Nec Tokin Corporation

Ihara Chemical Industry Co., Ltd.

Tokin Corporation

Tomoki Nobuta

Toshihiko Nishiyama

Satoshi Suzuki

Masaya Mitani

Hiroyuki Kamisuki

Masato Kurosaki

Yasuhisa Sugawara

Naoki Takahashi

Gaku Harada

Yuji Nakagawa

Ryuta Kobayakawa

Shinako Kaneko

Yasuhiro Tomioka

Shinya Yoshida

Yuuji Nakagawa

Yuji Yoshida

Tetsuya Yoshinari

Naoto Yazawa

Hideo Ooi

Hiroyuki Demizu

Hiroki Satoh

Tetuya Yoshinari

An electrically conductive polymer composition has high electrical conductivity, excellent water resistance, high density, and excellent smoothness. Also disclosed is a solid electrolyte capacitor which is prevented from the reduction in electrical conductivity, has low ESR, and also has excellent reliability. Further disclosed is a method for producing the solid electrolyte capacitor. The electrically conductive polymer composition is produced by removing a dispersion medium from an electrically conductive polymer suspension, wherein the electrically conductive polymer suspension includes: an electrically conductive polymer material including a dopant composed of a polyacid or a salt thereof and an electrically conductive polymer; at least one compound (A) selected from erythritol, xylitol and pentaerythritol; and the dispersion medium.

Solid electrolytic capacitor

An electric conductive polymer suspension is produced by performing chemical oxidative polymerization of a monomer for providing an electric conductive polymer by using an oxidant in a solvent containing an organic acid or a salt thereof as a dopant to form an electric conductive polymer, recovering the electric conductive polymer, allowing an oxidant to act on the electric conductive polymer in an aqueous solvent containing a polyacid, and further mixing a dispersant with a branched structure and then pulverizing the electric conductive polymer. According to the electric conductive polymer suspension, an organic material high in conductivity, and excellent in adhesiveness to a substrate and water resistance, and a method for producing the material, as well as an electrolytic capacitor and a method for producing the capacitor can be provided.

Electric conductive polymer suspension and method for producing the same, electric conductive polymer material, and electrolytic capacitor and method for producing the same

Provided is an electroconductive polymer composition with a good film forming property and a high electroconductivity. Also, provided is an electroconductive polymer material and an electroconductive substrate with a high electroconductivity and transparency. Further, provided is a solid electrolytic capacitor with a high capacity and a low ESR. Disclosed is an electroconductive polymer composition, containing an electroconductive polymer obtained by an oxidation polymerization by using an oxidant in a reaction solution which contains at least one monomer selected from the group consisting of pyrrole, thiophene and derivatives thereof, a polyacid or a salt thereof as a dopant, and a solvent containing water and an aprotic solvent.

Electroconductive polymer composition, electroconductive polymer material, electroconductive substrate, electrode and solid electrolytic capacitor

Provided is an electroconductive polymer composition with a good film forming property. Also, provided is an electroconductive polymer material with a high electroconductivity and a high transparency as well as an electroconductive substrate having the electroconductive polymer material on a substrate, and an electrode. Further, provided is an electronic device having the electrode as well as a solid electrolytic capacitor with a high capacitance and a low ESR. Disclosed is an electroconductive polymer composition, containing an electroconductive polymer in which a dopant is doped, a water-soluble polymer resin, and a solvent which contains water and an organic solvent whose dielectric constant is higher than that of water.

Provided are an electroconductive polymer suspension solution and a method for producing the same, which has excellent adhesion to a substrate and excellent liquid resistance and which can provide an organic material having high electroconductivity. An electroconductive polymer suspension solution of an exemplary embodiment of the invention contains an electroconductive polymer, at least one kind of a water-soluble polyhydric alcohol, and at least one kind of a water-soluble organic substance having two or more functional groups which can be polycondensed with the water-soluble polyhydric alcohol. The electroconductive polymer suspension solution can be produced by collecting an electroconductive polymer which is obtained by chemical oxidative polymerization of a monomer giving the electroconductive polymer by using an oxidant in a solvent containing an organic acid or a salt thereof as a dopant, by contacting the electroconductive polymer with an oxidant in an aqueous solvent containing a polyacid, and further by mixing at least one kind of a water-soluble polyhydric alcohol and at least one kind of a water-soluble organic substance having two or more functional groups which can be polycondensed with the water-soluble polyhydric alcohol.

Conductive polymer suspension and method for producing the same, conductive organic material, and electrolytic capacitor and method for producing the same

The present invention provides an electroconductive polymer suspension solution and an electroconductive polymer material which has a high electroconductivity and in which the time-related deterioration of the electroconductivity is suppressed. Also, the present invention provides an electrolytic capacitor with a low ESR using the electroconductive polymer material as a solid electrolyte and a method for producing the same. In the present invention, electroconductive polymer particlesin the electroconductive polymer material are bonded via organic dispersantand cross-linkerto obtain a strong bond between electroconductive polymer particles

Electroconductive polymer suspension solution, electroconductive polymer material, and electrolytic capacitor and method for producing the same

The present invention provides an electroconductive polymer solution in which the good dispersibility is maintained and the pH is arbitrarily adjusted, and an electroconductive polymer composition having an excellent heat resistance. Further, the present invention provides a solid electrolytic capacitor having an excellent reliability. The present invention is an electroconductive polymer solution, containing an electroconductive polymer in which a dopant is doped, a first compound having an amino group and a hydroxyl group, a second compound having a carboxylic acid group, and a dispersing medium.

