Mitsubishi Chemical Industries Limited

Hitachi, Ltd.

Mitsubishi Kasei Corporation

Mitsubishi Chemical Corporation

Canon Kabushiki Kaisha

Tomio Yoneyama

Masaharu Kaneko

Shuji Imazeki

Mikio Sato

Akio Mukoh

Hiroshi Takimoto

Tetsuo Ozawa

Hideo Sano

Masahiro Yamada

Masatsune Kobayashi

Yuko Suga

Konoe Miura

Junko Iwanami

Yukichi Murata

Tokuya Ohta

Masami Kadowaki

Ryuichi Hasegawa

Tomohiro Chino

Minoru Masuda

Akio Mukoo

Junichi Oizumi

Masaaki Nishimura

Akira Kajikawa

Tokuya Ohata

An anisotropic dye film having high dichromatic properties is provided. An anisotropic dye film wherein the period d attributable to molecular stacking is at most 3.445 &#x212b;, and the column length L thereof is at least 105 &#x212b;. The anisotropic dye film preferably has a degree of orientation of the molecular stacking axes of at least 85% and a film thickness of at most 30 &#x3bc;m, and is formed by a wet film-forming method. Since it has a molecular alignment suitable to develop a dichroic ratio, it provides high dichromatic properties. A polarizing element having this anisotropic dye film is excellent in heat resistance, light fastness and polarizing performance.

Dyes for anisotropic dye films, dye compositions for anisotropic dye films, anisotropic dye films and polarizing elements

A metal chelated dyestuff for inkjet recording is described, which is a water soluble azo metal chelated compound formed from an azo compound represented by the following general formula (1) and a metal element and is good at the clearness of color tone, light resistance, indoor discoloring and fading property, solubility, storage stability, and the like.

Metal chelated dyestuff for inkjet recording and aqueous inkjet recording liquid using the same

A dichroic azo dye represented by general formula �I! ##STR1## wherein D.sup.1 and D.sup.2 each represents an optionally substituted phenyl group or an aromatic heterocyclic group; W represents a connecting group comprising a linear polycyclic aromatic group; X represents a group selected from the group consisting of --OCH.sub.2 --, --CH.sub.2 0--, --OOC--, --COO--, --CH.sub.2 NR--, and --NRCH.sub.2 --, where R represents a hydrogen atom or a methyl group; Z.sup.1 to Z.sup.12 each represents a hydrogen atom, a halogen atom, a methyl group, or a methoxy group, or Z.sup.2 and Z.sup.3, Z.sup.5 and Z.sup.6, Z.sup.8 and Z.sup.9, and Z.sup.11 and Z.sup.12 are bonded to each other to form an aliphatic ring, an aromatic ring, or a nitrogen-containing aromatic ring; and m and n each represents a number of 0 to 2. A liquid-crystal composition containing the above dye and a liquid-crystal element employing the composition are also disclosed.

Dichroic dye liquid crystal composition containing the dye, and

Dichroic dye, and liquid-crystal composition and liquid-crystal display

A recording liquid excellent in print quality, light resistance, and water resistance which is characterized in that it contains an aqueous medium and at least one dye selected from the dyes represented by general formulae [I] to [V]: ##STR1## (wherein R.sub.1 and R.sub.2 each represents H, CH.sub.3, or OCH.sub.3 ; R.sub.3 represents H, Cl,CH.sub.3, or OCH.sub.3 ; R.sub.4 represents an alkyl group having 1 to 6 carbon atoms, a phenyl group, a tolyl group, or an anisyl group; R.sub.5 represents H, a phenyl group which may be substituted with a COOM group, or an alkyl group having 1 to 3 carbon atoms which is substituted with a COOM group; R.sub.6 represents H or an alkyl group having 1 to 3 carbon atoms which is substituted with a COOM group; X represents SO.sub.3 M or COOM; Y represents --CO-- or --SO.sub.2 --; m represents 1 or 2; n represents 0 or 1; A represents a phenylene group which may have one or more members selected from the group consisting of an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, an amino group, a --COOM group, a hydroxyl group, an --SO.sub.3 M group, and a halogen atom; and M represents an alkali metal, an ammonium group, or an organic amine salt.)

Recording liquid

A recording liquid comprising an aqueous medium and at least one dye selected from dyes, free acid forms of which are represented by formulae (I) and (II): ##STR1## The symbols in formulae (I) and (II) are defined in the specification.

