Bayer Technology Services Gmbh

Centrum Fur Angewandte Nanotechnologie (can) Gmbh

Nanosolutions Gmbh

Thorsten Heidelberg

Christiane Meyer

Burkhard Köhler

Werner Hoheisel

Markus Haase

Stephan Haubold

Kerstin Bohmann

Fernando Ibarra

Imke Kühl

Stefan Haubold

Stephan c/o Hanosolutions Gmbh Haubold

The present invention relates to a method for the production of nanoparticulate metal(III) vanadates or vanadate/phosophate mixed crystals, comprising the reaction in a reaction medium of a reactive vanadate source and optionally a phosphate source dissolvable or dispersible in the reaction medium and of a reactive metal(III) salt dissolvable or dispersible in the reaction medium under heating, wherein the reaction medium contains water and a polyol in a volume ratio of 20/80 to 90/10, and the particles thereby obtained. The synthesis provides a high yield of metal(III) vanadate or vanadate/phosphate having a narrow particle size distribution. Doped embodiments thereof are distinguished by excellent luminescence properties.

Synthesis of nanoparticles comprising metal (III) vanadate

A process for synthesizing nanoparticles, in particular metal salt nanoparticles. To the synthesis mixture is added a modifying reagent which binds, by means of a first functional group, to the nanoparticle surface and which carries a second functional group for binding to molecules which are specifically selected in dependence on the subsequent use of the nanoparticles. This dispenses with a postsynthetic, separate, application-specific modification step. A new substance class, the pentaalkyl iminobis(methylenephosphono)carboxylates, are particularly suitable for this purpose. These modifying reagents permit the nanoparticles to grow in a specifically controlled manner and, at the same time, modify the surface of the growing nanoparticles, (in-situ) during the synthesis, such that the particles can be very readily dissolved in a large number of solvents and carry functional groups for coupling on molecules, resulting in the particles having, immediately after having been synthesized, a certain all-round usability.

Production and use of in situ-modified nanoparticles

The invention relates to synthesis of nanoparticles, in particular to methods for producing nanoparticles with networks consisting of Z sulphate (Z=magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba) or the binary mixtures thereof). The inventive method consists in synthesising the nanoparticles by crystal growth from an ion Z source and a sulphate ion source in a liquid phase mixture. The invention produces Z sulphate nanoparticles having a small diameter and uniformly dispersible in water or other solvents in a simple way. Co-ordinating solvents like glycerine, glycol ethylene and other polyethylene glycols, polyalcohols or dimethylsulphoxide (DMSO) are used for the synthesis mixture.

Method for producing alkaline earth sulphate nanoparticles

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Hamburg, Germany

Thorsten Heidelberg