Hitachi Metals, Ltd.

Nippon Hoso' Kyokai

Other

Matsushita Electric Industrial Co., Ltd.

Honda Motor Co., Ltd.

Mitsumi Electric Company Ltd.

Proterial, Ltd.

Sumitomo Precision Products Co., Ltd.

The Society of Japanese Aerospace Companies

Hitachi, Ltd.

Denso Corporation

Ngk Spark Plug Company, Limited

Agency of Industrial Science and Technology

Babcock-hitachi Kabushiki Kaisha

Mitsubishi Hitachi Power Systems, Ltd.

Toshihiro Uehara

Takehiro Ohno

Rikizo Watanabe

Katsuhiko Ohishi

Akihiro Toji

Akira Nakamura

Kenji Machida

Etsuo Fujita

Hiroshi Yakuwa

Chuya Aoki

Matsuho Miyasaka

Junichi Nishida

Shuhei Nakahama

Naoto Hayashi

Junji Numazawa

Yasuhiko Shinjo

Kunichika Kubota

Yusei Nishimoto

Tatsuya Kurioka

Toshiaki Nonomura

Nobuhito Nakama

Yoshinobu Oba

Morio Kondo

Shigeru Sawada

Yoshihiro Minagi

Hotaka Minaguchi

Seiichi Namba

Kazutoshi Mutou

Shinya Imano

Kenichi Inoue

Koji Sato

Hiroyuki Doi

Osamu Yoshimoto

Yasunori Kawakami

Masahide Kawabata

Kunio Suesada

Katsuaki Sato

Takehito Kuno

Tomonori Kanemaru

Mikio Fujiwara

Shiro Tsuji

Shuichi Nakamura

Tomo-o Tanaka

Haruo Okuda

Kazuhiro Yamamura

Keigo Majima

Norio Hasegawa

Taiji Yokoyama

Sigekazu Togashi

Tadashi Nakayama

Katsuhiko Tominaga

Shigenori Tanaka

Takashi Sato

Shoichi Nakaya

Shogo Momono

Satoshi Kubota

Nobutaka Yasuda

Motoi Yamaguchi

Gang Bao

Kenji Yokoyama

Hideo Oshima

Naoya Sato

Tomo-O Tanaka

Ichiro Kishigami

A martensitic stainless steel for a fuel injection member contains, in mass %, at least 0.35% and less than 0.50% of C, more than 0.20% and at most 0.40% of Si, 0.2-0.4% of Mn, 0.25% or less of Ni, 15.0-17.0% of Cr, more than 2.0% and at most 3.0% of Mo, 0.1-0.3% of W, 0.001-0.003% of B, and at least 0.15% and less than 0.20% of N, with the remainder comprising Fe and inevitable impurities, which include 0-0.025% of P, 0-0.005% of S, 0-0.2% of Cu, 0-0.05% of Al, 0-0.02% of Ti, 0-0.02% of Nb, 0-0.15% of V, 0-0.003% of O, and 0-0.001% of H.

Martensitic stainless steel for fuel injection member and fuel injection member using same

Provided is a metal gasket including, expressed in mass%, C: 0.10% or less, Si: 1.0% or less, Mn: 2.0% or less, P: 0.04% or less (including 0%), S: 0.01% or less (including 0%), Ni: 25.0-60.0%, Cr: 10.0-20.0%, either Mo or W alone, or both Mo+W/2: 0.05-5.0%, Al: more than 0.8% to 3.0% or less, Ti: 1.5-4.0%, Nb: 0.05-2.5%, V: 1.0% or less (including 0%), B: 0.001-0.015%, Mg: 0.0005-0.01%, S/Mg: 1.0 or less, N: 0.01% or less (including 0%), and O: 0.005% or less (including 0%), with the remainder being Fe and unavoidable impurities. The metal gasket has a metal structure in which a precipitate γ′ phase having an average equivalent circle diameter of 25 nm or larger is not present within the austenite base.

