Quantumscape Corporation

Quantumscape Battery, Inc.

Quantrumscape Corporation

Tim Holme

Niall Donnelly

Sriram Rangarajan Iyer

Zhebo Chen

Cheng-Chieh Chao

Oleh Karpenko

Will Hudson

Mohit Singh

Adrian Winoto

Dong Hee Anna Choi

Lei Cheng

Kian Kerman

Marie A Mayer

Gilbert N Riley, Jr

Shuang Li

Amal Mehrotra

William Hudson

William H Gardner

Gengfu Xu

Kim Van Berkel

Arnold Allenic

Weston Arthur Hermann

Yang Li

Wes Hermann

Joseph Han

Larry Beck

Cheng Chieh Chao

Tommy Huang

Christopher Dekmezian

Sunil Mair

Rainer Johannes Fasching

Eric Tulsky

Harsh Maheshwari

Nick Perkins

Friedrich B Prinz

Jagdeep Singh

Deepika Singh

Will Gardner

Wei Zhang

Bradley Owen Stimson

David Eric Berkstresser

Aram Yang

Jingning Shan

Tiffany Ho

David Cao

Anna Choi

Phil Weicker

Brian Pevear

Jay Underwood

Ken Desmond

Drake Nguyen

The present invention provides an energy storage device comprising a cathode region or other element. The device has a major active region comprising a plurality of first active regions spatially disposed within the cathode region. The major active region expands or contacts from a first volume to a second volume during a period of a charge and discharge. The device has a catholyte material spatially confined within a spatial region of the cathode region an spatially disposed within spatial regions not occupied by the first active regions. The device has a protective material formed overlying exposed regions of the cathode material to substantially maintain the sulfur species within the catholyte material. Also included is a novel dopant configuration of the LiMPS(LMPS) [M=Si, Ge, and/or Sn] containing material.

Solid state catholyte or electrolyte for energy storage devices

Provided herein are detect-free solid-state separators which are useful as Liion-conducting electrolytes in electro-chemical cells and devices, such as, but not limited to, rechargeable batteries. In some examples, the separators have a Liion-conductivity greater than 1*10S/cm at room temperature.

Translucent and transparent separators

Setter plates are fabricated from Li-stuffed garnet materials having the same, or substantially similar, compositions as a garnet Li-stuffed solid electrolyte. The Li-stuffed garnet setter plates, set forth herein, reduce the evaporation of Li during a sintering treatment step and/or reduce the loss of Li caused by diffusion out of the sintering electrolyte. Li-stuffed garnet setter plates, set forth herein, maintain compositional control over the solid electrolyte during sintering when, upon heating, lithium is prone to diffuse out of the solid electrolyte.

Lithium stuffed garnet setter plates for solid electrolyte fabrication

Set forth herein are processes and materials for making ceramic thin films by casting ceramic source powders and precursor reactants, binders, and functional additives into unsintered thin films and subsequently sintering the thin films under controlled atmospheres and on specific substrates.

Processes and materials for casting and sintering green garnet thin films

The instant disclosure sets forth multiphase lithium-stuffed garnet electrolytes having secondary phase inclusions, wherein these secondary phase inclusions are material(s) which is/are not a cubic phase lithium-stuffed garnet but which is/are entrapped or enclosed within a lithium-stuffed garnet. When the secondary phase inclusions described herein are included in a lithium-stuffed garnet at 30-0.1 volume %, the inclusions stabilize the multiphase matrix and allow for improved sintering of the lithium-stuffed garnet. The electrolytes described herein, which include lithium-stuffed garnet with secondary phase inclusions, have an improved sinterability and density compared to phase pure cubic lithium-stuffed garnet having the formula LiLaZrO.

Lithium-stuffed garnet electrolytes with secondary phase inclusions

The present disclosure sets forth battery components for secondary and/or traction batteries. Described herein are new solid-state lithium (Li) conducting electrolytes including monolithic, single layer, and bi-layer solid-state sulfide-based lithium ion (Li) conducting catholytes or electrolytes. These solid-state ion conductors have particular chemical compositions which are arranged and/or bonded through both crystalline and amorphous bonds. Also provided herein are methods of making these solid-state sulfide-based lithium ion conductors including new annealing methods. These ion conductors are useful, for example, as membrane separators in rechargeable batteries.

