Basf Se Corporation

Thomas Maximilian Wurm

Peter Rudolf

Indre Thiel

Joaquim Henrique Teles

Bernd Bruchmann

Dominic Riedel

Burkhard Walther

Jan-Dirk Arndt

Achim Kaffee

Elliot Christ

Jens Langhanki

A process can be used for the synthesis of compounds containing at least one non-cyclic carbonate group, wherein a compound A) containing at least one five-membered cyclic monothiocarbonate group is reacted with at least one hydroxy group of a compound B) or of compound A) itself.

Process for the synthesis of polycarbonates from cyclic monothiocarbonates

A process reduces the odor of compounds with al least one five-membered cyclic monothiocarbonate group, referred to as monothiocarbonate compounds. The monothiocarbonate compounds are in are liquid phase and are brought into contact with an oxidant.

Reduction of the odor of monothiocarbonate compounds by addition of oxidants

Provided is a process for the preparation of a compound with at least one five-membered cyclic monothiocarbonate group. A compound C1 with at least one halohydrin group is used as starting material. Compound C1 is reacted with phosgene or an alkyl chloroformate to give an adduct C2. The adduct C2 is reacted with a compound that includes anionic sulfur to obtain the compound with at least one five-membered cyclic monothiocarbonate group.

Method for the preparation of thiocarbonates

A process synthesizes a compound with at least one alkylene group and at least one thiol or thiolate group. The process involves reacting a compound with at least one five-membered cyclic monothiocarbonate group with a starter selected from a compound with at least one thiol group, from a compound with at least one hydroxy group, or from a basic inorganic composed; to obtain a compound with at least one alkylene group and at least one thiol or thiolate group and carbon dioxide.

Process for the preparation of compounds with at least one alkylene group and at least one thiol or thiolate group

A process for the purification of organic sulfur compounds involves bringing the organic sulfur compounds, in a liquid phase, into contact with an oxide of a metal from groups VIIb or VIIIb and an oxide of a metal from groups Ia to IIIa of the periodic system, or alternatively, with a mixed-oxide thereof; for a contact period of at leastminute. Afterwards, the oxides and the organic sulfur compounds are separated.

Process for the purification of organic sulfur compounds

A process prepares a cross-linked polymer containing urethane groups and silicon atoms. Starting materials of the process include a compound A) with a five-membered cyclic monothiocarbonate group, a compound B) with an amino group, selected from primary or secondary amino groups or blocked amino groups, and optionally, a compound C) with at least one functional group that reacts with a group &#x2014;SH. One of the compounds contains a silicon-functional group. In one example of the process, compounds A) and B), and optionally C), are then reacted under exclusion of water to obtain a polymer with curable silicon-functional groups. The polymer is applied to a surface, gap, or a three-dimensional template. The silicon-functional groups are cured with ambient water. The polymer contains 0.001 to 0.3 mol of silicon per 100 g of the polymer.

Preparation of a cured polymer comprising urethane groups and silicon atoms

A process prepares a prepolymer containing a urethane group and a curable silicon-functional group, or a prepolymer of formula (IV), The prepolymer may be cured to a cross-linked polymer by ambient moisture and is therefore suitable for use as a component in a one-component sealant or adhesive composition.

One-component sealant or adhesive composition

A composition comprising a compound of formula (Va) wherein n is 1 or 2 and wherein m is 1 or 2, with n and m preferably both being 1 or both being 2, more preferably both being 1, and/or, preferably and, a compound of formula, wherein n is 1 or 2 and wherein m is 1 or 2, with n and m preferably both being 1 or both being 2, more preferably both being 1, and wherein at least 90 weight-% of the composition consist of compounds of formula (Va) and formula (Vb). 

Preparation of 2,6- and 2,7-disubstituted anthraquinone derivates

The present invention relates to novel anthraquinone derivatives, 2,6-diisohexylanthracene-9,10-dione and 2,7-diisohexyl-anthracene-9,10-dione, preferably to be used for the preparation of hydrogen peroxide, and to a process for the preparation of these anthraquinone derivatives.

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Ludwigshafen, Germany

Thomas Maximilian Wurm