Cyclics Corporation

Auterra, Inc.

Timothy A Thompson

Peter David Phelps

Kyle Erik Litz

Jennifer L Vreeland

Jonathan Rankin

Thomas W DeLancey

Steven J Winckler

Yi-Feng Wang

Donald G Le Grand

Jonathan P Rankin

Thomas W Delancey

A reaction system and method for removing heteroatoms from oxidized-heteroatom-containing hydrocarbon streams and products derived therefrom are disclosed. An oxidized-heteroatom-containing hydrocarbon feed is reacted in a reaction system thereby forming non-ionic hydrocarbon products. The products derived therefrom are useful as transportation fuels, lubricants, refinery intermediates, or refinery feeds.

Reaction system and products therefrom

Processes for isolating, formulating, and shaping macrocyclic oligoesters were developed which allow efficient production of macrocyclic oligoesters substantially free from solvent, which may include additives, fillers, and catalysts.

Isolation, formulation, and shaping of macrocyclic oligoesters

Organo-titanate catalysts are prepared that are useful to catalyze depolymerization of a polyester to produce macrocyclic oligoesters substantially free from macrocyclic co-oligoesters.

Organo-titanate catalysts for preparing pure macrocyclic oligoesters

In one aspect, the invention relates to processes for producing substantially free-flowing shapes of macrocyclic oligoester, wherein the freshly-shaped macrocyclic oligoester is maintained at elevated temperature for a sufficient time. In certain embodiments, the shapes are heated in water, thereby avoiding agglomeration during the heating process itself. In another aspect, the invention relates to processes for removing solvent from a solution of macrocyclic oligoester using elevated temperature, reduced pressure, or both, thereby obviating the need for an anti-solvent to precipitate the macrocyclic oligoester from the solution. Other aspects of the invention related to shaping of macrocyclic oligoesters are presented as well.

Processes for shaping macrocyclic oligoesters

Processes for isolating, formulating, and shaping macrocyclic oligesters were developed which allow efficient production of macrocyclic oligoesters substantially free from solvent, which may include additives, fillers, and catalysts.

Isolation, formulation and shaping of macrocyclic oligoesters

Acid impurities, such as carboxylic acid-terminated polymers, are removed from macrocyclic oligoesters with ion exchange resins, resulting in macrocyclic oligoesters that are substantially free of acid impurities. The ion exchange resins can be regenerated anew and reused by washing the resins with various wash solutions. Macrocyclic oligoesters substantially free of acid impurities polymerize to much higher molecular weight polyesters than macrocyclic oligoesters containing acid impurities.

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Clifton Park, NY, United States of America

Timothy A Thompson