Lithium, phosphorus, sulfur, and iodine containing electrolyte and catholyte compositions, electrolyte membranes for electrochemical devices, and annealing methods of making these electrolytes and catholytes

Set forth herein are electrolyte compositions that include both organic and inorganic constituent components and which are suitable for use in rechargeable batteries. Also set forth herein are methods and systems for making and using these composite electrolytes.

Composite electrolytes

The disclosure herein relates to rechargeable batteries and solid electrolytes therefore which include lithium-stuffed garnet oxides, for example, in a thin film, pellet, or monolith format wherein the density of defects at a surface or surfaces of the solid electrolyte is less than the density of defects in the bulk. In certain disclosed embodiments, the solid-state anolyte, electrolyte, and catholyte thin films, separators, and monoliths consist essentially of an oxide that conducts Li+ ions. In some examples, the disclosure herein presents new and useful solid electrolytes for solid-state or partially solid-state batteries. In some examples, the disclosure presents new lithium-stuffed garnet solid electrolytes and rechargeable batteries which include these electrolytes as separators between a cathode and a lithium metal anode.

Lithium-stuffed garnet electrolytes with a reduced surface defect density and methods of making and using the same

Set forth herein are electrochemical cells which include a negative electrode current collector, a lithium metal negative electrode, an oxide electrolyte membrane, a bonding agent layer, a positive electrode, and a positive electrode current collector. The bonding agent layer advantageously lowers the interfacial impedance of the oxide electrolyte at least at the positive electrode interface and also optionally acts as an adhesive between the solid electrolyte separator and the positive electrode interface. Also set forth herein are methods of making these bonding agent layers including, but not limited to, methods of preparing and depositing precursor solutions which form these bonding agent layers. Set forth herein, additionally, are methods of using these electrochemical cells.

Solid electrolyte separator bonding agent

Set forth herein are compositions comprising A·(LiBH)·B·(LiX)·C·(LiNH), wherein X is fluorine, bromine, chloride, iodine, or a combination thereof, and wherein 0.1≤A≤3, 0.1≤13≤4, and 0≤C≤9 that are suitable for use as solid electrolyte separators in lithium electrochemical devices. Also set forth herein are methods of making A·(LiBH)·B·(LiX)·C·(LiNH) compositions. Also disclosed herein are electrochemical devices which incorporate A·(LiBH)·B·(LiX)·C·(LiNH) compositions and other materials.

Electrolyte separators including lithium borohydride and composite electrolyte separators of lithium-stuffed garnet and lithium borohydride

A battery management system (BMS) for a vehicle includes a module for estimating the state of a rechargeable battery, such as its state of charge, in real time. The module includes a learning model for predicting the state of a battery based on the vehicle's usage and related factors unique to the vehicle, in addition to a sensed voltage, current and temperature of a battery.

Predictive model for estimating battery states

Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (&#x3c;50 um) free standing membranes of an ionically conducting material for use as a catholyte, electrolyte, and, or, anolyte, in an electrochemical device, a battery component (positive or negative electrode materials), or a complete solid state electrochemical energy storage device. Also, the methods set forth herein disclose novel sintering techniques, e.g., for heating and/or field assisted (FAST) sintering, for solid state energy storage devices and the components thereof.

Garnet materials for li secondary batteries and methods of making and using garnet materials

Garnet materials for Li secondary batteries and methods of making and using garnet materials

Set forth herein are processes for making lithium-stuffed garnet oxides (e.g., LiLaZrO, also known as LLZO) that have passivated surfaces comprising a fluorinate and/or an oxyfluorinate species. These surfaces resist the formation of oxides, carbonates, hydroxides, peroxides, and organics that spontaneously form on LLZO surfaces under ambient conditions. Also set forth herein are new materials made by these processes.

Lithium-stuffed garnet thin films and pellets having an oxyfluorinated and/or fluorinated surface and methods of making and using the thin films and pellets

Growing community of inventors

Mountain View, CA, United States of America

Tim Holme