Basf Aktiengesellschaft

Basf Se Corporation

Thorsten Johann

Andreas Brodhagen

Joaquim Henrique Teles

Mark Duda

Klaus Ebel

Johann-Peter Melder

Ekkehard Schwab

Hartmut Hibst

Stephan Andreas Schunk

Götz-Peter Schindler

Torsten Mäurer

Radwan Abdallah

Sven Crone

Thomas Hill

Michael Limbach

Regina Benfer

Christian Walsdorff

Steffen Maas

Marcus Sigl

Gerhard Olbert

Klaus Harth

Martin Ernst

Holger Borchert

Thomas Krug

Manuel Danz

Eike Johannes Bergner

Markus Weber

Stefan Rittinger

Stephan Schlitter

Bernd Stein

Heiko Urtel

Michael Koch

Michael Steiniger

Tilman Sirch

Sebastian Storck

Andrey Karpov

Markus Siegert

Eckhard Ströfer

Jörg Pastre

Neven Lang

Georg Seeber

Christian Bartosch

Oliver Löber

Günter Wegner

Martin Fiene

Jens Klein

Marie Katrin Schroeter

Beatrice Roessler

Marcelo Daniel Kaufman Rechulski

Sabine Borchers

Todd C Spengeman

Soo Yin Chin

Daniela Rieck

Wolfgang Kanther

Sandra Magnus

Mauricio Grobys

Christiane Kuretschka

Xue Liu

Stefan Dietrich

Christian Almer

Gerhard KOPPENHÖFER

Process for the continuous preparation of an amine by reaction of a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary and secondary amines at a temperature in the range from 60 to 300&#xb0; C. in the presence of a catalyst comprising copper oxide and aluminum oxide, wherein the reaction takes place in the gas phase and the catalytically active composition of the catalyst before reduction with hydrogen comprises from 20 to 75% by weight of aluminum oxide (AlO), from 20 to 75% by weight of oxygen-comprising compounds of copper, calculated as CuO, from 0 to 2% by weight of oxygen-comprising compounds of sodium, calculated as NaO, and less than 5% by weight of oxygen-comprising compounds of nickel, calculated as NiO, and the shaped catalyst body has a pellet shape having a diameter in the range from 1 to 4 mm and a height in the range from 1 to 4 mm.

Method for the continuous production of an amine using an aluminum&#x2014;copper catalyst

The use of a supported noble metal catalyst obtainable by applying a sparingly soluble noble metal compound to a support from solution or suspension, and subsequently treating thermally, for preparing olefinically unsaturated carbonyl compounds.

Use of a supported catalyst containing precious metal for oxidative dehydrogenation

A process for isomerizing olefinically unsaturated alcohols over supported noble metal catalysts with a support based on carbon in an oxygenous atmosphere.

Method for isomerizing olefinically unsaturated alcohols

A process for preparing olefinically unsaturated carbonyl compounds by oxidative dehydrogenation in an oxygenous atmosphere over a supported catalyst which comprises gold and optionally further noble metals at temperatures in the range from 50 to 240&#xb0; C.

Method for producing olefinically unsaturated carbonyl compounds by oxidative dehydrogenation of alcohols

A method for dehydrogenating primary or secondary alcohols having 1 to 12 carbon atoms to give the corresponding aldehydes or ketones in which the alcohol is brought into contact with a catalytically active composition comprising an active component of the formulaPdBiYZ,where

Method for dehydrogenating alcohols

Processes comprising: (a) enantioselectively hydrogenating a staffing material comprising a component selected from geraniol, nerol and mixtures thereof to form optically active citronellol; (b) converting the optically active citronellol to optically active citronellal; (c) cyclizing the optically active citronellal to form a mixture comprising optically active isopulegol; and (d) subjecting the mixture to further processing comprising: (i) separating the optically active isopulegol from the mixture and hydrogenating the separated optically active isopulegol to form optically active menthol; or (ii) hydrogenating the optically active isopulegol in the mixture to form optically active menthol and separating the optically active menthol from the mixture.

