Tosoh Corporation

Toyo Soda Manufacturing Co., Ltd.

Toshio Hironaka

Yukihiro Tsutsumi

Kazuhiko Sekizawa

Takanori Miyake

Masao Nakano

Yasushi Hara

Noritaka Nagasaki

Kiyotaka Oyama

Yuji Nonaka

Keiichi Kihara

Yukio Ito

Teruhisa Sakamoto

Yasuhiro Oda

Nobumasa Suzuki

Seiichi Asano

Nobuyuki Kanai

Satoshi Ishida

A process for producing an ethylenamine, which comprises reacting ammonia and/or an ethylenamine with an ethanolamine in the presence of hydrogen to obtain an ethylenamine having an increased number of ethylene chains over the ammonia and/or the ethylenamine used as the starting material, wherein a catalyst comprising Ni, X and M elements wherein X is Re, Ir, Pt or Pd, and when X is Re, Ir or Pb, M is at least one rare earth element selected from the group consisting of scandium, yttrium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium, and when X is Pd, M is at least one member selected from the group consisting of rare earth elements is used for the reaction.

Process for producing an ethylenamine

A process for producing an ethylenamine, which comprises reacting ammonia and/or an ethylenamine with an ethanolamine in the presence of hydrogen to obtain an ethylenamine having an increased number of ethylene chains over the ammonia and/or the ethyelenamine used as the starting material, wherein a catalyst comprising Ni and M elements wherein M is at least one rare earth element selected from the group consisting of scandium, yttrium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium, is used for the reaction.

Disclosed is a shaped zeolite catalyst used for liquid phase organic reactions. The shaped zeolite catalyst is composed of substantially spherical particles having a particle diameter substantially in the range of from 70 to 300 .mu.m, and which has fine pores having a pore volume of 0.4 to 1 cc per gram of the shaped catalyst and a median pore diameter based on the pore volume of 1,000 to 5,500 .ANG..

Shaped zeolite catalyst for liquid phase organic reactions

A para-substituted halogenobenzene derivative is prepared by halogenating a benzene derivative in the liquid phase in the presence of a molded zeolite catalyst body comprising, based on the weight of the molded zeolite catalyst body, 10 to 95% by weight of an L-type zeolite as the anhydrous state and 5 to 90% by weight of amorphous silica.

Process for preparing para-substituted halogenobenzene derivatives

A p-substituted halobenzene derivative, which is very valuable in industry, can be obtained by halogenation of benzene and/or a benzene derivative in the liquid phase using, as a catalyst, a faujasite type zeolite in the presence of any one member selected from the group consisting of sulfur-containing compounds, nitrogen-containing organic basic compounds, salts of said nitrogen-containing organic basic compounds, and a mixture of said nitrogen-containing organic basic compounds and salts thereof.

Process for producing halogenated benzene derivative using zeolite

p-Substituted halogenated benzene derivatives are prepared at a high selectivity by halogenating benzene and/or benzene derivatives by using as a catalyst a zeolite modified with a metal salt.

Process for preparation of halogenated benzene derivatives

In the liquid phase chlorination of benzene derivatives including benzene per se in the presence of a zeolite possessing the main pores having the opening formed of a 12-membered oxygen ring; para-substituted chlorinated benzene derivatives are preferentially obtained by adding a small quantity of a quaternary ammonium salt or salts to the reaction mixture.

Preparation of halogenated benzene derivatives

Olefins are hydrated to the corresponding alcohols in the presence of at least one crystalline alumino-silicate selected from offretite, ferrierite and erionite. The offretite, ferrierite and erionite are preferably characterized by X-ray diffraction patterns shown in Tables 1 and 7; Tables 2, 8 and 9; and Table 3, respectively. At least a part of the exchangeable cations in the offretite, ferrierite and erionite may be exchanged with at least one cation selected from a hydrogen ion, an alkaline earth metal ion and a rare earth metal ion. Furthermore, at least a part of the exchangeable cations in the erionite may be exchanged with an ammonium ion and/or an alkali metal ion.

Process for preparation of alcohols by hydration of olefins

Conjugated dienes containing a cyano group having the formula ##EQU1## wherein R.sub.1 and R.sub.2 represent hydrogen atom, an alkyl group or a phenyl group are produced by dehydrating 2-cyano-3-hydroxy-1-olefins in the presence of an alkaline catalyst while continually removing the product being formed from the reaction system.

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Tokuyama, Japan

Toshio Hironaka