Kanegafuchi Kagaku Kogyo Kabushiki Kaisha

Kanegafuchi Chemical Industry Co., Ltd.

Toragoro Mitani

Takamichi Komabashiri

Hideo Yasui

Hiroaki Yamauchi

Wataru Okada

Yasuhiro Miki

Hisashi Morikawa

Toshimitsu Nakashima

Masahiro Tsujinaka

The present invention provides a method for recovering polymer agglomerates in the form of dry powders or granules comprising steps of:

Method of recovering polymer agglomerates as dry powders or granules

Polymer scale deposition on polymerization reactor inside surfaces in the polymerization of a monomer or monomers having an ethylenic double bond and/or a monomer or monomers having diolefinic double bonds is prevented, peelability or removability of polymer scales deposited on such surface, if any, is improved and the scale inhibitor adherence to the wall surface of glass-lined polymerization reactors is improved by coating the inside surfaces of the reactor in advance with a coating composition comprising a quinone-amine compound having a molecular weight of at least 3,000 as obtained by subjecting at least one aromatic diamine and at least one aromatic quinone to addition reaction in at least one solvent having a solubility parameter of 8.5 to 24.0 and/or a reduced form of said quinone-amine compound and at least one silica organosol or a mixture of at least one silica organosol and at least one alkyl silicate to thereby form a hydrophilic coat film on the surfaces.

Method of preventing polymer scale deposition

A chemical cleaning method for removing scales and other substances deposited on the interior of a polymerization reactor used in emulsion polymerization or suspension polymerization. This method comprises chemically cleaning the interior using an aqueous solution or dispersion of an alkali agent and a surfactant. According to this method of cleaning, scales deposited on the interior of a polymerization reactor, in particular, scales deposited during polymerization on the inside surface, an agitator and baffle-plates of the reactor are completely removed.

Chemical cleaning method of the interior of polymerization reactor

A cleaning method for removing scales, etc., deposited on the interior of a polymerization reactor which has been used in emulsion or suspension polymerization. This method uses a chemical cleanser comprising a soap builder an, alkali agent, an aqueous solution or dispersion of a surfactant, and an organic solvent and/or polymerizable monomer. This system may further contain a plastic packing such as tellerettes. By this method, scales deposited on the interior of a polymerization reactor, particularly, scales deposited on the inside surface, agitator, and baffle-plates of the reactor, are compeltely removed.

Method of cleaning the interior of polymerization reactor

An apparatus for cleaning a tank-like vessel comprising

Apparatus for cleaning a tank-like vessel

A process for preparing a scale deposition preventing agent of a quinone-amine compound suitable for use in a polymerization of acrylic or methacrylic acid ester monomers, which comprises (A) subjecting an aromatic quinone and an aromatic diamine to addition reaction in a solvent having a solubility parameter of 8.5 to 24.0 to give an addition product, and (B) converting the addition product into a high molecular weight compound within 24 hours after beginning the addition reaction (A) by adding an oxidizing agent to the addition reaction mixture or by subjecting the addition reaction mixture to anodic oxidation with an electrode to give a quinone-amine compound. According to the present invention, the preparation rate of the scale deposition preventing agent of the quinone-amine compound can be remarkably increased, the yield can be increased, and the obtained compound has excellent properties.

Scale deposition preventing agent

A process for removing an organic compound having a high boiling point from a floatable polymer containing the organic compound, which comprises contacting a slurry of the polymer with a non-condensable gas at a high temperature by strongly agitating with an agitator at an impeller Reynolds number of not less than 10.sup.5. According to the process, the organic compound having a high boiling point can be readily removed down to not more than 10 ppm.

Process for removing organic compound having high boiling point from a

In a process of emulsion-polymerization in a polymerization system containing an acrylate or a methacrylate monomer at least 60%; the improvement which comprises carrying out the emulsion polymerization in a polymerization vessel having a film of a quinone-amine compound of not less than 3000 in average molecular weight on the inner vessel wall, said quinone-amine compound being prepared by addition-reacting an aromatic quinone and an aromatic diamine in a solvent medium having a solubility parameter of 9.0 to 12.2. According to the process, the polymer scale deposition can be prevented in the acrylate or methacrylate polymerization system.

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Takasago, Japan

Toragoro Mitani