Taiwan Semiconductor Manufacturing Comp. Ltd.

United Microelectronics Corp.

Prolific Technology Inc.

Tien-Wei Yu

Chia-Ming Tsai

Chandrashekhar Prakash Savant

Shahaji B More

Ming-Te Chen

Chin-Cheng Chien

Yu-Shu Lin

Ming-Hua Chang

Ke-Chih Liu

Szu-Hao Lai

Kin Shun Chong

Chun-Yuan Wu

Shih-Chi Lin

Chih-Wei Wang

Cheng-Sheng Chan

Zack Chong

Tsai-Yu Wen

Yuh-Ta Fan

Hsin-Kuo Hsu

Yu-Ren Wang

Tsuo-Wen Lu

Chin-I Liao

Shin-Chi Chen

Chih-Yueh Li

Tsung-Mu Yang

Tien-Chen Chan

Chun-Jen Chen

I-Cheng Hu

Kuan-Yu Lin

I-Ming Lai

Chiun-Shiu Chen

Chieh-Lung Wu

Fong-Lung Chuang

Chun-Shiu Chen

Chun-Hsu Chen

Ren-Jie Duan

Gate fabrication techniques are disclosed herein for providing gate stacks and/or gate structures (e.g., high-k/metal gates) with improved profiles (e.g., minimal to no warping, bending, bowing, and necking and/or substantially vertical sidewalls), which may be implemented in various device types. For example, gate fabrication techniques disclosed herein provide gate stacks with stress-treated glue layers having a residual stress that is less than about 1.0 gigapascals (GPa) (e.g., about −2.5 GPa to about 0.8 GPa). In some embodiments, a stress-treated glue layer is provided by depositing a glue layer over a work function layer and performing a stress reduction treatment, such as an ion implantation process and/or an annealing process in a gas ambient, on the glue layer. In some embodiments, a stress-treated glue layer is provided by forming at least one glue sublayer/metal layer pair over a work function layer, performing a poisoning process, and forming a glue sublayer over the pair.

Gate structure fabrication techniques for reducing gate structure warpage

A semiconductor device includes a gate structure disposed over a channel region and a source/drain region. The gate structure includes a gate dielectric layer over the channel region, one or more work function adjustment material layers over the gate dielectric layer, and a metal gate electrode layer over the one or more work function adjustment material layers. The one or more work function adjustment layers includes an aluminum containing layer, and a diffusion barrier layer is disposed at at least one of a bottom portion and a top portion of the aluminum containing layer. The diffusion barrier layer is one or more of a Ti-rich layer, a Ti-doped layer, a Ta-rich layer, a Ta-doped layer and a Si-doped layer.

Method of manufacturing semiconductor devices and semiconductor devices

The present disclosure describes a method for the formation of gate stacks having two or more titanium-aluminum (TiAl) layers with different Al concentrations (e.g., different Al/Ti ratios). For example, a gate structure can include a first TiAl layer with a first Al/Ti ratio and a second TiAl layer with a second Al/Ti ratio greater than the first Al/Ti ratio of the first TiAl layer.

Metal gate structures for field effect transistors

In a method of manufacturing a semiconductor device, a gate dielectric layer is formed over a channel region made of a semiconductor material, a first work function adjustment material layer is formed over the gate dielectric layer, an adhesion enhancement layer is formed on the first work function adjustment material layer, a mask layer including an antireflective organic material layer is formed on the adhesion enhancement layer, and the adhesion enhancement layer and the first work function adjustment material layer are patterned by using the mask layer as an etching mask. The adhesion enhancement layer has a higher adhesion strength to the antireflective organic material layer than the first work function adjustment material layer.

A method includes providing a structure having a substrate, a semiconductor channel layer over the substrate, an interfacial oxide layer over the semiconductor channel layer, and a high-k gate dielectric layer over the interfacial oxide layer, wherein the semiconductor channel layer includes germanium. The method further includes forming a metal nitride layer over the high-k gate dielectric layer and performing a first treatment to the structure using a metal-containing gas. After the performing of the first treatment, the method further includes depositing a silicon layer over the metal nitride layer; and then annealing the structure such that a metal intermixing layer is formed over the high-k gate dielectric layer. The metal intermixing layer includes a metal oxide having metal species from the high-k gate dielectric layer and additional metal species from the metal-containing gas.

