Tanaka Kikinzoku Kogyo K.k.

Catalytica, Inc.

Tanaka Kikinzoku K.k.

Toru Shoji

Ralph Albert Dalla Betta

Kazunori Tsurumi

Nobuyasu Ezawa

David K Yee

Scott A Magno

Yoshinobu Watanabe

Robert L Garten

Seiichiro Tanaka

Yoshikazu Takagi

Soichi Hitomi

Sarento George Nickolas

Ralph Dalla Betta

Hideo Segawa

Seiji Takeishi

Ralph A Della Betta

Ralph A Betta

Thomas Rostrup-Nielsen

Fabio H Ribeiro

A manufacturing method for an oxide-dispersed alloy wherein dispersed particles consisting of oxides of one or two or more additive metals are dispersed in a matrix metal, comprising the steps of (a) manufacturing alloy powder or an alloy wire rod consisting of the matrix metal and the additive metal; (b) oxidizing the additive metal in the alloy powder by water to form dispersed particles by introducing the alloy powder or alloy wire rod into a high-energy ball mill with water and by making agitation; and (c) moldedly solidifying the alloy powder or alloy wire rod after oxidation. The present invention is especially useful in manufacturing oxide-dispersed alloys in which the free energy of oxide formation of the matrix metal is higher than water standard free energy of formation, and the free energy of oxide formation of the additive metal is lower than water standard free energy of formation.

Manufacturing method for oxide dispersed alloy

This invention aims to provide a process for producing an oxide-dispersion strengthened platinum material which allows zirconium oxide to be more finely dispersed in a platinum material, and to further improve creep strength in an oxide-dispersion strengthened platinum material. This invention provides a process for producing an oxide-dispersion strengthened platinum material where zirconium oxide is finely dispersed in platinum, wherein powdered platinum is poured into water to prepare a platinum suspension; a zirconium nitrate solution and an urea solution are added in the platinum suspension for adjusting the suspension to a given pH to precipitate zirconium hydroxide and thus to form a zirconium hydroxide carrying platinum; the zirconium hydroxide carrying platinum is collected, which is then formed into a molding; the molding is sintered and forged under the conditions whereby secondary recrystallization growth in a platinum crystal proceeds, to form a platinum ingot; and the platinum ingot is cold-rolled in a processing rate of at least 70% and then the product is thermally recrystallized.

Process for producing oxide-dispersion strengthened platinum material

Platinum material reinforced by oxide-dispersion and process for producing the same

This invention relates to an electrically-heated catalyst (EHC) and a start-up method of a gas turbine engine for combusting a hydrocarbonaceous fuel/oxygen-containing gas mixture using this electrically-heated catalyst. The catalytic structure is electrically heated to a predetermined temperature prior to start up of the turbine so as to reduce emissions during the start-up of the system. The EHC unit is a stacked or spirally wound layering of flat and corrugated thin metal foils which forms a plurality of axially-extending, longitudinal channels. The channels are preferably coated on one surface with a catalytic material, leaving the other surface free from the reaction to act as a heat sink, making the design an IHE (integral heat exchange) catalytic unit. The preferred embodiment of the EHC has electrodes outside of the fuel/oxygen-containing mixture stream, and uses electrical power having a predetermined voltage in the range of 100 to 200 volts to heat the unit. A method for using the EHC in the start-up of a gas turbine is also disclosed wherein an electrical power is applied to heat the EHC a predetermined temperature prior to the fuel/oxygen-containing mixture being introduced and may be left on for a certain period of time after the introduction of the fuel/oxygen-containing mixture. The EHC may be maintained at the desired predetermined temperature by modulating the applied voltage. The electrical power is terminated when any one of several conditions are met including when the heat of the catalytic reaction is sufficient to maintain the catalyst at its steady-state condition or when a certain period of time has elapsed.

Electrically-heated combustion catalyst structure and method for

This invention is an improved catalyst structure and its use in highly exothermic processes like catalytic combustion. This improved catalyst structure employs integral heat exchange in an array of longitudinally disposed adjacent reaction passage-ways or channels, which are either catalyst-coated or catalyst-free, wherein the configuration of the catalyst-coated channels differs from the non-catalyst channels such that, when applied in exothermic reaction processes, such as catalytic combustion, the desired reaction is promoted in the catalytic channels and substantially limited in the non-catalyst channels. The invention further comprises an improved reaction system and process for combustion of a fuel wherein catalytic combustion using a catalyst structure employing integral heat exchange, preferably the improved structures of the invention, affords a partially-combusted, gaseous product which is passed to a homogeneous combustion zone where complete combustion is promoted by means of a flameholder.

