Showa Denko Kabushiki Kaisha

Showa Denko K.k.

Showa Highpolymer Co., Ltd.

Other

Japan Polyolefins Co., Ltd.

Taisei Polymer Co.

Toshio Taka

Kihachi Shishido

Eiichiro Takiyama

Yuichiro Yasukawa

Takuo Ohkubo

Akira Nakamura

Ryosuke Kamei

Tetuya Takahashi

Takuo Okubo

Takumi Araki

Ryuichi Katsumoto

Tadahiro Kegasawa

Kazuo Ozaki

Akihiro Hashimoto

Tomoaki Kobayashi

Takeshi Onoda

Isao Hashimoto

Keiitsu Kobayashi

Yoshimasa Saito

Terumitu Kotani

Yoshio Kawasaki

Kiyotaka Osanai

Terumitsu Kotani

Hisashi Hatano

Toshihiko Funato

Hisasi Hatano

Kihahi Shishido

Kazuo Yoneda

Takehiko Asano

The present invention relates to a laminated member comprising a polyethylene resin composition layer having a very high adhesive strength to a substrate, and a method for manufacturing the same. The present invention is directed to a method for manufacturing the laminated member, which has a high adhesive strength to a different kind of substrate within a range from low to high temperature, and can reduce the resin temperature during the extrusion-lamination molding and inhibit any noxious influence on the working and surrounding environments, and is also superior in terms of high-speed mold ability at low temperature, and the laminated member. In the present invention, a compound having a specific structure is incorporated into a polyethylene resin composition layer. The present invention can be used to particular advantage in laminate products such as packaging material.

Laminated member and method for manufacturing the same

The invention relates to a low-density polyethylene resin for laminates, a composition thereof, and a laminate and production method therefor. The low-density polyethylene resin is one obtainable by a high pressure radical polymerization method and has a density of 0.910 to 0.935 g/cm , a melt flow rate of 0.1 to 300 g/10 min., and a terminal vinyl group number of 0.4 or more per 1,000 carbon atoms. According to the invention, a laminate having high interlayer adhesion strength can be obtained also by low-temperature, high-speed molding so that the occurrence of smoking and odor can be prevented. Also, the resin is excellent in productivity and economics. Further, the resin is excellent in productivity and economics because it can be readily made thinner. The laminate is suitable for application to, for example, food wrapping materials, containers, etc.

Low-density polyethylene resin for laminating, composition thereof, laminates produced therefrom and process for producing the same

A method and apparatus for molding an inflation film even from a thermoplastic resin having a small melt tension, in which a melt resin bubble extruded from an extruder is molded, while controlling a resin temperature of the bubble to a certain temperature range by an air ring provided with a plurality of annular slits for blowing cooling air in a take-up direction of the melt resin bubble and provided at a position at which the melt resin bubble is remarkably expanded, after (a) cooling air is blown to a melt resin bubble from a first air ring provided at the proximity of a die outlet to cool said melt resin bubble; and, then, the bubble is either (i) brought into contact, on the inner surface thereof, with the surface of a stabilizer provided on a die surface, or (ii) is supported in a non-contact state through an air layer, while being taken up.

Method and apparatus for molding inflation film

Foamed thin materials such as foamed film and foamed fibrillated materials produced by extruding a composition consisting of 100 parts by weight of aliphatic polyester having a melt viscosity of 1.0.times.10.sup.3 -1.0.times.10.sup.5 poises at a temperature of 190.degree. C. and a shear rate of 100 sec.sup.-1, and having a melting point of 70.degree.-200.degree. C., and 0.2-5 parts by weight of foaming agent. These foamed thin materials has biodegradability, excellent mechanical, insulating, touch and aesthetic properties. They are useful materials as insulating, packaging, oil absorbing materials and filters.

Polyester foamed thin materials

An aliphatic polyester film which is synthesized from a glycol and an aliphatic polybasic acid having a melt viscosity of 2,000-100,000 poises at a temperature of 190.degree. C. and a shear rate of 100 sec.sup.-1, and having a melting point of 70.degree.-200.degree. C. The film is excellent in heat stability and mechanical strength as well as biodegradability when buried in the earth; and has low combustion heat than polyethylene and polypropyrene.

Polyester film

The present invention provides a low temperature heat shrinkable film comprising a linear low density polyethylene resin having a short branched chain and a density of 0.935 g/cm.sup.3, and whose film properties are such that the haze value is 5% or less, the heat shrinkages at 90.degree. C. in the M and T directions are 30% or more and 5% or less, respectively , and the shrinkage stress at 90.degree. C. in the M direction is 300 g/mm.sup.2 or more. This transparent film having an excellent low temperature heat shrinkability can be produced by drawing a film of the above-mentioned polyethylene resin between two rolls having a diameter of 200 mm or less at an air gap of 10 mm or less at a draw ratio of 3.0 to 6.0. Further, an inflation film having a multilayer structure can be obtained by press bonding or press bonding and drawing a plurality of films comprising the above-mentioned polyethylene resin. This laminate film has an excellent transparency and strength, and has a uniform film thickness.

Low temperature heat shrinkable film and process for producing the same

The present invention provides a low temperature heat shrinkable film comprising a linear low density polyethylene resin having a short branched chain and a density of 0.935 g/cm.sup.3, and whose film properties are such that the haze value is 5% or less, the heat shrinkages at 90.degree. C. in the M and T directions are 30% or more and 5% or less, respectively, and the shrinkage stress at 90.degree. C. in the M direction is 300 g/mm.sup.2 or more. This transparent film having an excellent low temperature heat shrinkability can be produced by drawing a film of the above-mentioned polyethylene resin between two rolls having a diameter of 200 mm or less at an air gap of 10 mm or less at a draw ratio of 3.0 to 6.0. Further, an inflation film having a multilayer structure can be obtained by press bonding or press bonding and drawing a plurality of films comprising the above-mentioned polyethylene resin. This laminate film has an excellent transparency and strength, and has a uniform film thickness.

A low-temperature heat-shrinkable film having a haze value not larger than 8%, a heat shrinkability in the machine direction at a temperature of 90.degree. C. of at least 30%, and a shrinkage stress of at least 300 g/mm.sup.2, is made from a composition comprising (a) a linear ethylene polymer containing short-chain branches and having a density not larger than 0.940 g/cm.sup.2 and (b) an ethylene/propylene random copolymer containing 3.5 to 10% by weigh of units derived from ethylene, wherein the proportion of the ethylene/propylene random copolymer in the composition is 15 to 50% by weight.

Low-temperature heat-shrinkable film

High density polyethylene type transparent film and process for

Low temperature heat shrinkable film

A medical bag composed of a laminate comprising (i) an inner layer of a low-density polyethylene, an ethylene-1-olefin copolymer having a density of 0.920 g/cm.sup.3 or more, or a high density polyethylene, (ii) an intermediate layer of an ethylene-1-olefin copolymer having a density of 0.935 g/cm.sup.3 or less, and (iii) an outer layer of a low-density polyethylene, an ethylene-1-olefin copolymer having a density of 0.920 g/cm.sup.3 or more, or a high-density polyethylene.

Medical bag

Heat resistant foamed shrinkable film

Growing community of inventors

Kawasaki, Japan

Toshio Taka