Daiso Co., Ltd.

Sharp Kabushiki Kaisha Corporation

Tohru Kitamura

Kazuhiko Sakaguchi

Yutaka Shiomi

Mitsuhiro Koden

Tomoaki Kuratate

Yoshikazu Takehira

Fumiaki Funada

Naoya Kasai

A ferroelectric liquid crystal device having a pair of substrates each provided with voltage applying means, an orientation control layer formed on at least one of the substrates, and a layer of ferroelectric liquid crystal composition disposed between the pair of substrates, the ferroelectric liquid crystal composition comprising at least one compound (a) having an optically active group of the formula (I): ##STR1## at least one compound (b) which is reverse to the compound (a) in the direction of a helical pitch induced in a nematic phase and at least one liquid crystal compound (c) exhibiting a smectic C phase, the liquid crystal composition exhibiting at least a smectic C phase, smectic A phase and nematic phase.

Ferroelectric liquid crystal display

Liquid crystalline compounds having an optically active .gamma.-lactone ring of the general formula (A): ##STR1## wherein R.sup.1 is a group selected from the class consisting of ##STR2## n and e are each independently 0 or 1, R.sup.3 is an alkyl group having 1 to 15 carbon atoms or an alkenyl group having 2 to 15 carbon atoms, said alkyl and alkenyl groups having each optionally one or more asymmetric carbon atoms, X and Y are each hydrogen atom, a halogen atom or a cyano group, R.sup.2 is an alkyl group having 1 to 15 carbon atoms or an alkenyl group having 2 to 15 carbon atoms, said alkyl and alkenyl groups having each optionally one or more asymmetric carbon atoms, and * means an asymmetric carbon atom, a liquid crystal composition containing the same and an element for opto-electronics devices comprising the liquid crystal composition.

Liquid crystalline compounds, liquid crystal compositions containing the

A ferroelectric liquid crystal device having a pair of substrates each provided with voltage application means, an orientation control layer formed on at least one of the substrates, and a layer of ferroelectric liquid crystal composition formed between the pair of substrates, the device being characterized in that the ferroelectric liquid crystal composition comprises at least one compound (a) having an optically active group of the formula (I): ##STR1## and at least one compound (b) which is reverse to the compound (a) in the direction of a helical pitch induced in a nematic phase, the liquid crystal composition exhibiting at least a smectic C phase, smectic A phase and nematic phase at least 20 .mu.m in helical pitch.

Ferroelectric liquid crystal device

Liquid crystalline compounds having an optically active .gamma.-lactone ring of the general formula (A): ##STR1## wherein R.sup.1 is a group selected from the class consisting of ##STR2## n and e are each independently 0 or 1, R.sup.3 is an alkyl group having 1 to 15 carbon atoms or an alkenyl group having 2 to 15 carbon atoms, said alkyl and alkenyl groups having each optionally one or more asymmetric carbon atoms, X and Y are each hydrogen atom, a halogen atom or a cyano group, R.sup.2 is an alkyl group having 1 to 15 carbon atoms or an alkenyl group having 2 to 15 carbon atoms, said alkyl and alkenyl groups having each optionally one or more asymmetric carbon atoms, and * means an asymmetric carbon atom, a liquid crystal composition Containing the same and an element for opto-electronics devices comprising the liquid crystal composition.

An optically active glycidyl ether, which is useful in making .gamma.-lactone containing liquid crystalline compounds, the ether having the following formula: ##STR1## wherein R.sup.1 is a group selected from the group consisting of ##STR2## n is 0 or 1; e is 1; R.sup.3 is an alkyl group having 1 to 15 carbon atoms; and the symbol * is an asymmetric carbon atom.

Liquid crystalline compounds and process for production thereof

A ferroelectric liquid crystal composition including: at least one optically active compound of the formula (I): ##STR1## where R.sup.1 and R.sup.2 are, the same or different, a straight or branched chain alkyl group having 1 to 15 carbon atoms, k represents an integer of 0 or 1, and * represents an asymmetric carbon atom; and at least one compound selected from the group consisting of: compounds of the formula (II): ##STR2## where R.sup.3 and R.sup.4 are a straight or branched chain alkyl or alkoxy group having 1-15 carbon atoms, ##STR3## and ##STR4## each represents ##STR5## X represents --O--, --CO-- or a single bond, m and n are independently an integer of 0 or 1; compounds of the formula (III): ##STR6## where R.sup.5 and R.sup.6 are, the same or different, a straight or branched chain alkyl or alkoxy group having 1-15 carbon atoms, and p is an integer of 0 or 1; said ferroelectric liquid crystal composition exhibiting at least nematic phase, smectic A phase and smectic C phase.

Ferroelectric liquid crystal composition and liquid crystal device using

Liquid crystalline compounds having an optionally active .gamma.-lactone ring of the formula: ##STR1## wherein R.sup.1 is a group selected from the group consisting of ##STR2## n and e are each independently 0 or 1; R.sup.3 is an alkyl group having 1 to 15 carbon atoms; R.sup.2 is a group of the formula: --(CO).sub.m --R.sup.4 ; m is 0 or 1; R.sup.4 is hydrogen atom or an alkyl having 1 to 15 carbon atoms; and the symbol * is an asymmetric carbon atom, and an intermediate thereof, and process for the production of the same.

A ferroelectric liquid crystal composition comprising at least one compound represented by the formula (I): ##STR1## wherein R.sup.1 and R.sup.2 are, the same or different, a straight-chain or branched-chain alkyl group having 1 to 15 carbon atoms, and each asterisk represents an asymmetric carbon atom, and at least one compound represented by the formula (II): ##STR2## wherein R.sup.3 and R.sup.4 are, the same or different, a straight-chain or branched-chain alkyl group having 1 to 15 carbon atoms, and each asterisk represents an asymmetric carbon atom, and liquid crystal device incorporating same.

Ferroelectric liquid crystal composition and liquid crystal device

An improved ferroelectric liquid crystal device comprising a pair of substrates each provided with voltage applying means, at least one of the substrates having an orientation control layer, and a ferroelectric liquid crystal layer disposed between the pair of substrates, the ferroelectric liquid crystal layer comprising specific .gamma.-lactone derivatives, which is useful as a liquid crystal shutter, liquid crystal display device or the like.

Liquid crystalline compounds having an optically active .gamma.-lactone ring of the formula: ##STR1## wherein R.sup.1 is a group selected from the group consisting of ##STR2## n and e are each independently 0 or 1; R.sup.3 is an alkyl group having 1 to 15 carbon atoms; R.sup.2 is a group of the formula: --(CO).sub.m --R.sup.4 ; m is 0 or 1; R.sup.4 is hydrogen atom or an alkyl having 1 to 15 carbon atoms; and the symbol * is an asymmetric carbon atom, and an intermediate thereof, and process for the production of the same.

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Kyoto, Japan

Tohru Kitamura