Metal gasket and production method therefor

Provided is a metal gasket including, expressed in mass %, C: 0.10% or less, Si: 1.0% or less, Mn: 2.0% or less, P: 0.04% or less (including 0%), S: 0.01% or less (including 0%), Ni: 25.0-60.0%, Cr: 10.0-20.0%, either Mo or W alone, or both Mo+W/2:0.05-5.0%, Al: more than 0.8% to 3.0% or less, Ti: 1.5-4.0%, Nb: 0.05-2.5%, V: 1.0% or less (including 0%), B: 0.001-0.015%, Mg: 0.0005-0.01%, S/Mg: 1.0 or less, N: 0.01% or less (including 0%), and O: 0.005%) or less (including 0%), with the remainder being Fe and unavoidable impurities. The metal gasket has a metal structure in which a precipitate &#x3b3;' phase having an average equivalent circle diameter of 25 nm or larger is not present within the austenite base.

The present invention provides a Ni-based alloy that is hot-workable and exhibits an excellent high-temperature strength, and provides a heat-resistant plate material using the same. This Ni-based alloy is composed of, by mass, C: 0.002 to 0.10%, Si: less than 1.0%, Mn: up to 1.0%, P: up to 0.04% (including 0%), S: up to 0.01% (including 0%), Cr: 15.0 to 25.0%, Co: 0.1 to 18.0%, Mo: not less than 2.0% and less than 4.0%, Al: 3.0 to 5.0%, Ti: not less than 0.01% and less than 0.5%, Zr: 0.01 to 0.1%, B: 0.001 to 0.015%, Fe: up to 3.0%, Mg or Mg+0.6&#xd7;Ca: 0.0005 to 0.01%, N: up to 0.01% (including 0%), O: up to 0.005% (including 0%), and the balance of Ni with inevitable impurities, S/Mg or S/(Mg+0.6&#xd7;Ca) being up to 1.0, and a G value represented by the following formula (1) being 30 to 45.=7+0.11Cr+8.23Al+4.66Ti&#x2212;0.13(Ni+Co)&#x2003;&#x2003;(1)

Ni-based alloy and heat-resistant sheet material obtained using same

There is provided a steel for solid oxide fuel cells which contains more than 0 and not more than 0.05 mass % of C, 0.05 mass % or less of N, 0.01 mass % or less of O, 0.2 mass % or less of Al, 0.15 mass % or less of Si, 0.1 to 1.0 mass % of Mn, 20.0 to 25.0 mass % of Cr, more than 0 mass % and not more than 1.0 mass % of Ni, 0.02 to 0.12 mass % of La, 0.1 to 0.5 mass % of Zr, 0.15 to 0.5 mass % of La+Zr, and Fe and impurities as a remainder. The following relational formula is satisfied, and an Fe and Zr-containing intermetallic compound viewed in a ferrite matrix is 1.1 % or less in terms of a visual field area ratio5(7C+6N)/(7&#x2212;4(7C+6N))&#x2264;Zr&#x2264;41(7C+6N)/(7+66(7C+6N)).

Steel for solid oxide fuel cells and manufacturing method thereof

A low thermal expansion superalloy is composed of, in mass %, 0.1% or less of C, 0.1-1.0% of Si, 1.0% or less of Mn, 25-32% of Ni, more than 18% but less than 24% of Co, more than 0.25% but 1.0% or less of Al, 0.5-1.5% of Ti, more than 2.1% but less than 3.0% of Nb, 0.001-0.01% of B and 0.0005-0.01% of Mg, with the balance of Fe and unavoidable impurities, while satisfying Mg/S&#x2265;1, 52.9&#x2264;1.235Ni+Co&#x3c;55.8%, (Al+Ti+Nb) is 3.5-5.5%, and the F value is 8% or less. In the superalloy, a granular intermetallic compound containing Si, Nb, and Ni alone or in a total amount of 36 mass % or more is precipitated at a grain boundary of an austenite matrix, and an intermetallic compound including a larger concentration of Ni, Al, Ti, and Nb and having 50 nm or smaller of an average diameter is precipitated in the austenite matrix.

