Sabic Global Technologies B.v.

Sabic Innovative Plastics IP B.v.

Tianhua Ding

Ganesh Kannan

Wei Zhang

Husnu Alp Alidedeoglu

Dake Shen

Sung Dug Kim

Chris Van Der Weele

Hongtao Shi

Rodney Fonseca

Tukaram Gunale

Yuzhen Yang

Ying Xi

Gunale Tukaram

Disclosed is a process for the manufacture of a polyalkylene terephthalate such as polybutylene terephthalate. In particular, the process comprises employing a titanium-containing catalyst formed by the reaction product of tetraalkyl titanate and a complexing agent comprising a phosphorous, nitrogen or boron atom. The process is used to prepare polyalkylene terephthalates characterized by improved hydrostability, as well as compositions derived therefrom.

Hydrostability of polycarbonate polyester composition

Disclosed is a process for the manufacture of a modified polyalkylene terephthalate such as modified polybutylene terephthalate. In particular, the process comprises employing a titanium-containing catalyst formed by the reaction product of tetraalkyl titanate and a complexing agent comprising a phosphorous, nitrogen or boron atom. The process is used to prepared modified polyalkylene terephthalates characterized by improved hydrostability, as well as compositions and compositions derived therefrom.

Hydrostability of polycarbonate polybutylene terephthalate composition

Disclosed is a process for the manufacture of a modified polyalkylene terephthalate such as modified polybutylene terephthalate. In particular, the process comprises employing a titanium-containing catalyst formed by the reaction product of tetraalkyl titanate and a complexing agent comprising a phosphorous, nitrogen or boron atom. The process is used to prepare modified polyalkylene terephthalates characterized by improved hydrostability, as well as compositions derived therefrom.

Hydrostability of polybutylene terephthalate composition

Disclosed herein is a polyalkylene terephthalate flame retardant composition, comprising (a) 30 to 60 parts by weight of a polyalkylene terephthalate or a mixture of polyalkylene terephthalates, (b) 0.25 to 2.5 parts by weight of an antidrip agent, (c) 4 to 18 parts by weight of melamine polyphosphate (hereinafter 'MPP'), and (d) 12 to 26 parts by weight of poly(pentabromobenzylacrylate) (hereinafter 'PBBPA'), provided that the combined amount of MPP and PBBPA is at least 18 parts by weight and less than or equal to 30 parts by weight and provided that the composition is substantially antimony free. The invention also provides processes for making such compositions as well as articles derived therefrom.

Antimony-free flame retardant polyester composition

Hydrostability of polyester composition

Disclosed is an improved process for preparing a modified polyalkylene terephthalate by melt polycondensation followed optionally by solid state condensation comprising reacting an alkylene diol and polyethylene terephthalate, wherein polymerization occurs in the presence of a catalyst complex formed by reaction of tetra(alkyl) titanate and a compound selected from phosphorus-containing compounds, nitrogen-containing compounds, boroncontaining compounds, and combinations thereof.

Process for the preparation of modified poly(alkylene terephthalate) employing an in-situ titanium-containing catalyst

A process of preparing a polyalkylene terephthalate comprising reacting an alkylene diol and an aromatic dicarboxy compound that is an aromatic dicarboxylic acid, aromatic dicarboxylic (C-C)alkyl ester, or a combination thereof, wherein ester interchange and polymerization occurs in the presence of a catalyst complex formed by the reaction of tetraisopropyl titanate and a boron, phosphorous or nitrogen-containing complexing agent, which catalyst can be synthesized in situ prior to ester interchange and introduced to a mixture of the alkylene diol and the aromatic dicarboxy compound prior to ester interchange.

Method for the preparation of polyalkylene terephthalate resin compositions employing titanium-containing catalyst complex

A process of preparing a modified polyalkylene terephthalate by melt polycondensation comprising reacting an alkylene diol and polyethylene terephthalate, wherein polymerization occurs in the presence of a catalyst complex formed by reaction of tetra(alkyl) titanate and a compound selected from phosphorus-containing compounds, nitrogen-containing compounds, boron-containing compounds, and combinations thereof.

