Fuji Photo Film Company, Limited

Fujifilm Corporation

Jgc Corporation

Fujifilm Holdings Corporation

Toshikazu Nakamura

Hidekazu Yamazaki

Yukihiro Katai

Hiroshi Miyachi

Tadahiro Tsujimoto

Muneyasu Ichimura

Keizo Hosoya

Kenji Sato

Yuji Suzuki

Kunio Ishii

Satoshi Hama

Rin Sasano

Takeo Murata

Katsumi Yamamoto

Masaru Sugiura

Akira Okada

Mamoru Morohashi

Yasuo Namikawa

In order to produce a cellulose ester film constructed of a front layer, an intermediate layer and a rear layer, a dope solution is doped on a supporter. In at least one of the front layer and the rear layer, a mass ratio of a cotton linter to a wood pulp (cotton linter/wood pulp) is between 5/95 and 0/100, and a solvent of the dope contains more than 15 wt.% alcohols and hydrocarbons whose carbon number each is 1-10. Further, a ratio of a solid content density of a solution for forming the front layer and the rear layer to a solid density of a solution for forming the intermediate layer is less than 0.9 wt.%, and a total thickness of the solutions for front and rear layers is more than 5% of the dope ribbon.

Method of producing of cellulose ester film

A pipe for supplying a dope to a co-casting die consists of a goose neck portion connected to a feed block of the co-casting die, and a straight pipe portion connected to the goose neck portion. The goose neck portion has a radius of curvature of 50 mm to 400 mm, and the straight pipe portion forms an angle of 0 to 20 degrees to the horizontal plane. Venting valves are opened up at the beginning of dope feeding, and are closed to some extent as the dope comes out. After the air is completely vented out, the venting valves are completely closed. Thereby, an air collection is completely let out from the pipe, a plastic web discharged from die lips of the co-casting die would not contain any air bubbles, it is prevented that the web splashes to put on the die lips, causing streaks on the produced film.

Film casting method

A cellulose acetate solution is filtrated with a filter medium formed of cellulose fiber. Hydroxyl groups on the filter medium are substituted to other functional groups. An acidic material is added to the cellulose acetate solution, and the filtration is preformed. In order to estimate the hydrogen ion concentration of the organic solvent, a sample solvent of thereof is mixed with water so as to transport hydrogen ions from the sample solvent to the water of a predetermined volume. Then the water is separated from the sample solvent, and the pH value of the water is measured with a pH meter. The result of the measurement is regarded as the pH value of the organic solvent.

Methods for filtrating and producing polymer solution, and for preparing solvent

A production method of cellulose film wherein cellulose film is produced by preparing a polymer solution through dissolving cellulose ester in a solvent containing a prescribed organic solvent as the main component, forming a filmy object from the prepared polymer solution, and evaporating the solvent in the filmy object; the residual amount of the organic solvent is reduced while the film quality is not degraded, and the production efficiency is degraded to a least possible extent; a poor solvent, highest in boiling point among the materials contained in the solvent, is added in the content ranging from 0.1 wt % to 1.0 wt %, taking the total amount of the solvent in the prepared polymer solution to be 100 wt %; and the solubility of cellulose ester in the poor solvent is inferior to the solubility of the cellulose ester in the organic solvent which is the main component of the solvent.

Production method of cellulose film, cellulose film, protective film for polarizing plate, optical functional film, polarizing plate, and liquid crystal display

In order to produce a cellulose ester film constructed of a front layer, an intermittent layer and a rear layer, a dope solution is doped on a supporter. In at least one of the front layer and the rear layer, a mass ratio of a cotton linter to a wood pulp (cotton linter/wood pulp) is between 5/95 and 0/100, and a solvent of the dope contains more than 15 wt. % alcohols and hydrocarbons whose carbon number each is 1&#x2013;10. Further, a ratio of a solid content density of a solution for forming the front layer and the rear layer to a solid density of a solution for forming the intermittent layer is less than 0.9 wt. %, and a total thickness of the solutions for front and rear layers is more than 5% of the dope ribbon.