Method for the production of menthol

A process for preparing 1-butene from 1-butane, which includes providing a n-butane-containing feed gas stream; introducing of the n-butane-containing feed gas stream into at least one dehydrogenation zone and nonoxidative catalytic dehydrogenation of n-butane; removing hydrogen, the low-boiling secondary constituents and optionally water vapor to give a Cproduct gas stream containing 10-80% by volume of n-butane, 5-40% by volume of 1-butene, 10-50% by volume of 2-butene, 0-40% by volume of butadiene and 0-10% by volume of further gas constituents; introducing the Cproduct gas stream containing 10-80% by volume of n-butane, 10-60% by volume of 1-butene, 15-60% by volume of 2-butene, 0-5% by volume of butadiene and 0-10% by volume of further gas constituents, into a selective hydrogenation zone and selective hydrogenation of butadiene to 1- and/or 2-butene to give stream consisting essentially of n-butane, 1-butene and 2-butene; and separating of the stream distillation into a desired product.

Process for preparing 1-butene

The present invention relates to a catalytically active composition comprising as active component The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.

Catalytically active composition and the use thereof in dehydration methods

The disclosure involves a process for preparing butadiene from n-butane. In the process, n-butane is first dehydrogenated autothermally under nonoxidative conditions to form a gas stream. The gas stream is then oxidatively dehydrogenated to form a second gas stream. From the second gas stream, a third gas stream containing n-butane, 2-butene and butadiene is obtained. From the third gas stream, a butadiene/butaine product stream is obtained and remaining n-butane and 2-butene is recycled into the first dehydrogenation zone.

Method for the production of butadiene

The disclosure involves a process for the preparation of butadiene and 1-butene. The process includes at least a first catalytic dehydrogenation of n-butane to obtain a gas stream which is followed by at least a second oxidative dehydrogenation to form a second gas stream. The second gas stream is then subjected to distillation and isomeration steps to obtain butadiene and 1-butene.

Method for the production of butadiene and 1-butene

A process for preparing 1-butene, which includes nonoxidatively, catalytically dehydrogenating n-butane to obtain a product gas stream of n-butane, 1-butene, 2-butene, butadiene, hydrogen, and secondary constituents; removing hydrogen and the secondary constituents to obtain a Cproduct gas stream; separating the Cproduct stream into a recycle stream of n-butane and a stream of 1-butene, 2-butene and butadiene by extractive distillation, and recirculating the recycle stream to the dehydrogenation zone; introducing the 1 -butene, 2-butene and butadiene stream into a selective hydrogenation zone and selective hydrogenation of butadiene to 1-butene and/or 2-butene to obtain a stream of 1-butene and 2-butene; introducing the 1-butene and 2-butene stream, and a circulating stream of 1-butene and 2-butene into a distillation zone and isolation of a product stream; and introducing the 2-butene-containing stream into an isomerization zone to obtain a circulating stream of 1-butene and 2-butene, and recirculating the circulating stream to the distillation zone.

Method for producing 1-butene

The disclosure relates to a process for preparing butadiene. The process involves nonoxidatively catalytically dehydrogenating butane to obtain a product gas stream containing butane, 1-butene, 2-butene, butadiene, hydrogen and secondary constituents. The 1-butene and 2-butene of the product gas stream is then oxidatively dehydrogenated to give a second gas stream containing butane,2-butene, butadiene, hydrogen, steam and secondary constituents. Next, the butane,2-butene and butadiene are separated from the second gas stream and the butane and 2-butene are then separated from the butadiene product. The butane and 2-butene are then recycled into the nonoxidative catalytic dehydrogenating zone.

Preparation of butadiene

The present invention relates to a process for preparing optically active aldehydes or ketones which have from 3 to 25 carbon atoms and at least one racemizable stereocenter by catalytic dehydrogenation of the corresponding optically active primary or secondary alcohols in the gas phase in the presence of a catalyst.

Method for producing optically active carbonyl compounds

Process for the catalytic hydrogenation of methylolalkanals of the general formula where Rand Rare each, independently of one another, a further methylol group or an alkyl group having from 1 to 22 carbon atoms or an aryl or aralkyl group having from 6 to 33 carbon atoms, in the liquid phase by means of hydrogen over a hydrogenation catalyst, wherein hydrogen is used in a molar ratio to methylolalkanal of greater than 1.

Hydrogenation of methylolalkanals

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Limburgerhof, Germany

Thorsten Johann