Fujifilm Corporation

Dowa Electronics Materials Co., Ltd.

Toshio Tada

Norihito Kasada

Masahito Oyanagi

Eiki Ozawa

Takuto Kurokawa

Takuro Sugiyama

Hirohisa Omoto

Hiroyuki Suzuki

Akinori Sugishima

Shuji Kaneda

Kazuyuki Kitada

Osamu Shimizu

Nobuo Yamazaki

Satoshi Matsubaguchi

Ayako Matsumoto

Kenji Masada

Kengo Saito

Satoshi Shiki

Daisuke Abe

Shiho Kamisawa

Akira Manabe

Atsushi Morooka

Tatsuya Yamashita

Yasuhiro Kawatani

Futoshi Nagashima

Provided is an Al-containing hexagonal ferrite magnetic powder which produces an excellent durability-improving effect on a magnetic recording medium, wherein uniform pulverization of the magnetic powder can be easily achieved by dispersion treatment in preparation of a magnetic coating material even in cases where the magnetic powder has a small primary particle size or has a composition which is likely to produce hard secondary particles. The magnetic powder for a magnetic recording medium is an Al-containing hexagonal ferrite magnetic powder having an Al/Fe molar ratio of 0.030 to 0.200, and has a particle size distribution in which the volume ratio of particles having a particle size of 30 μm or more as measured by a laser diffraction particle size distribution analyzer with a dispersion pressure of 100 kPa is 5.0% or less, and an activation volume Vact of 1800 nmor less.

Magnetic powder for magnetic recording medium

Provided is a hexagonal ferrite magnetic powder for a magnetic recording medium, containing hexagonal ferrite magnetic particles having aluminum hydroxide adhered on the surface thereof, the hexagonal ferrite magnetic powder having an Al/Fe molar ratio of 0.030 to 0.200, a Co/Fe molar ratio of 0.002 to 0.030, and a Nb/Fe molar ratio of 0.005 to 0.050, and having an Fe site valence Aof 3.015 to 3.040 as calculated by A=(3+2&#xd7;[Co/Fe]+5&#xd7;[Nb/Fe])/(1+[Co/Fe]+[Nb/Fe]) wherein [Co/Fe] represents the Co/Fe molar ratio and [Nb/Fe] represents the Nb/Fe molar ratio, and preferably having an activation volume Vact of 1400 to 1800 nm. This magnetic powder simultaneously achieves an increase in magnetic characteristics including SNR of a magnetic recording medium and a further increase in durability thereof.

Hexagonal ferrite magnetic powder

The magnetic tape has a magnetic layer containing ferromagnetic powder and binder on a nonmagnetic support, wherein the centerline average surface roughness Ra as measured on the surface on the magnetic layer side of the magnetic tape is less than or equal to 1.8 nm, and the logarithmic decrement as determined by a pendulum viscoelasticity test on the surface on the magnetic layer side of the magnetic tape is less than or equal to 0.050.

Magnetic tape having a characterized magnetic layer and method of manufacturing the same

The magnetic recording medium includes a non-magnetic support and a magnetic layer which contains ferromagnetic powder and a binder, in which the ferromagnetic powder is ferromagnetic hexagonal ferrite powder, the magnetic layer contains an abrasive, Int (110)/Int (114) of a crystal structure of the hexagonal ferrite, determined by performing X-ray diffraction analysis on the magnetic layer by using an In-Plane method, to a peak intensity of a diffraction peak of (114) plane of the crystal structure is equal to or higher than 0.5 and equal to or lower than 4.0, a squareness ratio of the magnetic recording medium in a vertical direction is equal to or higher than 0.65 and equal to or lower than 1.00, and a logarithmic decrement obtained by performing a pendulum viscoelasticity test on a surface of the magnetic layer is equal to or lower than 0.050.

Magnetic recording medium having characterized magnetic layer

The magnetic recording medium includes a magnetic layer which contains ferromagnetic hexagonal ferrite powder and a binder, in which the magnetic layer contains an abrasive and a fatty acid ester, Int (110)/Int (114) of a crystal structure of the hexagonal ferrite, determined by performing XRD analysis on the magnetic layer by using an In-Plane method, is equal to or higher than 0.5 and equal to or lower than 4.0, a squareness ratio of the magnetic recording medium in a vertical direction is equal to or higher than 0.65 and equal to or lower than 1.00, FWHMand FWHMis greater than 0 nm and equal to or smaller than 7.0 nm, and a difference between spacings measured within a surface of the magnetic layer by an optical interference method before and after the heating in a vacuum is greater than 0 nm and equal to or smaller than 8.0 nm.

