Mitsubishi Chemical Corporation

Mitsubishi Petrochemical Company Limited

Tomoatsu Iwakura

Naohiro Nojiri

Yukio Sakai

Isao Teshigahara

Nariyasu Kanuka

Makoto Takiguchi

Kohei Sarumaru

Hidekazu Miyagi

Katsumi Nakashiro

Yoshiaki Saotome

Yukako Kawakatsu

Takako Imamoto

Akikazu Watanabe

Toshimichi Ito

Yasuo Yoshino

Mikio Mori

Nariyasu Kunuka

A composite oxide catalyst for the oxidation of an olefin containing Mo and Bi as essential components, characterized in that it has a specific surface area of 5 to 25 m/g and a pore volume of 0.2 to 0.7 cc/g, and has a pore diameter distribution wherein the volume of the pores having a pore diameter of 0.03 to 0.1 &#x3bc;m accounts for 30% or more of the total pore volume, the volume of the pores having a pore diameter of 0.1 to 1 &#x3bc;m accounts for 20% or more of the total pore volume, and the volume of the pores having a pore diameter of less than 0.03 &#x3bc;m is 10% or less of the total pore volume; a composite oxide catalyst for use in the vapor phase catalytic oxidation of acrolein or methacrolein or the like which comprises Mo, Bi and a halogen; either of the above two composite oxide catalysts which comprises Mo, Bi, Fe, Si and an element selected from alkali metals and thallium, and optionally Co, Ni, Mg, Ca, Zn, Ce, Sm, a halogen, B, P, As and W; a method for preparing any of the above composite catalysts; and a method for using any of the above composite oxide catalysts.

Composite oxide catalyst and method for preparation thereof

Composite oxide catalyst and method of producing the same

A process for producing an alkylene glycol which comprises a step of reacting an alkylene oxide with water in the presence of a catalyst, wherein the catalyst comprises an anion-exchange resin comprising: a polymer of a vinylaromatic compound as a substrate; and quaternary ammoniums group each bonded to the respective aromatic groups of the polymer substrate via a connecting group having a chain length of three or more atoms.

Process for producing alkylene glycol

A method for dehydrogenation of a hydrocarbon, which comprises selectively oxidizing hydrogen in a gas mixture which is obtained by subjecting a feed hydrocarbon to a dehydrogenation reaction in the presence of a dehydrogenation catalyst and which comprises a dehydrogenated hydrocarbon, an unreacted feed hydrocarbon and hydrogen, by contacting the gas mixture with an oxygen-containing gas in the presence of an oxidation catalyst, and further subjecting a hydrocarbon-containing gas obtained by the oxidation reaction to a dehydrogenation reaction, wherein a catalyst comprising a component having platinum and/or palladium supported on a carrier obtained by calcining at least one member selected from the group consisting of tin oxide, titanium oxide, tantalum oxide and niobium oxide, at a temperature of from 800.degree. C. to 1,500.degree. C., is used as the oxidation catalyst.

Method for dehydrogenation of hydrocarbon

A catalyst for oxidation of hydrogen, which is characterized in that: A. it is a catalyst having platinum supported on alumina; B. said alumina has a BET specific surface area of from 0.5 to 6 m.sup.2 /g; and C. said alumina has an ammonia adsorption of at most 5 .mu.mol/g, is used at the time of producing an unsaturated hydrocarbon by dehydrogenation of a hydrocarbon, whereby hydrogen present in the gas mixture can selectively be oxidized, and thus, the yield can be improved particularly when styrene is produced by dehydrogenation of ethylbenzene.

Catalyst for oxidation of hydrogen, method for selective oxidation of

A catalyst for oxidizing ethylene and producing ethylene oxide, said catalyst being prepared by pretreating a porous carrier with a solution containing a lithium compound and a cesium compound, thereafter, impregnating a solution containing a silver compound and a cesium compound in the pretreated porous carrier and then heat-treating the impregnated porous carrier. The use of the catalyst of this invention provides high selectivity in the production of ethylene oxide by the vapor contact oxidation of ethylene.

Catalyst for production of ethylene oxide

A catalyst for the production of ethylene oxide which contains silver, tungsten, cesium and, in some cases, an alkaline metal other than cesium, an alkaline-earth metal, a rare-earth metal, and/or metal selected from Groups I B, II B, III B, IV A, IV B, V A, V B and VI A of the Periodic Table and tellurium. The use of the catalyst of this invention provides high selectivity in the production of ethylene oxide by the vapor contact oxidation of ethylene.

Catalyst for production of ethylene oxide and process for producing the

A silver-deposited catalyst for the production of ethylene oxide by the oxidation of ethylene, said catalyst comprising

Silver-deposited catalyst for production of ethylene oxide

A silver-deposited catalyst for production of ethylene oxide by oxidizing ethylene, having high selectivity and long life, is provided by this invention. The catalyst is characterized by a combination of (a) catalyst ingredients comprising silver and a cation component selected at least from sodium, potassium, rubidium and cesium, and (b) a carrier composed mainly of alpha-alumina, said carrier having a surface area of 0.6 to 2 m.sup.2 /g, a water absorption of 20 to 50%, a silica content of 0.5 to 12% by weight, a silica content, per m.sup.2 /g of surface area, of 0.5 to 12, preferably 1 to 8, and a sodium content of 0.08 to 2% by weight.

A process for producing silver oxalate, which comprises reacting

Process for producing silver oxalate

A method for producing an alkenylbenzene by catalytically dehydrogenating an alkylbenzene non-oxidatively in the presence of steam in the reaction zone comprising a fixed-bed of potassium-containing dehydrogenation catalyst particles, wherein the potassium-containing dehydrogenation catalyst particles are prevented from powdering by (a) using a fixed-bed comprising particles of at least two kinds of potassium-containing dehydrogenation catalyst with respectively different potassium contents and (b) arranging the catalyst particles so that those with higher potassium content are not disposed on the inlet side of said catalyst bed with respect to the reaction.

Growing community of inventors

Mie, Japan

Tomoatsu Iwakura