Basf Aktiengesellschaft

Thomas Wirth

Lambertus Manders

Wolfgang Gaschler

Hubertus Kroener

Volker Schaedler

Dirk Lawrenz

Ralf Brueckmann

Holger Schoepke

Juergen Hartmann

J&uuml;rgen Schmidt-Th&uuml;mmes

Roland Ettl

Bernhard Schuler

Hermann Seyffer

Peter Claassen

Hartmann F Leube

Stefan Kirsch

Berthold Sturm

Kai Olfermann

Titus Leman

Harald Nissler

A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M comprising styrene, butadiene, and if desired up to 30% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers other than styrene and butadiene; in a polymerization vessel by a monomer feed technique in the presence of a regulator system containing, based on 100% by weight of monomers, from 0.02 to 0.5% by weight of at least one hydrocarbon HC having from 6 to 20 carbon atoms, selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or 1-phenylallyl radical, and &#x3b1;-methylstyrene dimer, and from 0.3 to 2% by weight of an organic compound S containing at least one SH group wherein at least 30%, preferably at least 50%, in particular at least 80%, and with particular preference the entirety (or &#x3e;95%) of hydrocarbon HC is included in the initial charge to the polymerization vessel.

Method for producing aqueous styrene-butadiene-iv polymer dispersions

A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC selected from compounds having 6 to 20 carbon atoms which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from &#x3b1;-methylstyrene dimer comprises supplying the monomers to be polymerized to the polymerization reaction over the course of 3 hours.

Method for producing aqueous styrene-butadiene polymer dispersions

A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC having 6 to 20 carbon atoms, which is selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from &#x3b1;-methylstyrene dimer comprises including at least 30% of the hydrocarbon HC in the initial charge to the polymerization vessel and supplying the remainder of the hydrocarbon HC to the polymerization reaction in the course of that reaction.

Method for producing aqueous styrene-butadiene polymer dispersions III

A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC having 6 to 20 carbon atoms selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and &#x3b1;-methylstyrene dimer comprises raising, at a point in time when at least 70% of the monomers to be polymerized have been supplied to the polymerization reaction, the concentration of butadiene in the monomer feed for a period of at least 1% of the total feed time by at least 10% by weight, based on monomers in the feed.

Method for producing aqueous styrene-butadiene polymer dispersions II

A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M that comprises by a monomer feed technique that includes supplying to the polymerization reaction a regulator system containing,

Preparation of aqueous styrene-butadiene polymer dispersions

A process for impregnating base paper or fiber webs with an aqueous dispersion of a polymer of free-radically polymerizable compounds (monomers), which comprises from 0.1 to 5% by weight of the monomers being methacrylic acid.

Polymer dispersion for impregnating paper

The present invention provides paper coating slips comprising a low-crosslink copolymer as their binder.

Paper coating slips based on low-crosslink binders

Process for making a printing paper with binder mixtures for paper

Paper coating

Copolymers suitable for use as temporary surface protection for two- or three-dimensional structures and as sizing agents are based on C.sub.1 -C.sub.8 -alkyl acrylates and/or methacrylates and are obtainable by free radical emulsion or solution polymerization of

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Freinsheim, Germany

Thomas Wirth