Process and catalyst structure employing intergal heat exchange with

This invention is an improved catalyst structure and its use in highly exothermic processes like catalytic combustion. This improved catalyst structure employs integral heat exchange in an array of longitudinally disposed, adjacent reaction passage-ways or channels, which are either catalyst-coated or catalyst-free, wherein the configuration of the catalyst-coated channels differs from the non-catalyst channels such that, when applied in exothermic reaction processes, such as catalytic combustion, the desired reaction is promoted in the catalytic channels and substantially limited in the non-catalyst channels.

Catalyst structure employing integral heat exchange

This invention is both a partial combustion process in which the fuel is partially combusted using specific catalysts and catalytic structures and also a catalyst structure for use in the process. The choice of catalysts and supports solves problems in the art dealing with the stability of the overall catalyst structure and ease of catalyst operation. The catalyst structure is stable due to its comparatively low operating temperature, has a low temperature at which catalytic combustion begins, and yet is not susceptible to temperature 'runaway'. The combustion gas produced by the catalytic process typically is below the autocombustive temperature for the gas mixture; the gas may be used at that temperature, or fed to other combustion stages for ultimate use in a gas turbine, furnace, boiler, or the like.

Catalyst structure for use in a partial combustion process

A support structure for securing a catalyst structure wherein a combustion reactor has a plurality of hollow, internally cooled, elongated support members which are secured to the combustion reactor and which abut the catalyst structure to limit the axial movement of the catalytic structure. The support structure is in fluid communication with a cooling medium which maintains the support structure at a temperature at which its strength properties are retained.

Cooled support structure for a catalyst

This invention is a catalyst comprising palladium on a support containing zirconium and a partial combustion process in which the fuel is partially combusted using that catalyst. The choice of catalysts and supports solves a problem dealing with the long term stability of palladium as a partial combustion catalyst. The catalyst structure is stable in operation, has a comparatively low operating temperature, has a low temperature a which oxidation begins, and yet is not susceptible to temperature 'runaway'. The combustion gas produced by the catalytic process typically is at a temperature below the autocombustive temperature and may be used at that temperature or it may be fed to other combustion stages for further use in a gas turbine, furnace, boiler, or the like.

Partial combustion catalyst of palladium on a zirconia support and a

Partial combustion process and a catalyst structure for use in the

This invention is a catalyst comprising palladium on a support containing zirconium and a partial combustion process in which the fuel is partially combusted using that catalyst. The choice of catalysts and supports solves a problem dealing with the long term stability of palladium as a partial combustion catalyst. The catalyst structure is stable in operation, has a comparatively low operating temperature, has a low temperature at which oxidation begins, and yet is not susceptible to temperature 'runaway'. The combustion gas produced by the catalytic process typically is at a temperature below the autocombustive temperature and may be used at that temperature or it may be fed to other combustion stages for further use in a gas turbine, furnace, boiler, or the like.

This invention is a graded catalyst comprising palladium and also a partial combustion process in which the fuel is partially combusted using that catalyst. The catalyst utilizes a catalytic support structure suitable for high flow rates of combustible gas mixtures through it. The catalyst is situated on the support so that in the flowing gas stream a leading portion of the support has a higher combustion activity, such as by a higher concentration of catalytic metal, than has the trailing portion. The combination of graded catalyst and support provides a low 'light off' temperature for the combustible gas (only a low preheat temperature is needed to cause the combustion reaction to begin) and yet does not cause 'hot spots' to occur because of excess activity. The combustion gas produced by the catalytic process may be at a temperature below the adiabatic combustive temperature, may be used at that temperature, or fed to other combustion stages for further use in a gas turbine, furnace, boiler, or the like.

Graded palladium-containing partial combustion catalyst

This invention is a catalyst structure having integral heat exchange surfaces and a method for using the structure in highly exothermic processes, such as a combustion process, while maintaining the catalyst and the structure wall at a temperature below the adiabatic combustion temperature.

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Sunnyvale, CA, United States of America

Toru Shoji