Toyo Seikan Group Holdings, Ltd.

Kansai Paint Company, Ltd.

Toyo Seikan Kaisha, Ltd.

Toyo Seikan Kaisya, Ltd.

Tomohiro Miyai

Yusuke Obu

Kashiko Kawai

Shunya Nangou

Yuji Funagi

Takuya Kashiwakura

Arata Sakuragi

Hideki Masuda

Takahiro Hidaka

Nan Zhang

An organic resin-covered surface-treated metal sheet having formed on at least one surface of a metal sheet a surface-treatment coating and an organic resin film on the coating. The surface-treatment coating contains a polyvalent metal compound and a poly-carboxylic acid type polymer containing not less than 60 mol % constituent units derived from at least one polymerizable monomer selected from acrylic acid, maleic acid, methacrylic acid, and itaconic acid. The surface-treatment coating measured for its infrared-ray absorption spectra has a peak height ratio (&#x3b2;/&#x3b1;) of a maximum absorption peak height (&#x3b1;) in a wave number range of 1660 to 1760 cmand a maximum absorption peak height (&#x3b2;) in a wave number range of 1490 to 1659 cmis from 0.37 to 2.35. Also disclosed is a can body made from the organic resin-covered surface-treated metal sheet and a can lid made from the organic resin-covered surface-treated metal sheet.

Organic resin-covered surface-treated metal sheet

A chromium-free surface-treated metal sheet includes a metal sheet, a surface-treatment coating that contains a polycarboxylic acid type polymer and a zirconium compound and that is formed on at least one surface of the metal sheet, and a coating that contains a polyester resin, a phenol resin and an acid catalyst and that is formed on the surface-treatment coating. The surface-treated metal sheet can be used for producing cans and can lids maintaining excellent dent resistance even for acidic beverages, without permitting the organic resin film formed on the coating to be peeled even under high-temperature and wet environments during a sterilization treatment or the like, and maintaining excellent hot water-resistant adhering property.

Surface-treated metal sheet and organic resin-covered surface-treated metal sheet

An organic resin-covered surface-treated metal sheet having formed on at least one surface of a metal sheet a surface-treatment coating and an organic resin film on the surface-treatment coating. The surface-treatment coating contains a poly-carboxylic acid type polymer and a polyvalent metal compound. The surface-treatment coating measured for its infrared-ray absorption spectra has a peak height ratio (&#x3b2;/&#x3b1;) of a maximum absorption peak height (&#x3b1;) in a wave number range of 1660 to 1760 cmand a maximum absorption peak height (&#x3b2;) in a wave number range of 1490 to 1659 cmof from 0.05 to 2.35.

A surface-treated aluminum plate obtained by forming, on at least one surface of an aluminum plate, a conversion-coated layer that contains a polyester resin and a zirconium compound or a titanium compound. The surface-treated aluminum plate excellently adheres to an organic resin coating and can be used as a material for producing cans featuring excellent corrosion resistance and shock resistance.

Surface-treated aluminum plate, organic-resin-coated surface-treated aluminum plate, can body and can lid formed by using the same

A gas barrier material comprising a polycarboxylic acid polymer, and containing 0.10 to 1.4% by weight of a monovalent metal element, at least not less than 5.0% by weight of a polyvalent metal element, and 0.01 to 3.0% by weight of a nitrogen element per the total weight of nitrogen and carbon. The gas barrier material exhibits excellent gas barrier property, excellent waterproof property after the bend working and excellent appearance on the surface of the coating.

Gas barrier material and gas barrier laminate

To provide a coating composition for undercoating which, in forming a gas-barrier layer having a crosslinked structure between a polycarboxylic acid type polymer and polyvalent metal ions by the heating at a low temperature for a short period of time, permits polyvalent metal ions to be easily and quickly fed into the polycarboxylic acid type polymer and, besides, into the whole gas-barrier layer. A coating composition containing, as chief components, a nonaqueous polyester polyol, an isocyanate compound, and an alkaline compound of a polyvalent metal that serves as an ion source for forming the crosslinked structure, wherein the nonaqueous polyester polyol contains a nonaqueous polyester polyol which contains a metal element in the resin skeleton thereof as an essential component, and the alkaline compound of the polyvalent metal has an average primary particle size in a range of 0.005 to 0.5 &#x3bc;m.

Coating composition for undercoating

A method of producing a gas-barrier laminated member having a gas-barrier layer formed by crosslinking the carboxyl groups of a polycarboxylic acid polymer with multivalent metal ions. The method comprises forming a layer (A) containing an alkaline compound of a multivalent metal on at least one surface of a plastic base material, applying a solution (b) obtained by dissolving a polycarboxylic acid polymer in a solvent containing at least water onto the layer (A) that contains the alkaline compound of the multivalent metal, and removing the solvent by a heat treatment so that a metal-ionically crosslinked structure is formed with the multivalent metal ions among the carboxyl groups in the solution (b). The gas-barrier laminated member has excellent adhesion to the base material, gas-barrier property, retort resistance and flexibility, and is efficiently produced by only being heated at a low temperature for a short period of time through a decreased number of simplified steps.

Method of producing gas-barrier laminated member

A gas barrier laminate having an undercoating (A) which comprises a main resin, an isocyanate type curing agent and an alkaline compound of a polyvalent metal; and a barrier layer (B) of a polycarboxylic acid polymer forming an ionic crosslinking due to the polyvalent metal among the carboxyl groups; formed on at least one surface of a plastic base material (P), wherein a region (b) free of the alkaline compound of the polyvalent metal is formed in the undercoating (A) on the side of the barrier layer (B), the content of nitrogen in the region (b) being larger than the content of nitrogen in the undercoating (A) other than the region (b), the gas barrier laminate having excellent gas barrier property, retort resistance, producibility as well as excellent flexibility without developing interlayer peeling even if it is folded and featuring excellent interlayer adhesion.

Gas barrier laminate and method of producing the same

To provide a gas barrier laminate having a gas barrier layer obtained by crosslinking the carboxyl groups of a polycarboxylic acid-type polymer with polyvalent metal ions maintaining good productivity, the crosslinking being accelerated with polyvalent metal ions to exhibit more excellent gas barrier property. A gas barrier laminate comprising a layer (A) of a non-aqueous resin containing a metal element in the polymer skeleton thereof, and a layer (B) of a polycarboxylic acid-type polymer in which an ionic crosslinking is formed with a polyvalent metal among the carboxyl groups.

Growing community of inventors

Kanagawa, Japan

Tomohiro Miyai