Mobil Oil Corporation

Thomas R Kiliany, Jr

David A Pappal

John P McWilliams

Stephen Harold Brown

Jeffrey C Trewella

Tai-Sheng Chou

Clinton R Kennedy

Minas R Apelian

Anthony S Fung

Timothy L Hilbert

Sowmithri Krishnamurthy

George H Hatzikos

Paul P Durand

Chang-Kuei Lee

Catherine T Sigal

Chung-Hur Lee

Poh K Ng

This invention is a process for the upgrading of distillate feeds. A batch of supported hydroprocessing catalyst is placed in a reaction zone, which is usually a fixed bed reactor. The hydroprocessing catalyst comprises an effective amount of a noble metal or metals and has a specific activity. Both low aromatic diesel and jet fuel may be produced in separate blocks over the same catalyst batch, using different feeds and often different conditions. The activity of the catalyst is restored each time the feed is switched. When production is switched from jet fuel to low aromatics diesel, activity may be regained more quickly by holding the catalyst at a higher temperature than the reaction temperature for a specific period of time prior to dropping the temperature to the reaction temperature. Switching from one feed to the other may continue for about one year before the catalyst batch is changed. A dual catalyst system may alternatively be employed. In this case a hydroprocessing catalyst batch comprising an effective amount of at least one base metal is used in combination with the catalyst comprising an effective amount of at least one noble metal catalyst. The feed contacts the catalyst comprising the base metal before it contacts the catalyst comprising a noble metal. In a dual catalyst system, the feeds may be switched for about two years over the two catalyst batches before fresh catalyst is necessary.

Distillate upgrading process

A process for reducing sulfur content in a gaseous stream with the production of elemental sulfur by first treating the gaseous steam with hydrogenation and hydrolysis to convert substantially all of the sulfur components therein to hydrogen sulfide. Then reducing the water content of the gaseous stream to optimize chemical equilibrium. Thereafter, the gaseous steam is contacted in an oxidation reactor with an acid catalyst at a temperature of about 150.degree. C. to about 350.degree. C. to convert hydrogen sulfide to elemental sulfur. The product gas leaving the oxidation reactor is cooled to separate elemental sulfur by condensation. The acid catalyst is a shape selective zeolite, a metal-exchanged or impregnated alumina, or a mixture thereof. The alumina is gamma phase alumina impregnated with from about 0.2 wt % to about 2.0 wt % metal.

Reduction of sulfur content in a gaseous stream

There is provided a process for regenerating a coked catalyst comprising a zeolite and a noble metal such as platinum. The process involves treating the coked catalyst under somewhat mild oxidation conditions, whereby a sufficient portion of the coke is removed from the catalyst to restore the hydrocarbon sorption properties of the zeolite component to the level observed in the non-coked form. Surprisingly, the original activity of the catalyst is substantially restored, even though a substantial amount of coke remains on the regenerated catalyst.

Regeneration of noble metal containing zeolite catalysts via partial

Disclosed is an improved method and apparatus for creating a more uniform filter cake on a vacuum filter belt. A weir box for depositing a slurry on the filter belt has an outlet in the form of a plurality of slots spaced transversely of the filter belt with each slot being in the form of a truncated triangle with the base of the triangle being located closer to the filter belt than the truncated portion of the triangle.

Method and apparatus for forming and ion-exchanging a filter cake

Abatement of nitrogen oxides in an industrial exhaust gas is effected by reduction of the nitrogen oxides with ammonia in the presence of a catalyst comprising a porous crystalline siliceous solid such as a ZSM-5 type zeolite. Fast responses to changes of NO.sub.x load is achieved with a zeolite of low to moderate acid activity. The catalyst may be virgin catalyst, aged catalyst previously used for the conversion of a hydrocarbon or an organic compound, or artifically aged catalyst.

Abatement of NO.sub.x in exhaust gases

Growing community of inventors

West Chester, PA, United States of America

Thomas R Kiliany, Jr