The magnetic tape includes a magnetic layer including ferromagnetic powder, non-magnetic powder, and a binding agent and a back coating layer including non-magnetic powder and a binding agent, in which the ferromagnetic powder is ferromagnetic hexagonal ferrite powder, a center line average surface roughness measured regarding a surface of the magnetic layer is equal to or smaller than 1.8 nm, an intensity ratio of a peak intensity of a diffraction peak of a (110) plane with respect to a peak intensity of a diffraction peak of a (114) plane of a hexagonal ferrite crystal structure obtained by an X-ray diffraction analysis of the magnetic layer by using an In-Plane method is 0.5 to 4.0, a vertical squareness ratio of the magnetic tape is 0.65 to 1.00, and a contact angle with respect to 1-bromonaphthalene measured regarding a surface of the back coating layer is 15.0&#xb0; to 30.0&#xb0;.

Magnetic tape having characterized magnetic layer

Provided is a magnetic tape in which an Ra measured regarding a surface of a magnetic layer is equal to or smaller than 1.8 nm, Int(110)/Int(114) of a hexagonal ferrite crystal structure obtained by an XRD analysis of the magnetic layer by using an In-Plane method is 0.5 to 4.0, a vertical squareness ratio of the magnetic tape is 0.65 to 1.00, full widths at half maximum of spacing distribution measured by optical interferometry regarding the surface of the back coating layer before and after performing a vacuum heating with respect to the magnetic tape are greater than 0 nm and equal to or smaller than 10.0 nm, and a difference between the spacings measured by optical interferometry regarding the surface of the back coating layer before and after performing the vacuum heating is greater than 0 nm and equal to or smaller than 8.0 nm.

The magnetic tape includes a magnetic layer including ferromagnetic powder, non-magnetic powder, and a binding agent and a back coating layer including non-magnetic powder and a binding agent, in which the ferromagnetic powder is ferromagnetic hexagonal ferrite powder, an Ra measured regarding a surface of the magnetic layer is equal to or smaller than 1.8 nm, an intensity ratio of a peak intensity of a diffraction peak of a (110) plane with respect to a peak intensity of a diffraction peak of a (114) plane of a hexagonal ferrite crystal structure obtained by an X-ray diffraction analysis of the magnetic layer by using an In-Plane method is 0.5 to 4.0, a vertical squareness ratio of the magnetic tape is 0.65 to 1.00, and a logarithmic decrement acquired by a pendulum viscoelasticity test performed regarding a surface of the back coating layer is equal to or smaller than 0.060.

The magnetic recording medium includes a non-magnetic support and a magnetic layer, wherein the magnetic layer contains ferromagnetic hexagonal ferrite powder and an abrasive, Int (110)/Int (114) of a crystal structure of the hexagonal ferrite determined by performing XRD analysis on the magnetic layer by using an In-Plane method is equal to or higher than 0.5 and equal to or lower than 4.0, a squareness ratio of the magnetic recording medium in a vertical direction is equal to or higher than 0.65 and equal to or lower than 1.00, one or more kinds of components selected from the group consisting of a fatty acid and a fatty acid amide is contained in a magnetic layer side portion on the support, and a C&#x2014;H-derived C concentration obtained by ESCA within a surface of the magnetic layer at a photoelectron take-off angle of 10&#xb0; is equal to or higher than 45 at %.

Provided is a magnetic tape in which an Ra measured regarding a surface of a magnetic layer is equal to or smaller than 1.8 nm, Int(110)/Int(114) of a hexagonal ferrite crystal structure obtained by an X-ray diffraction analysis of the magnetic layer by using an In-Plane method is 0.5 to 4.0, a vertical squareness ratio of the magnetic tape is 0.65 to 1.00, the back coating layer includes one or more kinds of component selected from the group consisting of fatty acid and fatty acid amide, and a C&#x2014;H derived C concentration calculated from a C&#x2014;H peak area ratio of C1s spectra obtained by X-ray photoelectron spectroscopic analysis performed on the surface of the back coating layer at a photoelectron take-off angle of 10 degrees is equal to or greater than 35 atom %.