Low thermal expansion superalloy and manufacturing method thereof

A high-strength Ni-base alloy having favorable corrosion resistance, high strength, and high ductility, around room temperature is provided. A high-strength Ni-base alloy includes: in % by mass, less than 0.01% of C, not more than 0.5% of Si, not more than 0.5% of Mn, 15 to 25% of Cr. 1.0 to 5.0% of Mo or Mo+0.5W, 0.2 to 0.8% of Al, 1.0 to 2.0% of Ti, 3.00 to 3.80% of Nb, not more than 30% of Fe, and 0.0007 to 0.010% of Mg; Ni; and impurities. A value represented by Mg/S is not less than 0.7, and an A value is not less than 0.015 and less than 0.027, the A value being represented by A value=Al/(Al+1.77(Ti&#x2212;1.36C)+3.44(Nb&#x2212;5.1C)).

High-strength Ni-base alloy

An electrode material for at least one of a center electrode () and a ground electrode () provided with a chip () for use in a spark plug (). The electrode material contains Ni as a principal component, and has a Si content of from 0.50% to 1.0% by mass, an Al content of from 0.2% to 2.0% by mass, a Cr content of from 12% to 34% by mass, a rare-earth element or the like content of from 0.03% to 0.2% by mass, a Fe content of more than 0% but not more than 20% by mass, a C content of not more than 0.10% by mass, and a Mn content of not more than 1.0% by mass. The total content of Si and Al is not less than 0.80% by mass, and less than one tenth of the Cr content.

Electrode material and spark plug

Disclosed is steel for a solid oxide fuel cell, which has excellent oxidation resistance, reduces Cr evaporation, has good electrical conductivity and has a thermal expansion coefficient similar to that of a ceramic component such as an electrolyte or an electrode. Specifically disclosed is steel for solid oxide fuel cells, which has excellent oxidation resistance and contains, in mass %, 0.1% or less of C, 0.2% or less of Al, 0.2% or less of Si, 0.4% or less of Mn, 16.0-28.0% of Cr, 1.5% or less of Ni, 1.0% or less of REM and/or Zr in total, 1.0-3.0% of W, and more than 0.2% but 4.0% or less of Cu, with the balance made up of Fe and unavoidable impurities.

Steel for solid oxide fuel cell having excellent oxidation resistance

An electrode material to be used for producing an earth electrode of a spark plug has a chemical composition of 0.3 to 3.0 mass % of Si, 0.01 to 0.3 mass % of one or more elements selected from the group consisting of Y and rare earth elements, not more than 0.5 mass % of Ti, not more than 1.2 mass % of Fe, and one or both of not more than 0.20 mass % of Ca and not more than 0.08 mass % of Mg. The electrode material further contains C, Mn, Cr, Al, N, S, a remainder Ni, and incidental impurities. In a total content of C, Mn, Cr, Al, N and S, C is not more than 0.1 mass %, Mn is less than 0.5 mass %, Cr is less than 0.5 mass %, Al is not more than 0.3 mass %, N is not more than 0.05 mass %, and S is not more than 0.03 mass %.

Electrode material for electrode of spark plug

Provided is an Ni-base alloy excellent in strength, ductility and other properties through the resolution of micro-segregation. Also provided is a process for manufacturing an Ni-base alloy containing by mass C:0.15% or less, Si:1% or less, Mn:1% or less, Cr:10 to 24%, Mo+(1/2)W (where Mo may be contained either alone or as an essential component):5 to 17%, Al:0.5 to 1.8%, Ti:1 to 2.5%, Mg:0.02% or less, and either B:0.02% or less and/or Zr:0.2% or less at an Al/(Al+0.56Ti) ratio of 0.45 to 0.70 with the balance consisting of Ni and impurities, which comprises subjecting, at least one time, an Ni-base alloy material which is prepared by vacuum melting and has the above composition to homogenization heat treatment at 1160 to 1220&#xb0; C. for 1 to 100 hours. The Mo segregation ratio of the alloy is controlled to 1 to 1.17 by the homogenization heat treatment.