Electroconductive polymer solution, electroconductive polymer composition, and solid electrolytic capacitor therewith and method for producing same

An exemplary embodiment of the invention provides an electroconductive polymer composition having high electroconductivity which is suitable for a solid electrolytic capacitor, and provides a solid electrolytic capacitor having low ESR as well as low leakage current (LC). In an exemplary embodiment of the invention, an electroconductive polymer composition having high electroconductivity is formed by drying an electroconductive polymer suspension solution which comprises a polyanion having a cross-linked structure, an electroconductive polymer, and a solvent. In an exemplary embodiment of the invention, a solid electrolytic capacitor having low ESR as well as low LC is obtained by using the electroconductive polymer composition for a solid electrolyte layer that is an electroconductive polymer layer.

Electroconductive polymer composition, method for producing the same, and solid electrolytic capacitor using electroconductive polymer composition

A solid electrolytic capacitor includes an anode formed of a valve metal and having a roughened surface layer at a surface thereof, a dielectric layer formed of a valve metal oxide and formed on the anode, a cathode formed of a conductive polymer layer formed on the dielectric layer, an anode lead formed adjacent to and integrally with the anode, and a resist formed of an insulating material and delimiting the anode and the anode lead. The anode and the anode lead have a first stepped portion having both surfaces each cut in a thickness direction and covered with the resist, and the anode lead has a second stepped portion having both surfaces each cut deeper in the thickness direction than the first stepped portion.

Solid electrolytic capacitor with small leakage current and method of manufacturing the same

The present invention provides a conductive polymer suspension for providing a conductive polymer material having high conductivity and a method for producing the same, and particularly provides a solid electrolytic capacitor having low ESR and a method for producing the same. In an emulsion comprising a dopant of a low molecular organic acid or a salt thereof, obtained by emulsifying a monomer providing a conductive polymer, using a nonionic surfactant, in a water, the monomer is subjected to chemical oxidative polymerization, using an oxidant, to synthesize a conductive polymer. The obtained conductive polymer is purified, and then, the purified conductive polymer and an oxidant are mixed in an aqueous solvent containing a polyacid component to produce a conductive polymer suspension.

Conductive polymer suspension and method for producing the same, conductive polymer material, and solid electrolytic capacitor and method for producing the same

A conductive polymer composition with excellent water resistance and conductivity, and a solid electrolytic capacitor with low ESR, excellent reliability, and especially moisture resistance. The conductive polymer composition includes a conductive polymer, a polyanion that includes a hydrophilic group, where the polyanion functioning as a dopant of the conductive polymer. At least a part of the hydrophilic group of the polyanion is condensed with an epoxy group in a compound with one epoxy group. A solid electrolytic capacitor of the present invention includes the conductive polymer composition.

Conductive polymer composition, method of producing the same, and solid electrolytic capacitor

The present invention provides a conductive polymer suspension for providing a conductive polymer material having a high conductivity and a method for producing the same, and in particular, a solid electrolytic capacitor having a low ESR and a method for producing the same. The conductive polymer suspension is produced by: synthesizing a conductive polymer by chemical oxidative polymerization of a monomer giving the conductive polymer by using an oxidant in a solvent containing a dopant consisting of a low-molecular organic acid or a salt thereof; purifying the conductive polymer; and mixing the purified conductive polymer and an oxidant in an aqueous solvent containing a polyacid component.

Conductive polymer suspension and method for producing the same, conductive polymer material, electrolytic capacitor, and solid electrolytic capacitor and method for producing the same

The present invention provides a conductive polymer suspension for providing a conductive polymer material having a high conductivity and a method for producing the same, and in particular, a solid electrolytic capacitor having a low ESR and a method for producing the same. The conductive polymer suspension can be is produced by: synthesizing a conductive polymer by chemical oxidative polymerization of a monomer giving the conductive polymer by using an oxidant in an aqueous solvent containing a dopant consisting of a low-molecular organic acid or a salt thereof, or a polyacid having a weight average molecular weight of less than 2,000 or a salt thereof.

In a solid electrolytic capacitor including a porous valve-acting metal, an anode conductor has a large number of pores having openings on the surface thereof according to the porosity of the valve-acting metal. A solid electrolyte layer is formed on the surface of the anode conductor so as to be filled in at least a portion of each of the pores and to close the openings thereof. Further, a cathode conductor is formed on the solid electrolyte layer. Preferably, the solid electrolyte layer has a two-layer structure with two layers having different particle sizes.

Solid electrolytic capacitor with improved moisture resistance properties and method of manufacturing the same

A solid electrolytic capacitor manufacturing method includes a process of removing a roughened surface layer (') from a distal portion () of a metal member () and from part of an intermediate portion () adjacent to the distal portion (), a process of forming a resist () on the distal portion () and the intermediate portion () of the metal member (), a process of forming a conductive polymer layer () of a conductive polymer on a proximal portion () of the metal member (), and a process of removing a resist (&#x2032;) and a surface layer portion (&#x2032;) of the metal member () from the distal portion () of the metal member ().

Growing community of inventors

Miyagi, Japan

Tomoki Nobuta