The magnetic recording medium includes a non-magnetic support and a magnetic layer containing ferromagnetic powder and a binder, in which the ferromagnetic powder is ferromagnetic hexagonal ferrite powder, the magnetic layer contains an abrasive, an intensity ratio of a peak intensity of a diffraction peak of (110) plane of a crystal structure of the hexagonal ferrite, determined by performing X-ray diffraction analysis on the magnetic layer by using an In-Plane method, to a peak intensity of a diffraction peak of (114) plane of the crystal structure is equal to or higher than 0.5 and equal to or lower than 4.0, a squareness ratio of the magnetic recording medium in a vertical direction is equal to or higher than 0.65 and equal to or lower than 1.00, and a contact angle with 1-bromonaphthalene measured within a surface of the magnetic layer is in a range of 50.0&#xb0; to 55.0&#xb0;.

The magnetic recording medium has a non-magnetic support and a magnetic layer which is provided on the support and contains ferromagnetic powder and a binder, in which the ferromagnetic powder is ferromagnetic hexagonal ferrite powder, the magnetic layer contains an abrasive, an intensity ratio (Int (110)/Int (114)) of a peak intensity Int (110) of a diffraction peak of (110) plane of a crystal structure of the hexagonal ferrite, determined by performing X-ray diffraction analysis on the magnetic layer by using an In-Plane method, to a peak intensity Int (114) of a diffraction peak of (114) plane of the crystal structure is equal to or higher than 0.5 and equal to or lower than 4.0, and a squareness ratio in a vertical direction is equal to or higher than 0.65 and equal to or lower than 1.00. The present invention also provides a method for manufacturing the magnetic recording medium.

Magnetic recording medium having characterized magnetic layer and method for manufacturing same

Provided is a magnetic tape in which a vertical direction squareness ratio and/or a longitudinal direction squareness ratio obtained by measurement performed by sweeping an external magnetic field in the magnetic tape in a predetermined range by a vibrating sample magnetometer is 0.70 to 1.00, and A calculated by Expression 1 is equal to or smaller than 5.0%. In Expression 1, n represents the number of measurement points measured at magnetic field strength of &#x2212;40 kA/m to 40 kA/m during the sweeping and is 52, Mr(Hex) represents a magnetization quantity measured at magnetic field strength Hex, and &#x3bc; represents an arithmetical mean of Mr(Hex) obtained by measurement performed in the range of the magnetic field strength during the sweeping. 

Magnetic tape

The magnetic tape has a nonmagnetic layer containing nonmagnetic powder and binder on a nonmagnetic support and a magnetic layer containing ferromagnetic powder and binder on the nonmagnetic layer, wherein a fatty acid ester is contained in at least the magnetic layer, the ferromagnetic powder is ferromagnetic hexagonal ferrite powder, the ferromagnetic hexagonal ferrite powder has a crystallite volume as determined by X-ray diffraction analysis ranges from 1,000 nmto 2,400 nm, and a ratio of the crystallite size Dobtained from a diffraction peak of a (107) plane to a particle size in a direction of an easy axis of magnetization Das determined by observation with a transmission electron microscope, D/D, is greater than or equal to 1.1, and &#x394;SFD in a longitudinal direction of the magnetic tape as calculated with Equation 1: &#x394;SFD=SFD&#x2212;SFD, ranges from 0.50 to 1.60.

Magnetic tape and method of manufacturing the same

A magnetic tape has a magnetic layer containing ferromagnetic powder and binder on a nonmagnetic support. The magnetic layer contains a fatty acid ester. The full width at half maximum of the spacing distribution as measured by optical interferometry on the magnetic layer side surface of the magnetic tape before vacuum heating the magnetic tape is greater than 0 nm but less than or equal to 5.0 nm. The full width at half maximum of the spacing distribution after vacuum heating the magnetic tape is greater than 0 nm but less than or equal to 5.0 nm. The difference between the spacing Safter vacuum heating the magnetic tape and the spacing Sbefore vacuum heating the magnetic tape, S&#x2212;S, is greater than 0 nm but less than or equal to 8.0 nm.

Growing community of inventors

Minami-ashigara, Japan

Toshio Tada