Xerox Corporation

Gm Global Technology Operations LLC

Bar-ilan University

Timothy J Fuller

John F Yanus

Damodar M Pai

Markus Rudolf Silvestri

Ram S Narang

Dale S Renfer

Michael R Schoeneweiss

Yuhua Tong

William W Limburg

Ion C Halalay

Paul J DeFeo

Kathleen M Carmichael

Kenny-Tuan Dinh

Thomas W Smith

David J Luca

Frank D Coms

Mahmoud H Abd Elhamid

Dennis J Prosser

Huoy-Jen Yuh

Samuel Kaplan

Satchidanand Mishra

Anthony M Horgan

Kent J Evans

John S Chambers

Cindy C Chen

Merlin E Scharfe

Min-Hong Fu

Robert C U Yu

James R Larson

Michael Jon Levy

Craig S Gittleman

Bob Ross Powell

Edward F Grabowski

David H Pan

Lanhui Zhang

Gerald W Fly

Tao Xie

Ihor W Tarnawskyj

Richard H Blunk

John Graham

Michael K Budinski

Richard B Lewis

Frank J Bonsignore

Brian K Brady

Chu-Heng Liu

Mark William Verbrugge

Stephan V Drappel

Gary Alan Kneezel

Robert C Yu

Gerald M Fletcher

Youssef Morcos Mikhail

John W Spiewak

John S Berkes

Michael K Georges

Gayatri Vyas

Geoffrey M T Foley

William M Schwarz

Matthew J Beutel

T Edwin Freeman

Alexander N Klymachyov

Daniel John Lisi

Keith E Newman

Guerino G Sacripante

Santokh Singh Badesha

Beng S Ong

Peter Michael Kazmaier

Ping Liu

Kock-Yee Law

Joseph C Mammino

James Daniel Mayo

James McConnell Duff

William H Wayman

Bing R Hsieh

Raymond W Wong

Timothy P Bender

Robert D Bayley

Katsumi Daimon

Robert J Gruber

Heiko Rommelmann

Cheng-Kuo Hsiao

Daniel A Foucher

Richard L Post

Michael P Balogh

Stephen F Pond

Linda L Ferrarese

Fang Dai

Thomas R Hoffend

Anne M Dailly

Milan Stolka

Steven C Hart

Nancy Lynn Belknap

Melvin D Croucher

Weizhong Zhao

Martin A Abkowitz

Alan Richard Kuntz

Almon P Fisher

Kathleen M McGrane

Timothy L Lincoln

James M Markovics

Terry L Bluhm

A thermal interface member configured to be disposed between a heat sink and a heat-releasing device includes a thermal interface member. The thermal interface member has a thermally conductive, cure-in-place, polymer foam pad configured to maintain uniform contact with each of the heat sink and the heat-releasing device. The thermal interface member is additionally configured to absorb the thermal energy released by the heat-releasing device and direct the released thermal energy to the heat sink. The polymer foam pad has a matrix structure including at least one of anisotropic and isotropic thermally conductive anisotropic filler material, and is characterized by foam material density below 0.5 g/cm.

Cure-in-place lightweight thermally-conductive interface

Electroactive materials having a nitrogen-containing carbon coating and composite materials for a high-energy-density lithium-based, as well as methods of formation relating thereto, are provided. The composite electrode material includes a silicon-containing electroactive material having a substantially continuous nitrogen-containing carbon coating formed thereon. The method includes contacting the silicon-containing electroactive material and one or more nitrogen-containing precursor materials and heating the mixture. The one or more nitrogen-containing precursor materials include one or more nitrogen-carbon bonds and during heating the nitrogen of the one or more nitrogen-carbon bonds with silicon in the silicon-containing electroactive material to form the nitrogen-containing carbon coating on exposed surfaces of the silicon-containing electroactive material.

