Japan Synthetic Rubber Co., Ltd.

Toyoda Gosei Co., Ltd.

Toshio Miyabayashi

Yasuhiko Takemura

Nobuyuki Sakabe

Hiroji Enyo

Shinichiro Zen

Toshio Ohhara

Teizo Kotani

Yoshiyuki Udagawa

Hiroshi Ise

Minoru Tanaka

Yasumasa Takeuchi

Masayoshi Ichikawa

Hozumi Sato

Kenya Makino

Noboru Ohshima

Hideyuki Fujiwara

Isao Furuta

Masato Sakai

Yosihiro Ohira

Yukihiro Sawada

A flexible heat and gasoline resistant rubber laminate having high interlaminar adhesion consisting of a rubber layer (1) consisting a blend of (a) acrylic polymer derived from plasticized crosslinkable acrylates and an unsaturated epoxy group containing compound and (b) a vinylidene fluoride resin, laminated to a rubber layer (2) consisting essentially of crosslinked acrylic polymer derived from plasticized crosslinkable acrylates and unsaturated epoxy group consisting compounds.

Rubber laminate

A hydrogenated copolymer rubber which is a hydrogenation product of a random copolymer rubber consisting of:

Hydrogenated copolymer rubber, rubber composition comprising said rubber

A novel ester group-containing (meth)acrylic acid ester represented by the general formula (I): ##STR1## wherein R.sup.1 is a hydrogen atom or a methyl group, R.sup.2 is a C.sub.3-20 alkylene group, R.sup.3 is a C.sub.1-20 hydrocarbon group or its derivative, and l is an integer of 1-20, and a (co)polymer composed of said ester group-containing (meth)acrylic acid ester and other monomer(s) copolymerizable therewith. This (co)polymer gives a crosslinked product superior in heat resistance, low-temperature resistance and oil resistance.

Novel ester group-containing (meth)acrylic acid ester, novel (co)polymer

A substantially random, linear vinylidene fluoride-acrylic acid ester copolymer comprising:

Vinylidene fluoride-acrylic acid ester copolymer, process for producing

An acrylic rubber obtainable by copolymerizing a monomer mixture of:

Acrylic rubber, acrylic rubber composition and cured rubber article

A multi-component copolymer rubber consisting essentially of (A) 20 to 69.5% by weight of a cyano-substituted alkyl (meth)acrylate, (B) 30 to 79.5% by weight of an alkyl acrylate, (C) 0.5 to 10% by weight of a crosslinkable monomer and (D) 0 to 10% by weight of other ethylenically unsaturated monomer copolymerizable with (A), (B) and (C), excels in heat resistance, ozone resistance, sour gasoline resistance and sour gasohol resistance. There properties of said multi-component copolymer rubber can further be improved by incorporating into the copolymer rubber a crosslinking agent, a metal salt, a vinylidene fluoride polymer, a vinyl chloride resin or other multi-component copolymer rubber.

Multi-component copolymer rubber, a process for producing the same and a

A multi-component copolymer rubber consisting essentially of (A) 20 to 69.5% by weight of a cyano-substituted alkyl (meth)acrylate, (B) 30 to 79.5% by weight of an alkyl acrylate, (C) 0.5 to 10% by weight of a crosslinkable monomer and (D) 0 to 10% by weight of other ethylenically unsaturated monomer copolymerizable with (A), (B) and (C), excels in heat resistance, ozone resistance, sour gasoline resistance and sour gasohol resistance. These properties of said multi-component copolymer rubber can further be improved by incorporating into the copolymer rubber a crosslinking agent, a metal salt, a vinylidene fluoride polymer, a vinyl chloride resin or other multi-component copolymer rubber.

Multi-component copolymer rubber, a process for producing the same, and

A multi-component polymer rubber comprising (A) 15 to 60 mole % of an .alpha.,.beta.-unsaturated nitrile, (B) 10 to 75 mole % of a conjugated diene, and (C) 2 to 55 mole % of a fluoroalkyl acrylate or methacrylate or a fluorine-containing .alpha.-olefin, and having a glass transition temperature (T.sub.g) of -50.degree. C. to -20.degree. C., the percentages of the components (A), (B) and (C) being based on the total sum of moles of the components (A), (B) and (C). Said multi-component polymer rubber is excellent in sour gasoline resistance and alcohol-containing gasoline resistance.

Multi-component polymer rubber

A heat-aging-resistant rubbery polymer composition comprising a rubbery polymer, at least one compound selected from the group consisting of diphenylamine derivatives and phenol derivatives as an age resister for said rubbery polymer, and polyalkylene ether glycol having an average molecular weight of 100-5,000, and optionally a compound represented by the formula, ##STR1## in which R is alkyl having 10 to 20 carbon atoms. Preferably, said at least one compound selected from the group consisting of diphenylamine derivatives and phenol derivatives is chemically linked to said rubbery polymer as a part of the molecular chain. Said rubbery polymer composition is unexpectedly superior in heat-aging-resistance to a composition consisting only of said rubbery polymer and said age resister or a composition consisting only of said rubbery polymer and said polyalkylene ether glycol.

Heat-aging-resistant rubber composition

By reacting a diene polymer having nitrile groups with an anti-deteriorating agent having at least one polar group selected from the group consisting of amino group and imino group in the presence of a catalyst, a diene rubber can be obtained in which said anti-deteriorating agent is chemically combined to the nitrile groups. Said rubber per se has resistance to deterioration and, at the same time, acts as an anti-deteriorating agent for other diene rubbers. The chemically combined anti-deteriorating agent is not extractable with solvent, so that said rubber has a stable resistance to deterioration and a stable anti-deteriorating action on other diene rubbers.

Diene rubber having anti-deteriorating function and process for

In the preparation of 1,2-polybutadiene with a vinyl content of at least 70% by contacting 1,3-butadiene with a catalyst consisting of:

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Yokkaichi, Japan

Toshio Miyabayashi