Canon Kabushiki Kaisha

Toshifumi Mori

Kenji Aoki

Atsushi Tani

Shuntaro Watanabe

Tetsuya Kinumatsu

Takashige Kasuya

Takaaki Kaya

Yoshihiro Nakagawa

Yusuke Kosaki

Ayako Okamoto

Koichi Suzuki

Akira Tsuboyama

Sakae Suda

Satoru Shiobara

Kazumichi Nakahama

Kenichi Ikari

Noritaka Toyoizumi

Shinnosuke Koji

Shohei Fukuya

A method of producing a toner including the steps of: mixing resin fine particles, an organic solvent, and a resin R with a dispersion medium containing carbon dioxide, to prepare a dispersion of resin R-containing droplets; and removing the organic solvent by flowing carbon dioxide, wherein the resin fine particles contain one or more resins that have a partial structure A, B, and C, and are soluble in chloroform; the SP value of the partial structure A, the resin R, and the partial structure B satisfy particular relationships; a resin A constituted of the partial structure A and a resin B constituted of the partial structure B are soluble in the organic solvent; and a resin C constituted of the partial structure C is insoluble in the organic solvent.

Resin fine particles, method of producing resin fine particles, method of producing resin particles, and method of producing toner

A method for producing a toner particle include: (a) mixing a binder resin A, resin fine particles containing a resin B, a resin C, an organic solvent, and carbon dioxide, thereby forming a droplet of a resin solution containing the binder resin A, covered with the resin fine particles; (b) applying a pressure by introducing carbon dioxide, thereby precipitating the resin C at the surface of the droplet; and (c) passing carbon dioxide so as to remove the organic solvent from the droplet with the carbon dioxide. The resin C has an organic polysiloxane structure and a weight average molecular weight of 50,000 to 500,000. The ratio of the weight average molecular weight to the number average molecular weight of the resin C is not more than 5.0. The proportion of the resin C to the rein fine particles is 5.0% by mass to 50.0% by mass.

Methods for producing toner particle and producing resin particle

A toner includes toner particles which contain a binder resin, a colorant, a wax, and a resin A having an organic polysiloxane structure; the amount of Si atoms of the toner particles is 4.5 to 10.0; in an analysis of a cross-section of each toner particle, in a surface layer region R from the periphery of the cross-section of the toner particle to the inside at a distance of 10.0% of the particle diameter in the cross-section of the toner particle, the content of Si atoms derived from the organic polysiloxane structure is 90.0% or more with respect to the total amount of Si atoms contained in the toner particle; and in a line analysis along a straight line between the periphery of the surface layer region R and a gravity center of the cross-section, an intensity count of Si atoms in the toner particle satisfies formula Si&#x3e;Si&#x3e;Si&#x3e;Si&#x2265;0.

Toner and method for manufacturing the same

Provided is a toner containing toner particles, each of which includes a binder resin containing a polyester as a main component, a colorant, and a wax, in which the binder resin includes a block polymer in which a segment capable of forming a crystalline structure and a segment incapable of forming a crystalline structure are bonded, the toner has a maximum endothermic peak from the binder resin, as determined by differential scanning calorimetry measurement, with a peak temperature in a specific range and with an endothermic quantity in a specific range, and the wax is an ester wax having a functionality of 3 or more.

Toner

A method for producing a toner that comprises toner particles, each of which comprises a binder resin, which comprises a resin (A) capable of forming a crystalline structure, and a colorant, the method including: a pressure holding step of, after preparing toner particles, holding the toner particles for 5 minutes or more at a pressure of 2.0 MPa or more under conditions of a temperature T1 (&#xb0; C.) represented by formula (1):20&#x2266;1&#x2266;2&#x2003;&#x2003;(1)(wherein, Tp2 represents the onset temperature of the maximum endothermic peak derived from the resin (A)), wherein a peak temperature Tp1 of the maximum endothermic peak derived from the resin (A) during the first temperature rise of the toner particles as determined by differential scanning calorimetric measurement is 50&#xb0; C. to 90&#xb0; C.

Toner production method

A toner has toner particles containing a binder resin that comprises a block polymer as a main component, obtained by chemically bonding a crystalline polyester resin with an amorphous polyurethane resin, wherein the binder resin has a specific content of a crystalline polyester resin component, and has a concentration of ester bonds derived from the crystalline polyester resin component of not more than 5.2 mmol/g, and The maximum value Eof the flexural elasticity modulus E in a three-point bending test on the toner and the strain energy u for the toner satisfy specific values.

