Idemitsu Petrochemical Co., Ltd.

Tohru Yukumoto

Atsushi Fujii

Akira Funaki

Katsumi Uchiyama

Masahiro Akamatsu

Osamu Tohya

Kenichi Fujiwara

Tomohiro Nagao

A producing apparatus is used, in which a metallic endless belt having a mirror face is wound on and extends between a first cooling roller covered with an elastic member and a second cooling roller, and a third cooling roller having a mirror face on its surface and touching the first cooling roller through a molten thermoplastic resin sheet and the endless belt oriented therebetween to hold the molten thermoplastic resin sheet pressed with the endless belt. While the temperature of the third cooling roller and the endless belt directly touching the molten thermoplastic resin sheet is retained at less than 50&deg; C. and more than the dew-point, the molten thermoplastic resin sheet is guided into the area between the first and third cooling rollers to touch the endless belt, touching the first cooling roller, and the third cooling roller at approximately the same time, and the molten thermoplastic resin sheet is touch-rolled on the face and cooled by the first and third cooling rollers along a nip width of more than or the same as 5 mm during the elastic deformation of the elastic member, caused by a pressing force between the first and third cooling rollers, and subsequently, the molten thermoplastic resin sheet is cooled by touch-rolling the face to the third cooling roller with the endless belt.

Producing method of a thermoplastic resin sheet and producing apparatus thereof

A polyethylene type soft transparent resin sheet according to the present invention includes a layer made of a polyethylene resin and has the following characteristics: (a) tensile modulus of 20 to 1000 MPa; (b) number of foreign substances having a refractivity different from the amorphous resin composition occupying a major part of the volume fraction of the sheet at any cross section of the sheet is less than or the same as 500/mm and the average length of the foreign substance being less than or the same as 10 &mgr;m; and (c) the surface roughness Ra of at least one surface is less than or the same as 0.2 &mgr;m. The polyethylene type resin is a copolymer of ethylene and a polar group substituted ethylene such as ethylene-vinyl acetate copolymer, ethylene-ethylacrylate copolymer and so on.

Soft transparent polyethylene resin sheet and process for producing the same

Producing method of a thermoplastic resin sheet and producing apparatus therefor

A method produces a decorative sheet with the use of an apparatus having a metallic endless belt that is wound on a first roller and a second roller, and an emboss roller that is placed to abut through the metallic endless belt onto the first roller. The method includes the steps of: adhering a first resin sheet having a pictured layer onto the metallic endless belt abutting the first roller; running the first resin sheet, adhered onto the metallic endless belt, along the outer circumferential face of the emboss roller; guiding a second resin sheet, moltenly extruded from a molten-resin extrusion means, between the emboss roller and the metallic endless belt abutted to the first roller; laminating and joining the second resin sheet to the first resin sheet; and embossing patterns onto the second resin sheet with the emboss roller during the laminating and joining step for the first and second resin sheets.

Method for producing a decorative sheet and apparatus for producing the same

A first thermoplastic resin film is laid on a heated endless belt to be moved together with the endless metal belt, a second thermoplastic resin film is superposed on the first thermoplastic resin film laid on the belt, and the first and second thermoplastic resin films laid on the belt are touch-rolled by a combination of the belt and a second roller to be laminated. The second thermoplastic resin film can be superposed on the first thermoplastic resin film laid on the belt after being touched to the second roller. A thermally produced molding is obtained by heat treating the laminated thermoplastic resin film.

Method for producing a laminated thermoplastic resin film, a laminated

A method is provided for producing a thermoplastic resin sheet or film by hot-melting and then cooling a thermoplastic resin to form a sheet or film. The thermoplastic resin sheet or film is moved so that it is pressed against the outer surface of an external heated roll and against a heated, endless metal belt. The endless metal belt is disposed at one end around a moving, internal heating roll and at an opposite end thereof around a moving, internal cooling roll. The internal heating roll heats the endless metal belt to a temperature higher than the softening point of the thermoplastic resin and higher than the temperature of the external heating roll to thermally adhere the thermoplastic resin sheet or film to the external heated roll or the heated, endless metal belt. The thermoplastic resin sheet or film is then moved along on the external heated roll or belt into a high temperature zone. The thermoplastic resin sheet or film is then released from the contact with the external heated roll and released from contact with the endless metal belt in a low temperature zone. The thermoplastic resin sheet or film is then peeled from the endless metal belt. Methods are also provided for producing a laminate of two or more thermoplastic resin sheets or films. The above methods provide non-stretched thermoplastic resin sheets, films or laminates with high-quality surfaces, which are suitable for wrapping foods and medicines.

Method for producing thermoplastic resin sheet or film

A laminated resin sheet consisting of (a) at least one layer of an ethylene-vinyl alcohol copolymeric resin (EVOH resin), (b) at least one layer of a hot-melt adhesive resin and (c) at least one layer of a polystrene-based resin, the layer (b) being interposed between the layers (a) and (c) to serve to adhesively bond them together. The laminated sheet has excellent moldability only when the EVOH resin has a thermal characteristic specified in terms of the integrated value of the peak areas in a diagram obtained by the DSC (differential scanning calorimetry) measurement in the course of temperature elevation. The sheet may be formed into a vessel having a multilayered wall structure by hot molding.

Process of shaping a vessel having a multilayered wall structure

A method for producing a thermoplastic resin sheet or film, wherein a raw resin material containing one or more of the following additives: a nucleating agent, fine powder of a high melting point polymer, a petroleum resin, a terpene resin and an organic peroxide (and/or a crystalline polypropylenic copolymer) is melted under heat to form a resin sheet or film, the resulting resin sheet or film is brought into contact with and adhered to the outer surface of a cooling roll having a mirror-finished surface or the outer surface of an endless metal belt having a mirror-finished surface and then it is moved along with the roll or the belt, thereafter it is inserted, pressed and cooled between the outer surface of the cooling roll and the outer surface of the endless metal belt. The non-oriented sheet or film thus produced has a high surface gloss, a high surface smoothness and a high transparency and is suitable for wrapping foods and medicines.

Disclosed is a laminated resin sheet consisting of (a) at least one layer of an ethylene-vinyl alcohol copolymeric resin (EVOH resin), (b) at least one layer of a hot-melt adhesive resin and (c) at least one layer of a polystyrene-based resin, the layer (b) being interposed between the layers (a) and (c) to serve to adhesively bond them together. The laminated sheet has excellent moldability only when the EVOH resin has a thermal characteristic specified in terms of the integrated value of the peak areas in a diagram obtained by the DSC (differential scanning calorimetry) measurement in the course of temperature elevation.

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Himeji, Japan

Tohru Yukumoto