Method for making silicon-containing composite electrodes for lithium-based batteries

Methods and devices for providing an even distribution of waste heat in a vehicular battery pack, including a battery pack, a cold plate, a coolant reservoir, a support structure between the battery pack and the coolant reservoir, and a conformable thermal interface material for filling the space between cells of the battery pack and the coolant reservoir so as to provide thermal contact between the cells and the coolant reservoir for distributing the waste heat. In addition, methods and devices for providing an even distribution of waste heat and structural support in any heat source to heat sink for applications such as small devices such as computer motors.

Cure in place thermal interface material

A membrane electrode assembly component for a fuel cell includes a generally planar gas-permeable body having opposed first and second faces defining in-plane and through-plane directions, a side face extending about an outer perimeter of the body and adjoining each of the first and second faces, and an active region bounded by the first and second faces and an active region perimeter defined generally within the outer perimeter. The active region includes a distribution of cerium-zirconium oxide nanofibers dispersed across at least one of the in-plane and through-plane directions, wherein the cerium-zirconium oxide nanofibers have a molecular formula of CeZrO.

Cerium nanofiber additives for improved fuel cell durability

A thermal interface member may comprise a substrate having a first surface and an opposite second surface, an electrically conductive layer disposed on the first surface of the substrate, and an electrically resistive layer disposed on the first surface of the substrate. The substrate may comprise a compliant electrically insulating and thermally conductive material including a polymeric matrix phase and a dispersed phase of thermally conductive particles. The conductive layer may be patterned into a first electrode and a second electrode spaced apart from the first electrode on the first surface of the substrate. The resistive layer may be in electrical contact with the first and second electrodes of the conductive layer and may comprise a resistive material having a positive resistance temperature coefficient and a resistance that increases with an increase in temperature.

Thermal interface member and method of making the same

A method of making a metal organic framework (MOF)-polymer composite material includes forming a homogeneous solution comprising a solvent, a metal salt, a polymer which is soluble in the solvent, and a reactant which can be synthesized to provide an organic linker during formation of a MOF structure, synthesizing the homogeneous solution to crystallize a MOF structure in the homogenous solution to yield the MOF structure distributed in a remainder solution, applying an antisolvent to the remainder solution with the MOF structure distributed in the remainder solution to form a polymer-rich phase, where the MOF structure is integrated into the polymer matrix during forming of the polymer matrix to produce a MOF-polymer composite material. The MOF-polymer composite material can be formed on a substrate to produce a MOF structured object, which can be a membrane, film, or other object.

Metal organic framework (MOF) structured object and method

Methods of scavenging acid in a lithium-ion electrochemical cell are provided. An electrolyte solution that contains an acid or is capable of forming the acid is contacted with a polymer comprising a nitrogen-containing acid-trapping moiety selected from the group consisting of: an amine group, a pyridine group, and combinations thereof. The nitrogen-containing acid-trapping moiety scavenges acidic species present in the electrolyte solution by participating in a Lewis acid-base neutralization reaction. The electrolyte solution comprises a lithium salt and one or more solvents and is contained in the electrochemical cell that further comprises a first electrode, a second electrode having an opposite polarity from the first electrode, and a porous separator. Lithium ions can be cycled through the separator and electrolyte solution from the first electrode to the second electrode, where acid generated during the cycling is scavenged by the polymer comprising a nitrogen-containing acid-trapping moiety.

Acid-scavenging functional separators for power performance of lithium ion electrochemical cells

Electrochemical cells that cycle lithium ions and methods for suppressing or minimizing deposition of transition metal ions at negative electrodes are provided. The electrochemical cells include a positive electrode, a negative electrode, a separator disposed therebetween, and an electrolyte system including one or more lithium salts, one or more solvents, and at least one additive complexing compound. The at least one additive complexing compound includes an alkyl group having greater than or equal to 4 carbon atoms and less than or equal to 22 carbon atoms and a transition metal ion trapping group. The at least one additive compound associates with a surface of the separator via van der Waal's interactive forces and is further capable of complexing with transition metal ion within the electrochemical cell to sequester or tether the ions generated by contaminants to minimize or suppress the deposition of transition metal cations on the negative electrode.