Semiconductor devices with metal intercalated high-k capping

The present disclosure describes a method for forming gate stack layers with a fluorine concentration up to about 35 at. %. The method includes forming dielectric stack, barrier layer and soaking the dielectric stack and/or barrier layer in a fluorine-based gas. The method further includes depositing one or more work function layers on the high-k dielectric layer, and soaking at least one of the one or more work function layers in the fluorine-based gas. The method also includes optional fluorine drive in annealing process, together with sacrificial blocking layer to avoid fluorine out diffusion and loss into atmosphere.

Gate stack treatment

The present disclosure describes method to form a semiconductor device having a gate dielectric layer with controlled doping and to form multiple devices with different V. The method includes forming a gate dielectric layer on a fin structure, forming a buffer layer on the gate dielectric layer, and forming a dopant source layer including a dopant on the buffer layer. The gate dielectric layer includes an interfacial layer on the fin structure and a high-k dielectric layer on the interfacial layer. The method further includes doping a portion of the high-k dielectric layer adjacent to the interfacial layer with the dopant, removing the dopant source layer and the buffer layer, forming a dopant pulling layer on the gate dielectric layer, and tuning the dopant in the gate dielectric layer by the dopant pulling layer.

In a method of manufacturing a semiconductor device, a gate dielectric layer is formed over a channel region, a first conductive layer is formed over the gate dielectric layer, a shield layer is formed over the first conductive layer forming a bilayer structure, a capping layer is formed over the shield layer, a first annealing operation is performed after the capping layer is formed, the capping layer is removed after the first annealing operation, and a gate electrode layer is formed after the capping layer is removed.

A device includes a semiconductor region, an interfacial layer over the semiconductor region, the interfacial layer including a semiconductor oxide, a high-k dielectric layer over the interfacial layer, and an intermixing layer over the high-k dielectric layer. The intermixing layer includes oxygen, a metal in the high-k dielectric layer, and an additional metal. A work-function layer is over the intermixing layer. A filling-metal region is over the work-function layer.

Transistors with reduced defect and methods of forming same

The present disclosure describes method to form a semiconductor device with a diffusion barrier layer. The method includes forming a gate dielectric layer on a fin structure, forming a work function stack on the gate dielectric layer, reducing a carbon concentration in the work function stack, forming a barrier layer on the work function stack, and forming a metal layer over the barrier layer. The barrier layer blocks a diffusion of impurities into the work function stack, the gate dielectric layer, and the fin structure.

Semiconductor device and manufacturing method thereof

The present disclosure describes a semiconductor device having metal boundary trench isolation with electrically conductive intermediate structures acting as a metal diffusion barrier. The semiconductor structure includes a first fin structure and a second fin structure on a substrate, an insulating layer between the first and second fin structures, a gate dielectric layer on the insulating layer and the first and second fin structures, and a first work function stack and a second work function stack on the gate dielectric layer. The first work function stack is over the first fin structure and a first portion of the insulating layer, and the second work function stack is over the second fin structure and a second portion of the insulating layer adjacent to the first portion. The semiconductor structure further includes a conductive intermediate structure on the gate dielectric layer and between the first and second work function stacks.

Trench isolation with conductive structures

A semiconductor device includes a gate structure disposed over a channel region, and a source/drain region. The gate structure includes a gate dielectric layer over the channel region, a first work function adjustment layer, over the gate dielectric layer, a first shield layer over the first work function adjustment layer, a first barrier layer, and a metal gate electrode layer. The first work function adjustment layer is made up of n-type work function adjustment layer and includes aluminum. The first shield layer is made of at least one selected from the group consisting of metal, metal nitride, metal carbide, silicide, a layer containing one or more of F, Ga, In, Zr, Mn and Sn, and an aluminum containing layer having a lower aluminum concentration than the first work function adjustment layer.

A semiconductor device includes a substrate, a semiconductor fin, a gate structure, and source/drain structures. The semiconductor fin extends upwardly from the substrate. The gate structure is across the semiconductor fin and includes a high-k dielectric layer over the semiconductor fin, a fluorine-containing work function layer over the high-k dielectric layer and comprising fluorine, a tungsten-containing layer over the fluorine-containing work function layer, and a metal gate electrode over the tungsten-containing layer. The source/drain structures are on the semiconductor fin and at opposite sides of the gate structure.

Growing community of inventors

Kaohsiung, Taiwan

Tien-Wei Yu