Kaneka Corporation

Tomomichi Hashimoto

Akira Takaki

Takeshi Tanaka

Kazunori Saegusa

Kohei Kawamura

Mika Yorizane

Nobuo Miyatake

Hiroshi Tsuneishi

Masato Fujita

Tomokazu Higami

Sota Okumura

Toshio Mizuta

Mitsuo Kakutani

Takao Manabe

Hiroshi Tone

Takao Michinobu

Akihiro Okamoto

Akio Sato

Hiroshi Fujinaga

Tosio Mizuta

The present invention relates to a fiber for artificial hair having a hollow in a center of a fiber cross section. A ratio of an area of the hollow to an entire area of the fiber cross section is 5% to 50%. The fiber cross section has a flat multilobed shape, and the hollow has a first side and a second side that are inclined 70 to 110 degrees relative to a major axis of the fiber cross section. The present invention also relates to hair ornament products including the above fiber for artificial hair. Thus, the present invention provides a fiber for artificial hair having a favorable curl setting property when curling with a hair iron and a favorable combing property after curling with a hair iron, and hair ornament products including the same.

Fiber for artificial hair and hair ornament product including same

Modacrylic fibers for artificial hair include a modacrylic polymer; and a condensed phosphate. The modacrylic polymer includes 29.5 to 79.5% by mass of acrylonitrile, 20 to 70% by mass of vinyl chloride and/or vinylidene chloride, and 0.5 to 5% by mass of a sulfonic acid group containing vinyl monomer, with respect to a total mass of the modacrylic polymer. A content of the condensed phosphate in the modacrylic fibers is 0.05 to 0.57% by mass.

Acrylic fiber for artificial hair, method for producing same, and head decoration article containing same

A thermoplastic modacrylic resin composition includes a modacrylic resin and a plasticizer. The modacrylic resin includes 15 to 85 wt % of acrylonitrile, 15 to 85 wt % of vinyl chloride and/or vinylidene chloride, and 0 to 20 wt % of another vinyl monomer, and the plasticizer is an organic compound that is compatible with the modacrylic resin and has a boiling point of at least 200&#xb0; C. A method for manufacturing a thermoplastic modacrylic resin composition includes melt-kneading a powder mixture obtained by mixing a modacrylic resin powder and an organic compound that is compatible with the modacrylic resin and has a boiling point of at least 200&#xb0; C. Acrylic fibers are composed of a thermoplastic modacrylic resin composition.

Thermoplastic modacrylic resin composition, method for manufacturing same, molded article of same, and acrylic fibers and method for manufacturing same

An acrylonitrile-containing fiber includes 100 parts by mass of a polymer including at least 15 parts by mass of acrylonitrile; and 1.0 to 50 parts by mass of a water absorbent resin having a pure water absorption capacity (g/g) with respect to its own weight of at least 10 but less than 100, wherein the fiber is dyeable with a disperse dye.

Acrylonitrile-containing fiber dyeable with disperse dyes, method for producing same, and fiber product containing same

An acrylic fiber for artificial hair includes an acrylic polymer, wherein the acrylic polymer includes 29.5 to 79.5% by mass of acrylonitrile, 20 to 70% by mass of vinyl chloride and/or vinylidene chloride, and 0.5 to 5% by mass of a vinyl monomer comprising a sulfonic acid group. The acrylic fiber for artificial hair includes 0.3 to 2% by mass of a good solvent for the acrylic polymer and 0.1 to 5% by mass of a compound comprising an epoxy group.

