacity retention rate and I-V characteristics after repeated cycles. The secondary cell contains a negative electrode active material containing scaly graphite particles and coated graphite particles. The coated graphite particles contain graphite particles and a coating layer coating the surfaces of the graphite particles. The coating layer contains amorphous carbon particles and an amorphous carbon layer. It is preferable that the negative electrode active material contain 1 to 6% by mass of the scaly graphite particles and that the graphite particles, the amorphous carbon particles, and the amorphous carbon layer be in a mass ratio of 100:&#x3b1;:&#x3b2; where 1&#x2266;&#x3b1;&#x2266;10, 1&#x2266;&#x3b2;&#x2266;10, and &#x3b1;&#x2266;1.34&#x3b2;.

Non-aqueous electrolyte secondary cell containing negative active material including scaly graphite particles and graphite particles coated with amorphous carbon particles and amorphous carbon layer and method of manufacturing the same

A prismatic nonaqueous electrolyte secondary battery includes a flat winding electrode assembly formed by winding an elongated positive and negative electrodes with an elongated separator interposed therebetween, and an outer body storing the flat winding electrode assembly and a nonaqueous electrolyte. The positive electrode includes a positive electrode substrate exposed portion formed along a longitudinal direction. The negative electrode includes a negative electrode substrate exposed portion formed along a longitudinal direction. The nonaqueous electrolyte contains at least one of a lithium salt having an oxalate complex as an anion and lithium difluorophosphate (LiPFO) at the time of making the nonaqueous electrolyte secondary battery. The flat winding electrode assembly has eight or more layers of a winding portion formed only of the separator in its central portion. This battery can allow a nonaqueous electrolyte having a high viscosity to easily penetrate the inside of a flat winding electrode assembly.

A nonaqueous electrolyte secondary battery includes: an electrode assembly including positive and negative electrode plates; a nonaqueous electrolyte; an outer body; and a current interruption mechanism being provided on at least one of a conductive pathway between the positive electrode plate and a positive electrode external terminal and a conductive pathway between the negative electrode plate and a negative electrode external terminal. The nonaqueous electrolyte contains an overcharge inhibitor. The positive electrode active material layer has a specific surface area of 1.3 m/g or less. The positive electrode active material layer has a total surface area of 41 m/g or less with respect to the total mass of the overcharge inhibitor in the nonaqueous electrolyte. Thus the battery can increase a battery internal pressure inside the outer body in a short period of time to activate the current interruption mechanism to interrupt the conductive pathway if the battery is overcharged.

A nonaqueous electrolyte secondary battery according to an embodiment of the present invention includes an electrode assembly, a nonaqueous electrolyte, and a container. The electrode assembly has a positive electrode, a negative electrode, and a separator. The positive electrode contains particles of a lithium transition metal compound as a positive electrode active material. The negative electrode is opposed to the positive electrode. The separator is disposed between the positive electrode and the negative electrode. The nonaqueous electrolyte contains lithium difluorophosphate. The container houses the electrode assembly and the nonaqueous electrolyte. The battery capacity is not less than 21 Ah. The mean particle diameter (D) of the particles of the lithium transition metal compound is not less than 5 &#x3bc;m and not more than 15 &#x3bc;m. The (D&#x2212;D)/Dof the particles of the lithium transition metal compound is under 1.1.

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Hyogo, Japan

Toyoki Fujihara