A toner having good low-temperature fixability, charge stability, environmental stability, and durability and capable of stably producing high-quality images for a long time is provided. The toner includes a toner particle having a core-shell structure constituted of a core and a shell phase. The core contains a binder resin, a colorant, and wax, and the shell phase contains a resin A. The resin A is a comb polymer including a main chain portion (X), a side chain portion (Y), and a side chain portion (Z). The main chain portion (X) is a vinyl polymer, the side chain portion (Y) has an aliphatic polyester structure and has an ester group concentration of a polyester segment of 6.5 mmol/g or less, and the side chain portion (Z) has an organic polysiloxane structure and has an average number of Si&#x2014;O bond repeating units of a siloxane segment of 2 or more and 100 or less.

Provided is a toner that is excellent in terms of low-temperature fixability and hot offset resistance, has a wide fixing temperature range from a low-temperature region to a high-temperature region, and has high thermal storability. When the toner is measured with a capillary rheometer,

Toner and method for producing toner

Provided is a toner comprising toner particles, wherein each of the toner particles has a core-shell structure composed of a core and a shell phase formed on the core, the shell phase contains a resin (B), and the core contains a binder resin (A), a colorant and a wax, wherein the toner particles contain the resin (B) in a specific amount with respect to the core, and wherein the solubility parameter (SP value) of the binder resin (A) is denoted by SP(A), the SP value of the resin (B) is denoted by SP(B), the SP value of a repeating unit with the smallest SP value from among repeating units constituting the resin (B) is denoted by SP(C), and the SP value of the wax is denoted by SP(W), each of the SP(A), SP(B), SP(C) and SP(W) satisfy specific relationships.

Provided is a toner having an excellent low-temperature fixability and hot offset resistance, a broad fixing temperature latitude in low-temperature areas to high-temperature areas, and a high heat-resistant storage stability. The toner includes toner particles having a core-shell structure in which a shell phase containing a resin A is formed on a core containing a binder resin, a colorant and a wax. In measurement of resin A by a differential scanning calorimetry (DSC), the peak temperature TpA (&#xb0; C.) of a maximum endothermic peak in the first temperature rise is at least 55&#xb0; C. but not more than 80&#xb0; C. In measurement of a viscoelasticity of resin A, the loss elastic modulus at TpA&#x2212;10 (&#xb0; C.) is at least 1&#xd7;10Pa but not more than 1&#xd7;10Pa. In measurement of the viscoelasticity of resin A, the loss elastic moduli at TpA (&#xb0; C.), TpA+10 (&#xb0; C.) and TpA+25 (&#xb0; C.) satisfy specific conditions.

Provided is a toner comprising a toner particle having a core-shell structure in which a shell phase containing a resin A is formed on a core that contains a binder resin, a colorant and a wax, wherein the resin A is a vinyl resin prepared by copolymerizing a vinyl monomer X that has an organopolysiloxane structure and a vinyl monomer Y that has a polyester segment capable of forming a crystalline structure; the content of the vinyl monomer X in a total monomer used for the copolymerization is in a particular range; the toner particle contains resin A in a particular proportion; and the binder resin contains a crystalline resin.

An organic electroluminescent display apparatus having organic electroluminescent devices each of which is excellent in color reproducibility and has high emission efficiency in which green organic electroluminescent devices each have a delayed fluorescent material and a microcavity, and the hole transport layer of each of the devices has the same thickness as that of the hole transport layer of each of blue organic electroluminescent devices.

Organic electroluminescent display apparatus

A high-efficiency, white organic electroluminescent device has such a structure that its emission layer is obtained by laminating sub-emission layers of red, green, and blue, respectively. The green sub-emission layer contacting a hole transport layer has a delayed fluorescent material, and the red sub-emission layer has a phosphorescent light emitting material.

White organic electroluminescent device

Provided is an organic EL display apparatus including an organic EL device having a delayed fluorescence material which has good internal quantum efficiency and an organic EL device having a phosphorescent material. A soaking unit is provided in a plane in which the organic EL devices are provided.

Growing community of inventors

Tokyo, Japan

Toshifumi Mori