Method for producing of cellulose ester film

A pipe for supplying a dope to a co-casting die consists of a gooseneck portion connected to a feed block of the co-casting die, and a straight pipe portion connected to the gooseneck portion. The gooseneck portion has a radius of curvature of 50 mm to 400 mm, and the straight pipe portion forms an angle of 0 to 20 degrees to the horizontal plane. Venting valves are opened up at the beginning of dope feeding. and are closed to some extent as the dope comes out. After the air is completely vented out, the venting valves are completely closed. Thereby, an air collection is completely let out from the pipe, a plastic web discharged from die lips of the co-casting die would not contain any air bubbles, it is prevented that the web splashes to put on the die lips, causing streaks on the produced film.

Film casting apparatus for use in manufacturing a protective film for a polarizing plate

In the transparent film of optical application or the support for photographic material produced by a solution film forming method, the polymer resin film on which any coating unevenness does not occur even when a functional layer is coated on the film surface and the manufacturing method for the film are proposed. To be concrete, a polymer resin film produced by the solution film forming method characterized by that the pitch a [cm] of the periodic thickness unevenness of web longitudinal direction and a thickness unevenness factor d [%] satisfy formula (1) described below.&#x2212;0.910.6+1.01&#x2003;&#x2003;(1) The manufacturing method using said formula is also proposed.

Polymer resin film and its production

In the transparent film of optical application or the support for photographic material produced by a solution film forming method, the polymer resin film on which any coating unevenness does not occur even when a functional layer is coated on the film surface and the manufacturing method for the film are proposed. To be concrete, a polymer resin film produced by the solution film forming method characterized by that the pitch a [cm] of the periodic thickness unevenness of web longitudinal direction and a thickness unevenness factor d [%] satisfy formula (1) described below.0.46&#x2212;0.910.6&#x2003;&#x2003;(1) The manufacturing method using said formula is also proposed.

A process and apparatus for solvent casting which comprises, casting a polymer solution onto a casting support, cooling the polymer solution to gelatinize on the casting support to form web, stripping off the web from the casting support, thrusting side edges of the web into pins of a pin tenter by an inserting device, and drying the web while conveying the web with carrying the side edges of the web by the pin tenter, wherein the inserting device is cooled so that the surface temperature of the web in contact with the inserting device does not exceed a gelation temperature of the polymer solution are proposed. The present invention makes surely to convey the web without slipping from the pin tenters even when the pin tenters convey the web at a high speed. As a result, the productivity of film can be improved.

Solvent casting process and apparatus therefor

Film formation method capable of preventing fluctuation of ribbon

A heating furnace tube, a method of using the same and a method of manufacturing the same which have been developed with a view to eliminating inconveniences occurring when a carbon-containing fluid is made to flow in the heating furnace tube. The heating furnace tube which comprises a rare earth oxide particle distributed iron alloy containing 17-26 wt. % of Cr and 2-6 wt. % of Al. The method of manufacturing this heating furnace tube which comprises the steps of forming or inserting an insert metal on or into at least one of a joint end portion of one heating furnace tube element and that of the other heating furnace tube element, bringing these two joint end portions into pressure contact with each other directly or via an intermediate member, and diffusion welding the two heating furnace tube elements to each other by heating the insert metal.

Heating furnace tube and method of manufacturing the same

This invention relates to a solution casting process capable of decreasing uneven coating of a functional layer upon applying the functional layer onto a film surface, which comprises casting a solution of polymer dissolved in organic solvent into a film by extruding from a die onto a support, wherein the length of the film from the die opening to the landing of the film on the support is controlled to 3 to 40 mm.

Solution casting process

A clamp-type isolating pipe joint is disclosed, which can connect pipes by providing insulation between them, is easy to assemble and disassemble, has high reliability and allows easy replacement of parts and is inexpensive to manufacture and install. The joint comprises hubs weldable to connectable pipes, a seal ring interposed between butted surfaces of the hubs and a clamp disposed around the circumferences of the hubs for clamping itself with bolts in the radial direction of the hubs to be fixed as insulated from each other. The clamp and hubs are insulated by interposing between them a metal plate with an insulating resin coat formed thereon. Insulation layers are also provided between the seal ring and the hubs.

Clamp-type pipe joint

A thermal insulating supporting device for piping has a supporting member which is formed by cutting to specified dimensions a long member which has a specified cross-sectional shape, and which is made of a resin material that has heat-insulating properties and sufficient strength to support piping. The supporting device supports piping by connecting the supporting member to a supporting frame which is fastened to the piping.

Growing community of inventors

Kanagawa, Japan

Toshikazu Nakamura