A recording liquid for ink jet recording, which comprises an aqueous medium, a pigment and, as a dispersant, at least one member selected from the group consisting of compounds of the following formula (I) to (X): ##STR1## wherein R.sup.1 is a C.sub.8-20 alkyl group, m is an integer of from 1 to 3, and M is Na or NH.sub.4, ##STR2## wherein R.sup.2 is a C.sub.8-20 alkyl group, n is an integer of from 1 to 3, and M is Na or NH.sub.4, ##STR3## wherein each of R.sup.3 and R.sup.4 is a C.sub.6-16 alkyl or alkenyl group, and M is Na or NH.sub.4, ##STR4## wherein R.sup.5 is a C.sub.10-20 alkyl or alkenyl group, and M is Na or NH.sub.4, ##STR5## wherein R.sup.6 is a C.sub.6-16 alkyl or alkenyl group, and M is Na or NH.sub.4, ##STR6## wherein R.sup.7 is a C.sub.10-20 alkyl or alkenyl group, and M is Na or NH.sub.4, ##STR7## wherein R.sup.8 is a C.sub.10-20 alkyl or alkenyl group, R.sup.9 is a C.sub.1-4 alkyl group and R.sup.10 is a C.sub.1-3 alkylene group, and M is Na or NH.sub.4, ##STR8## wherein R.sup.11 is a C.sub.6-18 alkyl group, p is an integer of from 1 to 15, and M is Na or NH.sub.4, ##STR9## wherein R.sup.12 is a methyl group or a hydrogen atom, q is an integer of 1 or 2, r is an integer of from 1 to 8, and M is Na or NH.sub.4, and ##STR10## wherein t is an integer of from 1 to 10, R.sup.13 is a C.sub.10-20 alkyl or alkenyl group, and M is Na or NH.sub.4.

Recording liquid for ink jet recording

A recording medium comprising a non-porous substrate and a coating layer formed thereon, said coating layer comprising a carboxyl group-containing ionomer-type hydrophilic urethane resin and organic and/or inorganic fine particles.

Recording medium

A recording liquid comprising from 0.2 to 12% by weight, based on the total weight of the recording liquid, of a water-soluble dyestuff, from 0.5 to 25% by weight, based on the total weight of the recording liquid, of at least one member selected from the group consisting of compounds of the following formulas I, II and III, and an aqueous medium: ##STR1## wherein l is a number of from 4 to 20, ##STR2## wherein R is a lower alkyl group or a phenyl group, and each of m and n is a number of from 4 to 20, and ##STR3## wherein X is a halogen atom, and p is a number of from 4 to 20.

A guest-host type liquid crystal composition comprising one or more host liquid crystals and dissolved therein one or more pleochroic dyes having a trans-4-substituted cyclohexyl group, preferably in an amount of 70% by mole or more of said trans-4-substituted cyclohexyl group among 4-substituted cyclohexyl groups, can afford a liquid crystal display device improved in display contrast and good stability due to no photochemical reaction of the liquid crystal composition.

Guest-host type liquid crystal composition

A naphthalene trisazo compound represented by the general formula (I) or (II): ##STR1## wherein A and B each represents a substituted or unsubstituted benzene or naphthalene ring; m represents zero or 1; and M represents an alkali metal atom, ammonium or H.Am (wherein Am represents an amine); or ##STR2## wherein X represents a hydrogen atom, a lower alkyl group, a phenyl group or a phenyl group substituted by --SO.sub.3 M; m represents zero or 1; M represents an alkali metal atom, ammonium or H.Am (wherein Am represents an amine); A, B and C each represents a substituted or an unsubstituted benzene or naphthalene ring, provided that B and C do not represent a naphthalene ring at the same time. A recording liquid containing these compounds is suitable for use in an ink-jet recording system.

Amino sulfonaphtholtrisazo compounds and recording liquids containing

A black recording liquid suitable for use in ink-jet recording or as an ink for writing instruments comprises at least two water-soluble dyes and a liquid medium. Each of the dyes satisfies the condition defined by the following expression [I], and a mixture of these dyes satisfies the condition defined by the following expression [II]. ##EQU1## In these expressions, a* and b* are chromaticness indices defined in the CIE 1976 (L*, a*, b*) space, i indicates the ith dye of the dyes used together, and n is an integer of 2 or more.

Water-soluble dye composition and recording liquid containing the same

A liquid crystal composition containing azo dyes represented by the formula (I.sub.0) ##STR1## wherein X represents ##STR2## A.sup.1 represents --O-- or --NH--; R.sup.1 represents a hydrogen atom, an alkyl group, an alkoxyalkyl group, an aryloxyalkyl group, a dialkylaminoalkyl group, an arylaminoalkyl group, a cycloalkyl group, an alkoxy group, an alkoxyalkoxy group, an arylalkoxy group, an aryl group, a halogen atom or a group of ##STR3## D.sup.1 and D.sup.2 each represents an aromatic group which does not contain an ionic group;

Liquid crystal composition containing azo dyes

A naphthalenedisazoic dye represented by general formula (I); ##STR1## wherein Q represents ##STR2## or a naphthalene group substituted by --SO.sub.3 M; R represents a methyl group, a methoxy group, an ethoxy group; X represents a hydrogen atom, a phenyl group substituted by --SO.sub.3 M; m represents 1 or 2; n represents 1 when X represents a hydrogen atom and n represents zero when X represents a phenyl group substituted by --SO.sub.3 M, wherein X represents a hydrogen atom and m represents 1 when Q represents a naphthalene group substituted by --SO.sub.3 M; and M represents an alkali metal atom, an ammonium, or H.A (wherein A represents an amine), and a recording liquid containing the dye. The recording liquid is suitable for use in an ink-jet recording system.

Disazoic dye and recording liquid containing the same

A liquid crystal composition comprising a host liquid crystal material and at least one guest novel anthraquine dye dissolved in said host liquid crystal material has a high order parameter, sufficient solubility in the host liquid crystal and high stability.

Growing community of inventors

Yokohama, Japan

Tomio Yoneyama