Process for manufacturing Ni-base alloy and Ni-base alloy

Provided is a maraging steel strip which has such a composition that can reduce the content of TiN acting as the starting point of fatigue fracture in a high-cycle region, and the bending fatigue strength of which has been improved by the precipitation hardening effect yielded by precipitating coherent nitrides in the nitrided structure. A maraging steel strip produced by nitriding a managing steel which contains by mass, C: 0.01% or less, Si: 0.1% or less, Mn: 0.1% or less, P: 0.01% or less, S: 0.005% or less, Ni: 8.0 to 22.0%, Cr: 0.1 to 8.0%, Mo: 2.0 to 10.0%, Co: 2.0 to 20.0%, Ti: 0.1% or less, Al: 2.5% or less, N: 0.03% or less, and O: 0.005% or less, with the balance being Fe and unavoidable impurities, wherein Baker-Nutting orientation relationship with an orientation difference within 10&#xb0; exists between the Cr nitride precipitated in the nitrided layer and the matrix martensite.

Maraging steel strip

To provide an inexpensive heat-resisting steel for engine valves by causing Fe-based heat-resisting steel to exhibit high temperature strength not inferior to that of Ni-based heat-resisting steel. A heat-resisting steel for engine valves excellent in high temperature strength containing, in % by mass, C: 0.20 to 0.50%, Si: 1.0% or less, Mn: 5.0% or less, P: 0.1 to 0.5%, Ni: 8.0 to 15.0%, Cr: 16.0 to 25.0%, Mo: 2.0 to 5.0%, Cu: 0.5% or less, Nb: 1.0% or less (including 0%), W: 8.0% or less (including 0%), N: 0.02 to 0.2%, B: 0.01% or less, and remnants of Fe and impurities, wherein the heat-resisting steel for engine valves satisfies formulae below:442P(%)+12Mo(%)+5W(%)+7Nb(%)+328N(%)+171&#x2267;300&#x2003;&#x2003;Formula (1)&#x2212;38.13P(%)+1.06Mo(%)+0.13W(%)+9.64Nb(%)+13.52N(%)+4.83&#x2267;0.12&#x2003;&#x2003;Formula (2).

Heat-resisting steel for engine valves excellent in high temperature strength

A piston ring material is provided which retains excellent mechanical properties and processability, which are required of piston ring materials, and has wearing resistance and scuffing resistance, which are sliding properties required of piston rings. The piston ring material, which is for use in internal combustion engines, contains, in terms of mass %, 0.3-0.8% carbon, 0.1-3.0% silicon, 0.1-3.0% manganese, 0.01-0.3% sulfur, 0.1-2.0% chromium, and 0.05-2.0% the sum of titanium and/or zirconium, with the remainder being iron and incidental impurities. The titanium and/or zirconium contained in the piston ring material and the sulfur contained therein satisfy the following relationship. [Ti (%)+&#xbd;Zr (%)]/S (%)&#x2266;5.0 Preferably, the material may contain one or more members selected from up to 1.0% copper, less than 3.0% molybdenum, up to 1.0% aluminum, and less than 2.0% nickel, in terms of mass %.

Piston ring material for internal combustion engine

Disclosed is a low-thermal-expansion Ni-based super-heat-resistant alloy for a boiler, which has excellent high-temperature strength. The alloy can be welded without the need of carrying out any aging treatment. The alloy has a Vickers hardness value of 240 or less. The alloy comprises (by mass) C in an amount of 0.2% or less, Si in an amount of 0.5% or less, Mn in an amount of 0.5% or less, Cr in an amount of 10 to 24%, one or both of Mo and W in such an amount satisfying the following formula: Mo+0.5 W=5 to 17%, Al in an amount of 0.5 to 2.0%, Ti in an amount of 1.0 to 3.0%, Fe in an amount of 10% or less, and one or both of B and Zr in an amount of 0.02% or less (excluding 0%) for B and in an amount of 0.2% or less (excluding 0%) for Zr, with the remainder being 48 to 78% of Ni and unavoidable impurities.

Low-thermal-expansion Ni-based super-heat-resistant alloy for boiler and having excellent high-temperature strength, and boiler component and boiler component production method using the same

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Yasugi, Japan

Toshihiro Uehara