Teijin Limited

Dai-ichi Kogyo Seiyaku Co., Ltd.

Togi Suzuki

Kiyokazu Tsunawaki

Shinji Ohwaki

Osamu Wada

Akio Kimura

Shigeo Mori

Setsuo Yamada

Kohichi Iohara

Tadashi Konishi

Noboru Chujo

Wataru Funakoshi

Norihiro Minemura

Takatoshi Kuratsuji

Shigenobu Kobayashi

Kiyoshi Nawata

Masahiro Shiozaki

Hironori Yamada

Kimihiro Ogawa

Hajime Izawa

Masaaki Sekimoto

Katsuo Kunugi

Saori Aoyama

An aromatic polyester filament yarn dyed in a chromatic color and exhibiting a bright and clear shade, wherein the filaments of the yarn are composed of an aromatic polyester polymer copolymerized with an aliphatic dicarboxylic acid component and/or an aliphatic diol component and having a glass transition temperature (Tg) of not higher than 65&deg; C., the yarn appears as a whole to have been dyed visually uniformly despite that uneven build-up of dye exists in the individual filaments in the longitudinal direction, and the yarn has a chromaticness C* of at least 36 expressed in the L*a*b* color specification system when dyed with an aqueous dispersion of 1% o.w.f. of a disperse dye based on C.I. Disperse Blue 56.

Dyed filament yarn having clear hue

Method of filling hollow fiber with gel

An aromatic polyester shaped article, for example, a fiber, a film or a sheet, having excellent hydrophilic characteristics and a durable antistatic property, sweat-absorbing property and soil-releasing property, is prepared from an aromatic polyester composition comprising (a) 100 parts by weight of an aromatic polyester resin, (b) 0.2 to 30 parts by weight a water-insoluble polyoxyethylene type polyether represented by the formula (I): ##STR1## wherein Z is a residue of an organic compound having 1 to 6 active hydrogen atoms and a molecular weight of 300 or less, R.sup.1 is an unsubstituted or substituted alkylene group having at least 6 carbon atoms, R.sup.2 is H, a monovalent hydrocarbon group having 1 to 40 carbon atoms, or a monovalent acyl group having 2 to 40 carbon atoms, k is 1 to 6, l satisfies the relationship: k x l.gtoreq.70 and m is 1 or more, and having a number average molecular weight of 5000 to 16000, said R.sup.1, R.sup.2, l and m in the formula (I) satisfying the following relationships: ##EQU1## wherein [M(R.sup.1 O)] is a molecular weight of the R.sup.1 O and [M(R.sup.2)] is a molecular weight of the R.sup.2.

Hydrophilic aromatic polyester fiber

An aromatic polyester shaped article, for example, a fiber, a film or a sheet, having excellent hydrophilic characteristics and a durable antistatic property, sweat-absorbing property and soil-releasing property, is prepared from an aromatic polyester composition comprising (a) 100 parts by weight of an aromatic polyester resin, (b) 0.2 to 30 parts by weight a water-insoluble polyoxyethylene type polyether represented by the formula (I):

Aromatic polyester resin composition and fiber

An improved copolyester fiber capable of being dyed with cationic dyes and having an excellent brightness, heat resistance and a satisfactory mechanical strength comprises a copolyester resin comprising a polymerization product of at least one aromatic dicarboxylic acid compound, at least one alkylene diol compound and at least one quaternary phosphonium organic sulfonate of the formula (I): ##STR1## wherein A=an aromatic or aliphatic radical, X.sup.1 =H or an ester-forming organic radical, X.sup.2 =an ester-forming organic radical, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 =an alkyl or aryl radical, n=1 or more, and having an [.eta.].sub.f of 0.5 or more, the copolyester fiber having a silk factor of 25 or more and exhibiting the number of scission of backbone chains of the copolyester molecules of 140.times.10.sup.23 or less per 10.sup.6 g of fiber when wet heat-treated in a solution of 0.4 g/l of acetic acid in distilled water at 130.degree. for 60 minutes.

