Haldor Topsoe A/s

Haldor Topse A/s

Ton V W Janssens

Peter N R Vennestrøm

Pablo Beato

Svend-Erik Mikkelsen

Poul Erik Højlund Nielsen

Finn H Joensen

Bodil Voss

Søren Dahl

Claus Hviid Christensen

Niels Christian Schiødt

Pär L T Gabrielsson

Pär L Gabrielsson

Christophe Duwig

Simon Ivar Andersen

Peter N R VENNESTRØM

In a process for the oxidation of a lower alkene, such as ethylene, over a catalyst containing Cu and one or more zeolite or zeotype materials, the oxidation is conducted in the presence of ammonia in the feed gas at a process temperature below 350&#xb0; C. The oxidation can be performed in a continuous process.

Process for oxidation of a lower alkene at low temperatures in ammonia-containing gas mixtures

In a process for the oxidation of a lower alkane, such as methane, over a catalyst containing Cu and one or more zeolite or zeotype materials, the oxidation is conducted in the presence of ammonia in the feed gas at a process temperature below 350&#xb0; C. The oxidation can be performed in a continuous process.

Process for oxidation of a lower alkane at low temperatures in ammonia-containing gas mixtures

Method for the preparation of a metal-exchanged zeolites or mixtures of metal-exchanged zeolites, such as Cu-SSZ-13, Cu-ZSM-5, Cu-beta, or Fe-beta, comprising the steps of providing a dry mixture of a) one or more microporous zeotype materials that exhibit ion exchange capacity and b) one or more metal compounds; heating the mixture in a gaseous atmosphere containing ammonia to a temperature lower than 300&#xb0; C. for a time sufficient to initiate and perform a solid state ion exchange of ions of the metal compound and ions of the zeolite material; and obtaining the metal-exchanged zeolite material.

Method for producing metal exchanged zeolites by solid-state ion exchange at low temperatures

Method for the preparation of a metal exchanged crystalline microporous metalloaluminophosphate or mixtures containing metal exchanged microporous metalloaluminophosphates materials comprising the steps of providing a dry mixture containing a) one or more metalloaluminophosphates starting materials that exhibit ion exchange capacity, and b) one or more metal compounds; heating the mixture in a gaseous atmosphere containing ammonia to a temperature (less than 300 C) and for a time sufficient to initiate and perform a solid state ion exchange of ions of the metal compound and ions of the crystalline microporous material; and obtaining the metal-exchanged microporous metalloaluminophosphate material or mixtures containing the metal-exchanged microporous metalloaluminophosphate material.

Method for producing metal exchanged metallo-aluminophosphates by solid-state ion exchange at low temperatures

A method is disclosed for the preparation of a metal exchanged microporous materials, e.g. metal exchanged silicoaluminophosphates or metal exchanged zeolites, or mixtures of metal exchanged microporous materials, comprising the steps of providing a dry mixture of a) one or more microporous materials that exhibit ion exchange capacity and b) one or more metal compounds; heating the mixture in a gaseous atmosphere containing ammonia and one or more oxides of nitrogen to a temperature and for a time sufficient to initiate and perform a solid state ion exchange of ions of the metal compound and ions of the microporous material; and obtaining the metal-exchanged microporous material.

Method for producing metal exchanged microporous materials by solid-state ion exchange

Process for the synthesis of hydrocarbon constituents of gasoline comprising catalytic conversion in a gasoline synthesis step of an oxygenate-containing feed comprising methanol and/or dimethyl ether and a mixture of at least on a total oxygenate basis 0.05 wt % Chigher alcohols and/or their oxygenate equivalents to hydrocarbon constituents of gasoline.

Process for the synthesis of hydrocarbon constituents of gasoline

Method and system for operating a compression engine on ether containing fuel obtained by conversion of a primary fuel based on alcohol comprising the steps and means for: (a) continuously withdrawing the primary fuel based on alcohol from a fuel tank and pressurising the primary fuel based on alcohol in its liquid form to a final engine injection pressure; (b) continuously introducing the pressurized primary fuel based on alcohol into a fuel accumulation chamber; (c) continuously distributing the pressurized primary fuel based on alcohol into pipes connecting the accumulation chamber with fuel injectors of the engine; (d) prior to the fuel injectors continuously converting the pressurised primary fuel based on alcohol to an ether containing fuel by contact with an alcohol dehydration catalyst being arranged in each of the pipes upstream the fuel injectors; (e) continuously injecting the ether containing fuel at injection pressure into the engine; and (f) continuously withdrawing a part of the introduced primary fuel based on alcohol from the accumulation chamber; and (g) depressurising and recycling the withdrawn primary fuel based on alcohol to the fuel tank.

Method for operating a pressure ignition engine

Method of operating a compression ignition engine on ether containing fuel obtained by on board conversion of an alcohol containing primary fuel, and a system for use in the method. The alcohol containing primary fuel is heated within a dehydration reactor by indirect heat exchange with ether containing fuel prepared in the dehydration reactor by dehydrating the alcohol containing primary fuel. The ether containing fuel is cooled prior to withdrawal from the reactor as a result of the indirect heat exchange with the alcohol containing primary fuel.

Method and system for operating a compression ignition engine on alcohol containing primary fuels

A process for the conversion of oxygenates to hydrocarbons comprising contacting a feed stream comprising oxygenates with a catalyst containing a microporous material under oxygenate conversion conditions, wherein the catalyst contains a crystalline microporous material with intra-crystalline mesopores. The invention also includes a composition for use in the above process.

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Ton V W Janssens