Kaneka Corporation

Tomomi Meguro

Kenji Yamamoto

Masashi Hino

Mitsuru Ichikawa

Hisashi Uzu

Ryota Mishima

Katsuhiko Hayashi

Kunta Yoshikawa

Takashi Kuchiyama

Yuko Tawada

Akihiko Nakajima

Gensuke Koizumi

Naoaki Nakanishi

Susumu Fukuda

Fumiyasu Sezaki

Osamu Inaki

A method for manufacturing a stacked photoelectric conversion device includes forming an intermediate transparent conductive layer on a light-receiving surface of a crystalline silicon-based photoelectric conversion unit including a crystalline silicon substrate, and forming a thin-film photoelectric conversion unit on the intermediate transparent conductive layer. The stacked photoelectric conversion device includes the crystalline silicon-based photoelectric conversion unit, the intermediate transparent conductive layer, and the thin-film photoelectric conversion unit. The light-receiving surface of the crystalline silicon-based photoelectric conversion unit has a textured surface including a plurality of projections and recesses. The textured surface has an average height of 0.5 &#x3bc;m or more. The intermediate transparent conductive layer fills the recesses of the textured surface and covers the tops of the projections of the textured surface. At least a part of the thin-film photoelectric conversion unit is deposited by a wet method.

Stacked photoelectric conversion device and method for producing same

A tandem-type photoelectric conversion device includes, arranged in the following order from a light-incident side: a first photoelectric conversion unit; an anti-reflection layer; a transparent conductive layer; and a second photoelectric conversion unit. The first photoelectric conversion unit includes a light absorbing layer including a photosensitive material of perovskite-type crystal structure represented by general formula RNHMXor HC(NH)MX, wherein Ris an alkyl group, Mis a divalent metal ion, and X is a halogen. The second photoelectric conversion unit includes a light absorbing layer having a bandgap narrower than a bandgap of the light absorbing layer in the first photoelectric conversion unit. The anti-reflection layer and the transparent conductive layer are in contact with each other, and a refractive index of the anti-reflection layer is lower than a refractive index of the transparent conductive layer.

Photoelectric conversion device and photoelectric conversion module

A multi-junction photoelectric conversion device includes, in the following order from a light-receiving side: a first photoelectric conversion unit; an intermediate layer; and a second photoelectric conversion unit. The first photoelectric conversion unit includes: a first light absorbing layer comprising a perovskite-type crystal structure photosensitive material; a first charge transport layer on the light-receiving side of the first light absorbing layer; and a second charge transport layer on a rear side of the first light absorbing layer. The second charge transport layer is in contact with the intermediate layer. The second photoelectric conversion unit includes: a second light absorbing layer that is a crystalline silicon substrate; and a first conductive semiconductor layer that is in contact with the intermediate layer.

Multi-junction photoelectric conversion device and photoelectric conversion module

A composite solar cell comprises a spectroscopic element, a first photoelectric conversion element, and a second photoelectric conversion element. The first photoelectric conversion element is positioned in a first direction of the spectroscopic element and the second photoelectric conversion element is positioned in a second direction of the spectroscopic element. The first photoelectric conversion element is a perovskite-type photoelectric conversion element containing, in a light absorbing layer, a perovskite crystal structure material represented by a general formula RNHMX. A band gap of a light absorbing layer of the second photoelectric conversion element is narrower than the band gap of the light absorbing layer of the first photoelectric conversion element. The spectroscopic element preferentially outputs the short wavelength light of the incident light in the first direction and preferentially outputs the long wavelength light of the incident light in the second direction.

Composite solar cell, solar cell module, and concentrating solar cell

A solar cell includes a metal layer and a chalcopyrite compound semiconductor layer in this order on a polyimide film. A manufacturing method according to the present invention includes the following steps in the order: cast applying a polyimide precursor solution onto a support base containing an alkali metal; imidizing the polyimide precursor by heating to form a stacked body including a polyimide film on the support base; forming a metal layer on the polyimide film of the stacked body; and forming a chalcopyrite compound semiconductor layer on the metal layer.

Method for manufacturing compound semiconductor solar cell

The thin-film photoelectric conversion device of the present invention includes: a transparent electroconductive film having zinc oxide as a main component; a contact layer; a photoelectric conversion unit having a p-type semiconductor layer, an i-type semiconductor layer and an n-type semiconductor layer in this order; and a back electrode layer, in this order, on one main surface of a substrate. The contact layer has an intrinsic crystalline semiconductor layer and a p-type crystalline semiconductor layer in this order from the substrate side, and the intrinsic crystalline semiconductor layer of the contact layer and the transparent electroconductive film are in contact with each other. The p-type crystalline semiconductor layer of the contact layer is preferably a layer having as a main component a silicon alloy selected from the group consisting of a silicon oxide; a silicon nitride; and silicon carbide.

Thin-film photoelectric conversion device and method for manufacturing same

Disclosed is a substrate with a transparent conductive film, wherein an underlying layer and a transparent conductive film are arranged in this order on a transparent insulating substrate. The transparent conductive film-side surface of the underlying layer is provided with a pyramid-shaped or inverse pyramid-shaped irregular structure, and the transparent conductive film comprises a first transparent electrode layer which is formed on the underlying layer and a second transparent electrode layer which forms the outermost surface of the transparent conductive film. By forming a zinc oxide layer that serves as the second transparent electrode layer by a reduced pressure CVD method, a substrate with a transparent conductive film that is provided with an irregular structure smaller than that of the underlying layer can be obtained. The substrate with a transparent conductive film can improve the conversion efficiency of a photoelectric conversion device through an increased light trapping effect.

Substrate with transparent conductive film and thin film photoelectric conversion device

This invention intends to develop a technique for forming an interlayer with excellent optical characteristics and to provide a photoelectric conversion device having high conversion efficiency. To realize this purpose, a series connection through an intermediate layer is formed in the thin-film photoelectric conversion device of the invention, and the interlayer is a transparent oxide layer in its front surface and n pairs of layers stacked therebehind (n is an integer of 1 or more), wherein each of the pair of layers is a carbon layer and a transparent oxide layer stacked in this order. Film thicknesses of each layer are optimized to improve wavelength selectivity and stress resistance while keeping the series resistance.

Thin film photoelectric conversion device having a stacked transparent oxide and carbon intermediate layer

An integrated thin-film photoelectric conversion module includes a multi-layered film including a first electrode layer, a semiconductor layer and a second electrode layer stacked on a main surface of a substrate. The multi-layered film includes a cell region including a plurality of photoelectric conversion cells connected in series, a bypass diode region and a connection region. The connection region does not connect the bypass diode to the cell during reverse bias treatment of the cell and the bypass diode, while the connection region connects the bypass diode in antiparallel to at least one of the plurality of cells connected in series after the reverse bias treatment.

Integrated thin-film photoelectric conversion module

There is provided a photovoltaic module including a transparent substrate and hybrid photovoltaic cells arrayed on the substrate and series connected to each other, the cells including a back electrode facing the substrate, a transparent front electrode intervening between the substrate and the back electrode, a first photovoltaic layer intervening between the front and back electrodes and including an amorphous semiconductor layer, a second photovoltaic layer intervening between the first photovoltaic layer and the back electrode and including a crystalline semiconductor layer, and a conductive interlayer with a light-transmitting-and-reflecting property intervening between the first and second photovoltaic layers and having a thickness in a range of 10 nm to 100 nm and a specific resistance in a range of 1&times;10 &OHgr;&middot;cm to less than 1&times;10 &OHgr;&middot;cm.

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Settsu, Japan

Tomomi Meguro