The Clorox Company

Thomas S Coyne

Dale S Steichen

Frances E Mitchell

Blanca L Haendler

J Bruce England

Suzanne M Thompson

Daniel H Klapprott

David W Colborn

Barbara H Munk

Carolyn P Emrie

Ute H Riggin

Carrole L Johnson

Eric A Lutkin

Methods and compositions for increased stability of enzymes in oxidant dry bleach. Enzyme stability is adversely affected by increased temperature, humidity, and the presence of strong oxidants, such as peracids. The instant invention provides enzyme stability in the presence of oxidant bleaches by coating or encapsulating the enzyme, while providing enzyme solubility suitable for use in bleach mixtures upon introduction to an aqueous medium. Particularly, alkali and neutral materials act as protection agents, which neutralize oxidant species before they contact and denature the enzyme. Other standard bleaching composition adjuncts such as builders, fillers, buffers, brighteners, fragrances, and the like may be included in the enzyme-containing oxidant bleach composition in addition to the discrete coated enzyme granules.

Encapsulated enzyme in dry bleach composition

Methods and compositions for increased stability of enzymes in oxidant dry bleach. Enzyme stability is adversely affected by increased temperature, humidity, and the presence of strong oxidants, such as peracids. The instant invention provides enzyme stability in the presence of oxidant bleaches by coating or encapsulating the enzyme, while providing enzyme solubility suitable for use in bleach mixtures upon introduction to an aqueous medium. Particularly, alkali and neutral materials act as protection agents, which neutralize oxidant species before the contact and denature the enzyme. Other standard bleaching composition adjuncts such as builders, fillers, buffers, brighteners, fragrances, and the like may be included in the enzyme-containing oxidant bleach composition in addition to the discrete coated enzyme granules.

In one embodiment, the invention provides a stable peracid bleach composition comprising discrete granules which comprise peracid, namely, diperoxydodecanedioic acid. In another preferred embodiment, enzymes are present in the composition separate from the discrete peracid granules. In both the enzyme-containing and non-enzyme containing compositions, peracid and exotherm control agents are combined in a discrete granule in which the amount of water is carefully controlled to result in, respectively, maximum peracid and enzyme stability. Standard bleaching composition adjuncts such as fillers, brighteners, pH control agents and the like may be included in the compositions apart from the discrete peracid granules.

Stable peracid bleaching compositions: organic peracid, magnesium

A dry bleach product is based upon diperacid, particularly diperoxydodecanedioic acid. The dry product comprises separate granular, particulate and beaded components wherein the granular component is diperacid stabilized with an exotherm control agent, diluent and a binder that includes unneutralized polymeric acid. The beaded component is fragrance admixed with a water soluble starch; the particulate components include an agglomerated extender or bulking agent, a pH control agent, and protected fluorescent whitening agents, all as separate particulate components. The water content of the granular diperacid is carefully controlled, as is the ratio of exotherm control agent to diperacid.

Dry peracid based bleaching product

Most conventional animal litters develop malodors fairly quickly. An animal litter in accordance with the present invention selectively releases an odor masking component in response to agitation of the litter by an animal. The animal litter comprises absorbant particles having microcapsules affixed to exterior surfaces of at least some of the absorbant particles. The microcapsules encapsulate the odor masking component, which is released when the microcapsules are ruptured.

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Livermore, CA, United States of America

Thomas S Coyne