Acrylic fiber for artificial hair, manufacturing method therefor and head accessory containing same

The present invention relates to a polyester-based fiber for artificial hair obtained by melt spinning a polyester resin composition. The polyester resin composition includes 100 parts by weight of a polyester resin, 5 to 40 parts by weight of a brominated epoxy flame retardant, and 1.5 parts by weight or more and less than 7 parts by weight of an antimony oxide. The polyester resin is at least one kind of resin selected from the group consisting of polyalkylene terephthalate and a copolymerized polyester containing polyalkylene terephthalate as a main component. The polyester-based fiber for artificial hair has aggregates of the brominated epoxy flame retardant that are dispersed in the polyester resin in the form of islands, as viewed in the cross section of the fiber parallel to the fiber axis direction. The present invention also relates to hair ornament products including the polyester-based fiber for artificial hair and a method for producing the polyester-based fiber for artificial hair. Thus, the present invention provides a polyester-based fiber for artificial hair having a gloss and a texture that are similar to those of human hair, and hair ornament products including the polyester-based fiber for artificial hair.

Polyester-based fiber for artificial hair and hair ornament product including the same, and method for producing the same

A polyester-based fiber for artificial hair of the present invention is a polyester-based fiber for artificial hair formed of a polyester resin composition. The polyester resin composition contains 5 to 40 parts by weight of a brominated epoxy flame retardant and 0.05 to 5 parts by weight of an acidic compound with respect to 100 parts by weight of a polyester resin. The polyester resin is one or more kind of resin selected from the group consisting of polyalkylene terephthalate and copolymerized polyester containing polyalkylene terephthalate as a main component. The acidic compound is an acidic phosphorus-based compound having a pH of 3.5 or less. A hair ornament product of the present invention contains the polyester-based fiber for artificial hair.

Polyester-based fiber for artificial hair and hair ornament product including the same

The present invention relates to a flame retardant which is a graft copolymer. The graft copolymer is obtained by polymerizing a vinyl monomer containing at least two polymerizable groups, and at least one other vinyl monomer, in the presence of polyorganosiloxane particles in a latex state. The polyorganosiloxane particles contain grafting agents that are unevenly distributed on the surface thereof. The present invention also relates to thermoplastic resins containing this flame retardant.

Polyorganiosiloxane-containing graft copolymer, resin compositions containing the same and process for produciton of polyorganosiloxane emulsions

The present invention provides a polyorganosiloxane-containing graft copolymer A polyorganosiloxane-containing graft copolymer

Graft copolymers and impact-resistant flame-retardant resin compositions containing the same

The object of the present invention is to provide

Flame-retardant thermoplastic resin composition

There is provided a rubber latex for an excellent impact modifier used for a thermoplastic resin. A rubber latex containing water in particles obtained by seed polymerization with seed polymers which are highly hydrophilic and sufficiently swellable into a rubber monomer is used as an impact modifier for a thermoplastic resin.

Process for producing rubber latex containing water in particle

There is provided an excellent impact modifier for a vinyl chloride resin. There is used, as an excellent impact modifier, a copolymer which is prepared by polymerizing 10 to 70% by weight of a monomer or monomers containing 60 to 100% by weight of at least one vinyl monomer selected from the group consisting of a (meth)acrylate compound, an aromatic vinyl compound, a vinyl cyanide compound and vinyl chloride, and 0 to 40% by weight of the other monomer copolymerizable therewith, in the presence of 30 to 90% by weight of a hollow rubber particle of which glass transition temperature Tg is at most 0&deg; C. and a void ratio is 3 to 90% by volume in a latex state, and which contains a cross linking agent in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of the total rubber component monomer.

Impact modifiers for thermoplastic resins

A resin composition suitable as an impact modifier for thermoplastic resins, which has an excellent blocking resistance improved without lowering the effect of improving the impact resistance and which comprises 100 parts by weight of a graft copolymer containing a hollow rubber component and at least two additives selected from the group consisting of 0.1 to 10 parts by weight of a higher fatter acid soap, 0.1 to 10 parts by weight of a crosslinked polymer of 0.1 to 100% by weight of a crosslinking monomer and 0 to 99.9% by weight of a vinyl monomer and 0.001 to 5 parts by weight of a silicone oil.

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Osaka, Japan

Tomomichi Hashimoto