Matsushita Electric Industrial Co., Ltd.

Takomoto Oil & Fat Co., Ltd.

Toshikuni Kojima

Yasuo Kudoh

Sohji Tsuchiya

Masao Fukuyama

Susumu Yoshimura

Norishige Nanai

Kenji Akami

Kenji Kuranuki

Chiharu Hayashi

Yasuhiro Kobatake

Yasue Matsuya

Hiroshi Shimada

Akio Yamashita

Wataru Fujikawa

Koichi Yoshida

Hiromi Wakasono

Kazuo Tadanobu

Soji Tsuchiya

Sadashi Higuchi

Junji Ozaki

Takuhisa Sugimoto

Masanori Morii

Shohzoh Takahashi

Hirohiko Itoh

Yasunari Hoshii

A cathode ray tube includes a bulb including a front panel and a funnel, and an electron gun. The front panel includes a color selection mechanism and phosphors on an inner surface thereof. The funnel includes a conductive layer on an inner wall thereof. The electron gun is accommodated in a neck portion of the funnel. The conductive layer is divided into at least two regions, each of which has a different electric potential. A high electric potential conductive layer having a high electric potential, an insulating region, a resistive layer, and a low electric potential conductive layer having an electric potential lower than that of the high electric potential conductive layer are formed in this order from the panel side to the electron gun side. With this configuration, the two conductive layers do not interfere with each other because of discharge or the like and are independent, and stable voltage can be maintained. Thus, an electrostatic lens can be formed.

Cathode ray tube

A solid electrolytic capacitor having (A) a capacitor element including an oxide layer formed on a part of an outer surface of a valve metal anode body, a solid electrolyte layer formed on the oxide layer layer, and a cathode conductor layer formed on the solid electrolyte layer, and an anode lead out area on a remaining part of the anode body, (B) lead terminals connected to the cathode and the anode lead out area of the capacitor element, and (C) a packaging resin encapsulating the capacitor element with parts of the lead terminals exposed outside. The solid electrolytic capacitor has a first separation strip and a second separation strip formed on a part of the roughened surface layer and also has insulating material on the respective surfaces of the first and the second separation strips.

Solid electrolytic capacitor and its manufacturing method

A solid electrolytic capacitor comprising comprises a pair of electrodes, and a dielectric film provided between the paired electrodes wherein at least one of the paired electrodes comprising a first conductive polymer layer which is made of a polymer of a member selected from the group consisting of pyrrole and derivatives thereof, the first conductive polymer layer being doped with a mixed dopant of a polyvalent anion and a monovalent anion consisting of a sulfonate ion dissociated from an anionic surface active agent. The conductive polymer layer may have a double-layered or a multi-layered structure wherein a second and/or third conductive polymer layer is made of a doped polymer of a thiophene derivative. A method for making the capacitors are also described.

Solid electrolytic capacitors comprising a conductive layer made of a polymer of pyrrole or its derivative and method for making the same

A conductive polymer composition comprises a conjugated double bond-bearing polymer and a composite dopant consisting essentially of an organic anion derived from an anionic surface active agent and an inorganic anion derived from a transition metal salt. A process for preparing the conductive polymer composition is also described wherein the polymerizable proceeds rapidly in coexistence of the organic anion and the inorganic anion. Addition of fine particle of an oxide is effective in film formation on substrates.

Conductive polymer composition comprising polypyrrole and composite

A solid electrolytic capacitor is composed of a pair of electrodes and a dielectric film therebetween, wherein one electrode includes a conducting polymer doped with a polyvalent anion and a monovalent anion. The conducting polymer layer may have a multi-layer structure wherein a second or third conductive polymer layer is made of doped thiophene or derivative thereof.

Solid electrolytic capacitors comprising a conductive layer made of a

Solid electrolytic capacitors comprise a valve metal member having a dielectric film, with or without a conductive underlying layer, formed on the member, and a conductive polymer film formed on the layer. The conductive polymer film is formed by electrolytic polymerization of a polymerizable monomer contained in a system which comprises the monomer, a support electrolyte, and at least one member selected from silicic acids and silicates with or without phenol compounds. By this, the life of the capacitor even under high temperature and high humidity conditions is significantly improved. Methods for fabricating such capacitors are also described.

Solid electrolytic capacitors and method for manufacturing the same

A method for fabricating solid electrolytic capacitors which comprises providing a valve metal foil having a dielectric film and a conductive inorganic film formed on the valve metal foil in this order, contacting an electrode for electrolytic polymerization with part of the valve metal foil wherein the electrode is made of a material incapable of undergoing anodization in an electrolytic polymerization solution, subjecting the valve metal foil to electrolytic polymerization by application of a potential between the electrode and a counter electrode to form a conductive polymer film on the conductive inorganic film, and removing the electrode along with the contacted portion of the valve metal foil. At least one conductive paste film may be formed on the conductive polymer film prior to the removal of the electrode. In addition, an insulating film may be formed on an exposed portion of the valve metal foil after the removal of the electrode. A fabrication method of a capacitor unit having at least two capacitor elements is also described.