Method for the preparation of modified poly(alkylene terephthalate) employing in situ titanium-containing catalyst

A thermoplastic polyester composition comprising, based on the total weight of the composition, a chlorine- and bromine-free combination of: from 40 to 60 wt % of a polyester; from 25 to 35 wt % of a reinforcing filler; from 2 to 8 wt % of a flame retardant synergist selected from the group consisting of melamine polyphosphate, melamine cyanurate, melamine pyrophosphate, melamine phosphate, and combinations thereof; from 5 to 15 wt % of a phosphinate salt flame retardant; from more than 0 to less than 5 wt % of an impact modifier component comprising a poly(ether-ester) elastomer and a (meth)acrylate impact modifier; from more than 0 to 5 wt % poly(tetrafluoroethylene) encapsulated by a styrene-acrylonitrile copolymer; from more than 0 to 2 wt % of a stabilizer; wherein the thermoplastic polyester composition contains less than 5 wt % of a polyetherimide.

Flame resistant polyester compositions, method of manufacture, and articles thereof

A thermoplastic polyester composition comprising, based on the total weight of the composition, a chlorine- and bromine-free combination of: from 40 to 60 wt % of a modified poly(1,4-butylene terephthalate); from 25 to 35 wt % of a reinforcing filler; from 2 to 8 wt % of a flame retardant synergist selected from the group consisting of melamine polyphosphate, melamine cyanurate, melamine pyrophosphate, melamine phosphate, and combinations thereof; from 5 to 15 wt % of a phosphinate salt flame retardant; from more than 0 to less than 5 wt % of an impact modifier component comprising a poly(ether-ester) elastomer and a (meth)acrylate impact modifier; from more than 0 to 5 wt % poly(tetrafluoroethylene) encapsulated by a styrene-acrylonitrile copolymer; from more than 0 to 2 wt % of a stabilizer; wherein the thermoplastic polyester composition contains less than 5 wt % of a polyetherimide.

Flame resistant polyester compositions, method of manufacture, and articles therof

A composition comprises, based on the total weight of the composition: from 20 to 90 wt. % of a polyester component comprising a modified poly(butylene terephthalate) copolymer that is derived from a poly(ethylene terephthalate) component; from 5 to 35 wt. % of a flame retardant phosphinate and/or a flame retardant diphosphinate; from 1 to 25 wt. % of a melamine polyphosphate, melamine cyanurate, melamine pyrophosphate, and/or melamine phosphate; from greater than zero to 50 wt. % of a glass fiber having a non-circular cross-section; and from 0 to 5 wt. % of an additive.

Reinforced polyester compositions, method of manufacture, and articles thereof

A thermoplastic polyester composition comprises, based on the total weight of the composition, from 20 to 95 wt. % of a polyester comprising a poly(alkylene terephthalate); from 1 to 35 wt. % of a phosphorous flame retardant consisting of a phosphinate of the formula (I)[(R)(R(PO)&#x2014;O]M&#x2003;&#x2003;(I),a diphosphinate of the formula (II)[(O&#x2014;POR)(R)(POR&#x2014;O)]M&#x2003;&#x2003;(II), and/ora polymer derived from the phosphinate of formula (I) or the diphosphinate of the formula (II); from 0.1 to less than 20 wt. % of a copolyetherester; from 0.1 to 5 wt. % of an anti-dripping agent; from 0 to 4.5 wt. % of a reinforcing fiber; and from 0 to 5 wt. % of an additive selected from the group consisting of a mold release agent, an antioxidant, a thermal stabilizer, and a UV stabilizer.

Thermoplastic polyester compositions, methods of manufacture, and articles thereof

A composition comprises, based on the total weight of the composition: from 20 to 90 wt. % of a polyester component comprising a poly(butylene terephthalate); from 5 to 35 wt. % of a flame retardant phosphinate of the formula (I)[(R)(R)(PO)&#x2014;O]M&#x2003;&#x2003;(I)a flame retardant diphosphinate of the formula (II)[(O&#x2014;POR)(R)(POR&#x2014;O)]M&#x2003;&#x2003;(II),and/or a flame retardant polymer derived from the flame retardant phosphinate of the formula (I) or the flame retardant diphosphinate of the formula (II); from 1 to 25 wt. % of a melamine polyphosphate, melamine cyanurate, melamine pyrophosphate, and/or melamine phosphate; from greater than zero to 50 wt. % of a glass fiber having a non-circular cross-section; and from 0 to 5 wt. % of an additive selected from the group consisting of a mold release agent, an antioxidant, a thermal stabilizer, an antioxidant, and a UV stabilizer; wherein the components have a combined total weight of 100 wt. %.

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Newburgh, IN, United States of America

Tianhua Ding