Iron ion trapping van der Waals gripper additives for electrolyte systems in lithium-ion batteries

Electrochemical cells that cycle lithium ions and methods for suppressing or minimizing dendrite formation are provided. The electrochemical cells include a positive electrode, a negative electrode, and a separator disposed therebetween. At least one transition metal ion-trapping moiety, including one or more polymers functionalized with one or more trapping groups, may be included within the electrochemical cell as a coating, pore filler, substitute pendant group, or binder. The one or more trapping groups may be selected from the group consisting of: crown ethers, siderophores, bactins, ortho-phenanthroline, iminodiacetic acid dilithium salt, oxalates malonates, fumarates, succinates, itaconates, phosphonates, and combinations thereof, and may bind to metal ions found within the electrochemical cell to minimize or suppress formation of dendrite protrusions on the negative electrode.

Polymeric ion traps for suppressing or minimizing transition metal ions and dendrite formation or growth in lithium-ion batteries

Disclosed are fuel cell systems, reinforced membrane electrode assemblies, and methods for fabricating a reinforced membrane electrode assembly. In an example, a disclosed method includes depositing an electrode ink onto a first substrate to form a first electrode layer, and applying a first porous reinforcement layer onto a surface of the first electrode layer to form a first catalyst coated substrate. The method also includes depositing a first ionomer solution onto the first catalyst coated substrate to form a first ionomer layer. A membrane porous reinforcement layer is applied onto a surface of the first ionomer layer to form a reinforced membrane layer.

Reinforced electrode assembly

A lithium ion battery is provided that includes: a positive electrode; a negative electrode; a microporous polymer separator soaked in an electrolyte solution, the microporous polymer separator disposed between the positive electrode and the negative electrode; and a transition metal cation trap which is i) incorporated as a binder in any of the positive electrode or the negative electrode, ii) deposited onto a surface of any of the positive electrode or the negative electrode, iii) incorporated into the microporous polymer separator, iv) deposited onto a surface of the microporous polymer separator, or v) included as an additive in the electrolyte solution. The transition metal cation trap is a siderophore.

Lithium ion battery with transition metal ion traps

A lithium ion battery includes a positive and a negative electrode, and a nanoporous or microporous polymer separator soaked in electrolyte solution and disposed between the electrodes. At least two different chelating agents are included and selected to complex with: i) two or more different transition metal ions; ii) a transition metal ion in two or more different oxidation states; or iii) both i) and ii). The at least two different selected chelating agents are to complex with transition metal ions in a manner sufficient to not affect movement of lithium ions across the separator during operation of the battery. The chelating agents are: dissolved or dispersed in the electrolyte solution; grafted onto the polymer of the separator; attached to the binder material of the negative and/or positive electrode; disposed within pores of the separator; coated on a surface of the separator; and/or coated on a surface of an electrode.

Lithium ion battery

A method for forming a membrane includes a step of dissolving a lithium salt in a solution including an ionomer that includes protogenic groups to form a modified solution. A membrane is formed from the solution containing the lithium salt and the ionomer that includes protogenic groups. The membrane is dried and then contacted with water to form a plurality of pores therein.

Reverse osmosis membranes made with PFSA ionomer and ePTFE

A lithium ion battery includes positive and negative electrodes, and a nanoporous or microporous polymer separator soaked in an electrolyte solution, between the positive electrode and the negative electrode. Chelating agent(s) are included to complex with transition metal ions while not affecting movement of lithium ions across the separator during operation of the lithium ion battery. The chelating agents are: dissolved in the electrolyte solution; grafted onto the polymer of the separator; attached to the binder material of the negative and/or positive electrode; coated on a surface of the separator; and/or coated on a surface of the negative and/or positive electrode. The chelating agents are selected from: ion traps in molecular form selected from polyamines, thiols and alkali metal salts of organic acids; polymers functionalized with alkali metal salts of organic acids; polymers functionalized with nitrogen-containing functional groups; and polymers functionalized with two or more functional groups.

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Pittsford, NY, United States of America

Timothy J Fuller