Method for fabricating solid electrolytic capacitors using an organic

A solid electrolytic capacitor comprises a valve metal member having a dielectric oxide film and a conductive underlying layer formed on the member in this order, and a conductive polymer film formed on the layer. The conductive polymer film is formed by electrolytic polymerization of a polymerizable monomer contained in an aqueous solution containing a support electrolyte and a phosphate. By the presence of the phosphate in the aqueous solution, phosphate ions dissociated from the phosphate are adsorbed on the dielectric film during the course of the electrolytic polymerization. Thus, the humidity resistance of the dielectric oxide film is improved, resulting in improvements in the capacitance and loss of the capacitor under high temperature and high humidity conditions. A fabrication method of the capacitor is also described.

Solid electrolytic capacitor and method for manufacturing the same

Solid electrolytic capacitors comprise a valve metal member having a dielectric oxide film and a conductive underlying layer formed on the member in this order, and a conductive polymer film formed on the layer. The conductive polymer film is formed by electrolytic polymerization of a polymerizable monomer contained in a system containing the monomer and a support electrolyte consisting of a compound having at least one nitro group. By this, high temperature stability of the capacitor is significantly improved. Alternatively, the electrolytic polymerization may be effected in a system which comprises a monomer, a support electrolyte and a phenol or phenoxide derivative having at least one nitro group. Methods for fabricating such capacitors are also described.

Solid electrolytic capacitors comprise a capacitor element having a valve metal substrate, a dielectric film formed thereon, and a conductive polymer layer formed on the dielectric film. The capacitor element is encased in a resin casing as not directly contacting the element with the resin casing. The capacitance and leakage current characteristics are improved. Alternatively, a capacitor element includes a valve metal substrate, a dielectric film, an inorganic conductive layer and a conductive polymer layer formed on the substrate in this order, wherein the conductive polymer layer is formed after anodization of the inorganic conductive layer bearing substrate. The life of the resulting capacitor is significantly prolonged. This capacitor element may be encased in a resin casing in a manner as set forth above. Methods for manufacturing the solid electrolytic capacitor are also provided.

A method for manufacturing a solid electrolytic capacitor is described. The method comprises providing a valve metal member which has a dielectric film and an inorganic conductive layer formed on opposite sides of the valve metal member in this order, immersing the valve metal member in an electrolytic polymerization solution, and applying an electric potential sufficient to cause electrolytic polymerization between a first polymerization electrode which is provided on said at least one side of said valve metal member through an electric insulating member and a second polymerization electrode kept away from said first polymerization electrode. Further, the valve metal member may be separated into two regions with an insulating separation layer. One region is a capacitor region and the other is an anode terminal region. The anode terminal region is enfolded or convolutely wound to improve the volumetric efficiency. Solid electrolytic capacitors manufactured by the methods are also described.

A method for fabricating a solid electrolytic capacitor is described, in which a solid electrolyte is made of a conductive polymer layer and is formed on a conductive inorganic layer which is formed on a metallic foil through a dielectric film. For the formation of the conductive polymer layer, while an external electrode is not directly contacted with the conductive inorganic layer, the electrolytic polymerization reaction of a polymerizable monomer in an electrolytic solution is carried out. For this purpose, the external electrode may be covered with a conductive polymer film at the contact portion. Alternatively, the external electrode may be moved from one position to another or may be kept apart from the conductive inorganic layer during the electrolytic polymerization reaction. By this, the mechanical damages of the conductive inorganic layer with the external electrode are suppressed with good electric characteristics of the capacitor.

Method for manufacturing a solid electrolytic capacitor

A solid electrolytic capacitor comprising:

Solid electrolytic capacitor and method of manufacturing the same

A solid electrolytic capacitor comprising a capacitor element which includes a valve metal member capable of forming a dielectric oxide film thereon, a dielectric oxide film formed on the valve metal member, a manganese oxide layer formed on the dielectric oxide film, a conductive polymer film formed on the manganese oxide film by electrolytic polymerization, and terminals formed on the valve metal member and the conductive polymer film, respectively. The solid electrolytic capacitor is improved in capacitor characteristics. A method for manufacturing the solid electrolyte is also described wherein the conductive polymer film is readily formed on the manganese dioxide layer.

A solid electrolytic capacitor uses a solid electrolyte wherein manganese dioxide is uniformly diffused in a polymer made by electrochemical polymerization, and the solid electrolyte is disposed between a first electrode made of valve metal and having an anodic oxide film thereon and a second electrode opposite to the first electrode. The solid electrolytic capacitor shows splendid high frequency characteristics and small leakage current.

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Kawasaki, Japan

Toshikuni Kojima