Cationically-dyeable, thermally-resistant copolyester fiber comprising

A polyester fiber having a superior stainproof property comprises at least one fiber-forming polyester copolymer comprising a backbone polyester polymer and at least one type of terminal substituent which blocks at least some of the terminals of the molecules of the backbone polyester polymer and which substituent consists of a polyoxyalkyleneglycol monoether group of the formula (I):

Stainproof polyester fiber

A fiber composed of a polyester having at least a part of terminals blocked with the residue of at least one specific metal sulfonate compound, where the amount of the blocked terminals is 1.3 to 4.0 mol % based on the dicarboxylic acid component of the polyester and the alkali dissolution speed constant is 3.3.times.10.sup.-9 to 6.5.times.10.sup.-9 cm/sec. This polyester has a good dyeability with a cationic dye and is excellent in the heat resistance and alkali resistance. The polyester fiber can be spun at a high speed or super high speed and can be false-twisted at a high temperature.

Modified polyester fiber and process for preparation thereof

A polyester composition with an excellent high-speed melt-spinning property, comprising

Polyester composition

Hollow water-absorbing polyester filaments each having a number of fine caves which are evenly distributed in at least a portion of the filament and through which the hollow is connected to the outside of the filament, are produced (1) by preparing hollow filaments from a blend of a principal polyester component and a cave-forming agent consisting of at least one member selected from:

Process for producing hollow water-absorbing polyester filaments

A dyed polyester fiber composite structure having an enhanced brilliance and/or color depth, comprises (A) a dyed porous polyester fiber which has been produced (1) by preparing a polyester resin from a dicarboxylic acid component and a glycol component in the presence of a pore-forming agent containing 0.3 to 3 molar % of at least one phosphorus compound based on the molar amount of the dicarboxylic acid component, (2) by converting the polyester resin to a polyester fiber in which fine particles of the pore-forming agent are dispersed, by treating the polyester fiber with an aqueous alkali solution so that at least 2% of the weight of the fiber is removed and a number of fine pores are formed in the fiber and (4) by dyeing the porous polyester fiber; and (B) a coating layer on the peripheral surface of the dyed porous polyester fiber, comprising a polymeric material having a smaller refractive index than that of the porous polyester fiber.

Dyed polyester fiber composite structure

Hollow water-absorbing polyester filaments each having a number of fine caves which are evenly distributed in at least a portion of the filament and through which the hollow is connected to the outside of the filament, are produced (1) by prepared hollow filaments from a blend of a principal polyester component and a cave-forming agent consisting of at least one member selected from:

Hollow water-absorbing polyester filament textile material

Hollow water-absorbing polyester filaments each having a number of fine caves which are evenly distributed in at least a portion of the filament and through which the hollow is connected to the outside of the filament, are produced (1) by preparing hollow filaments from a blend of a principal polyester component and a cave-forming agent consisting of at least one member selected from: (i) copolyesters containing an additional divalent organic sulfonic acid compound moiety of the formula (II): ##STR1## wherein Z is a trivalent aromatic or aliphatic hydrocarbon radical, M.sup.1 is H or metal atom, R.sup.1 is an ester-forming organic radical and R.sup.2 is an H atom or ester-forming organic radical; (ii) phosphorus compounds of the formula (III): ##STR2## wherein R.sup.3 is a monovalent organic radical, X is --OR.sup.4, wherein R.sup.4 is an H atom or a monovalent organic radical, --OM.sup.3, wherein M.sup.3 is a metal atom, or a monovalent organic radical, M.sup.2 is a metal atom and m=0 or 1, and; (iii) aromatic carboxy-sulfonic acid compounds of the formula (IV): ##STR3## wherein Y is an H atom or ester-forming organic radical, M.sup.4 and M.sup.5 each are a metal atom, respectively, and n=1 or 2, and (2) by removing the at least a portion of cave-forming agent and a portion of the principal polyester component from the resultant hollow filaments so as to form numerous concaves on the peripheral and hollow surfaces, numerous pores in the body of the filament, and numerous channels through which the pores are connected to each other and to the concaves, the concaves and pores having a longitudinal size of 50 times or less the lateral size thereof, which is 0.01 to 3 microns.

Hollow water-absorbing polyester filaments and a process for producing

Hollow water-absorbing polyester filaments, each having fine pores evenly distributed throughout the filament and extending approximately in parallel to the filament axis, are produced by melt-spinning a blend of a polyester and a pore-forming agent consisting of at least one sulfonate compound of the formula:

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Matsuyama, Japan

Togi Suzuki