Nippon Shokubai Co., Ltd.

Oji Paper Co., Ltd.

Nippon Shokubai Kagaku Kogyo Co., Ltd.

Toshiaki Matsunaga

Hiroyuki Ikeuchi

Masatoshi Yoshida

Fumihide Tamura

Taketo Toba

Kazuo Takei

Masuji Izubayashi

Teruo Kikuta

Yohei Murakami

Shiro Nakano

Akira Hattori

Hidetoshi Hatta

Kohei Hori

Tsuneo Tsubakimoto

Takahiro Aoyama

Mitsuo Nakazaki

Akikazu Banba

Coating for water blocking agents

The present invention has its object to provide a friction reducing coating for engineering works, and, a soil adhesion-preventing sheet pile or steel tubular pipe wherein the above-mentioned friction reducing coating for engineering works applied thereto in advance, and, a soil adhesion-preventing construction method which comprises using the above-mentioned friction reducing coating for engineering works and/or the above-mentioned soil adhesion-preventing sheet pile or steel tubular pipe and further provide a negative friction cut construction method for foundation structures which comprises using the above friction reducing coating for engineering works and thus can cut the friction between a foundation structure after laying underground and the surrounding ground and reduce the influences of changes in the surrounding ground on the foundation structure as well as a caisson or pipe jacking construction method which comprises using the above friction reducing coating for engineering works and can reduce the friction between the substrate and soil while minimizing the influences on the surrounding ground and thus can markedly improve the speed and efficiency of construction work. A friction reducing coating for engineering works comprising a water-absorbing resin (a), a hydrophilic binder resin (b) and a solvent (c) as essential components, wherein said hydrophilic binder resin (b) has an acid value of 40 mg KOH/g to 500 mg KOH/g.

Friction reducing coating for engineering works, and sheet pile, steel tubular pipe and construction method

Disclosed herein are crosslinked spherical fine particles having good toughness, elastic properties, and chemical properties, and a process for producing the same, said fine particles being obtained by radical polymerization in the suspended state of a component [M] capable of radical polymerization containing a vinyl group-containing compound (V) capable of radical polymerization which is obtained by reaction of (a) a selected polyol, (b) an isocyanate group-containing compound, and (c) an active hydrogen-containing vinyl monomer capable of radical polymerization. Also disclosed herein are the secondary products of the crosslinked spherical fine particles, which include a coating composition and its derivatives (such as filmlike article, sheetlike article, adhesive filmlike article, and adhesive sheetlike article) and a peelable pressure-sensitive adhesive and peelable pressure-sensitive adhesive article.

Coating compositions containing crosslinked spherical fine particles

This invention provides a production process by which a polymer having a hydroxyl group at both terminals can be easily obtained with a cheap price and good efficiency from a wide field of vinyl-based monomers including polar ones. In this process, a polymerization reaction of a vinyl-based monomer (a) is performed by using hydrogen peroxide (b) and, on this occasion, either one or both of a hydrogen peroxide-decomposing accelerator (c) and an amphiphilic compound (d) are further used and any component other than the (a), (b), (c) and (d) is not substantially used.

Process for producing polymer having hydroxyl group at both terminals

This invention provides a process by which a polymer having a hydroxyl group at both terminals can be easily obtained with a cheap price and good efficiency from a wide field of vinyl-based monomers including polar ones. The process is arranged in such a manner that the polymerization of a vinyl-based monomer (a) is performed in the presence of an alcohol (b) having no addition-polymerization reactivity by using an initiator (c) consisting essentially of a peroxide and, on this occasion, at least one of catalysts (d) selected from a group consisting of an organic sulfonic acid compound having no addition-polymerization reactivity and an inorganic acid is further used and a reactor does not substantially contain any component other than the (a), (b), (c) and (d).

Process for producing polymer

Process for producing polymer having hydroxyl groups at both terminals

The present invention yields a coating film excellent in adhesion, water resistance, solvent resistance and durability. A compound having a carboxyl group and a long-chain alkylthio group or a salt thereof is used as an emulsifier and emulsion polymerization is carried out using a polymerizable monomer or monomers having, within their molecule, a group reactive with a carboxyl group as raw materials for emulsion polymerization, whereby the resin produced by emulsion polymerization and the emulsifier react with each other efficiently on the occasion of film formation and form a crosslinked structure. When a compound having a polymerizable unsaturated group in addition to the carboxyl group and long-chain alkylthio group or a salt thereof is used as the emulsifier, not only the above-mentioned crosslinked structure is formed but also the polymerizable unsaturated group in the emulsifier will react with the unsaturated group in the polymerizable monomer or monomers in the manner of grafting. As a result, the compatibility between the emulsifier and the emulsion-polymerized resin is improved.

Aqueous crosslinkable resin dispersions, method of their production and

A compound having a carboxy group and a long-chain alkylthio group and/or a salt thereof is used as an emulsifier and, on the other hand, emulsion polymerization is carried out using a polymerizable monomer or monomers having, within their molecule, a group reactive with a carboxyl group as raw materials for emulsion polymerization, whereby the resin produced by emulsion polymerization and the emulsifier react with each other efficiently on the occasion of film formation and form a crosslinked structure. When a compound having a polymerizable unsaturated group in addition to the carboxyl group and long-chain alkylthio group and/or a salt thereof is used as the emulsifier, not only the above-mentioned crosslinked structure is formed but also the polymerizable unsaturated group in the emulsifier will react with the unsaturated group in the polymerizable monomer or monomers in the manner of grafting. As a result, the compatibility between the emulsifier and the emulsion-polymerized resin is improved.

Heat-sensitive recording paper having an overcoat layer formed from an

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Suita, Japan

Toshiaki Matsunaga