Uop Lcc

Timothy M Cowan

Stephen R Dunne

Andrew S Zarchy

William Bachop Dolan

Mark M Davis

Kirit M Patel

Lawrence Tucker Kass

Dennis Reinertsen

A feedstream comprising nitrous oxide is purified by a pressure swing adsorption process employing a copurge with an oxygen-lean stream to produce a high purity nitrous oxide stream. The high purity nitrous oxide stream can be incorporated in a complex for the production of adipic acid to recover nitrous oxide from a dilute waste stream and pass the recovered nitrous oxide to a process for the production of phenol from an aromatic hydrocarbon. Unreacted nitrous oxide from the phenol production step acid can be recovered in a second, or vent PSA step, and combined with the recovery of byproduct nitrous oxide waste streams from the production of adipic for the overall recovery of nitrous oxide, thereby significantly reducing nitrous oxide emissions from the production of adipic acid.

Nitrous oxide purification by pressure swing adsorption

A process for treating an engine exhaust gas stream is disclosed. The process involves arranging a catalyst bed and a molecular sieve bed side by side with a connecting pipe between and parallel to the two beds. When the engine is first started, the cool exhaust is flowed through the catalyst bed, then through the connecting pipe, then through the molecular sieve bed and finally discharged to the atmosphere. When the molecular sieve bed reaches a temperature of about 150.degree. C. to about 200.degree. C. the exhaust stream is diverted such that it is first flowed through the molecular sieve bed, to desorb the adsorbed hydrocarbons, and then through the catalyst bed and finally discharged to the atmosphere. Finally, when all the hydrocarbons are desorbed from the molecular sieve bed, the exhaust stream is diverted such that it is flowed through the catalyst bed and then discharged to the atmosphere.

Combination catalyst/adsorber system for treating an engine exhaust gas

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St. Charles, IL, United States of America

Timothy M Cowan