Dow Global Technolgoies LLC

Toni Ristoski

Gary Lee Jialanella

Peter N Nickias

Shaoguang Feng

Eric E Cole

Dean A Johnson

Arthur F Cawley

Christopher P Christenson

David H Bank

Valeriy V Ginzburg

Lirong Zhou

Michael Frishcosy

Sean C Tobin

Mike Frishcosy

Sean Tobin

A Dean Johnson

Arthur Cawley

An acrylic ester containing resin mixture for production of reinforced composite, and the process of making and using the same.

Internal mold release agent for reinforced composite

A composition comprising a) one or more isocyanate functional components, one or more oligomers or prepolymers containing isocyanate functional groups and alkoxysilane groups, or prepolymers having a flexible backbone and silane moieties capable of silanol condensation: b) one or more catalysts for the reaction of isocyanate moieties with active hydrogen atom containing groups or for silanol condensation; c) one or more compounds comprising a dihydrocarbyl hydroxyl amine, an alicyclic hydroxyl amine, a nitrile oxide of a dihydrocarbyl hydroxyl amine or a nitrile oxide of an alicyclic hydroxyl amine in a sufficient amount to enhance the ultraviolet stability of the composition in a cured state; and d) a pigment that does not have reinforcing properties or the composition contains one of one or more oligomers or prepolymers containing isocyanate functional groups and alkoxysilane groups, or prepolymers having a flexible backbone and silane moieties capable of silanol condensation. The compositions are useful as adhesives and sealers.

Curable compositions containing isocyanate functional components having improved durability

A composition comprising: a) one or more isocyanate functional prepolymers; b) one or more catalysts for the reaction of isocyanate moieties with hydroxyl groups; c) one or more reinforcing fillers; and d) a stabilizing amount of one or more compounds comprising a dihydrocarbyl hydroxylamine, an alicyclic hydroxylamine, a nitrile oxide of a dihydrocarbyl hydroxylamine or a nitrile oxide of an alicyclic hydroxylamine. In another embodiment the invention is a method of bonding two or more substrates together which comprises contacting the two or more substrates together with a composition according to this invention disposed along at least a portion of the area wherein the substrates are in contact. The compositions of the invention are useful as an adhesive to bond substrates together.

The invention is an adhesive composition comprising: a) an isocyanate functional polyether base prepolymers having a z molecular weight average (Mz) of about 10,000 to about 80,000 g/mole; a carbon black having an average oil absorption number of at least about 80 to at most about 400 cubic centimeters of dibutyl phthalate per 100 grams of the carbon black; (c) reactive silicon in an amount from about 0.001% to about 10% by weight of the adhesive composition; and (d) one or more catalysts for the reaction of isocyanate with hydroxyl groups. The adhesive compositions of the invention surprisingly may have improved sag performance (i.e., decreased sag) when heated, while also making them more easily pumped.

Vehicular glass adhesive and method of adhering said glass

An organoborane complex is disclosed. The complex includes a blocking agent comprising a bifunctional Lewis base. The blocking agents include an amine group and a second functional group that has a lower Lewis basicity than the first functional group. The blocking is based on amino alkyl pyridines.

Blocking agents for organoborane compounds

The invention is amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate anion wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms, and a cationic counter ion.

Amido-organoborate initiator systems

The invention is a system for initiating free radical polymerization comprising:

The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on the weight of the second part of i) a halogenated polyolefin having halosulfonyl groups or ii) a mixture of a halogenated polyolefin and an organic sulfonyl halide. The second part may further contain a compound capable of causing the organoboron compound to form free radical generating species upon contacting the two parts. The first part may further comprise one or more compounds capable of free radical polymerization.

Accelerated organoborane initiated polymerizable compositions

The invention is polymerizable compositions comprising in one part an organoboron compound capable of forming a free radical generating species and a stabilizing amount of one or more compounds comprising a dihydrocarbyl hydroxyl amine, an alicyclic hydroxyl amine, or a nitrile oxide of a dihydrocarbyl hydroxyl amine or an alicyclic hydroxyl amine, and in the second part one or more compounds capable of free radical polymerization.

Growing community of inventors

Rochester Hills, MI, United States of America

Toni Ristoski