Shiseido Company, Limited

Clairol Incorporated

Thomas M Schultz

Keith C Brown

Leszek J Wolfram

Stephanie Wong

Sanae Kubo

Bryan Patrick Murphy

Alexander C Chan

Edward Borish

Giuseppe Prota

Andrew Savaides

Alice A Meyer

George Serban

Jitendra Patel

James S Anderson

Alice A Mayer

Teresa Ferullo

Eva Day

Adalberto Fleitas

Bridget Ijeh

Catherine Grillo

Lana Hochman

A highly effective, ammonia-free, permanent waving lotion is attained by employing one a reducing agent consisting of a thiol compound or mercaptan in combination with an alkalizing agent consisting of an alkanolamine and an alkali metal hydroxide. In accordance with this invention, the reducing agent is employed either independently as an aqueous solution or in association with desired additives for imparting additional benefits to the permanently waved hair. Preferably, the reducing agents of the present invention are employed in a permanent waving lotion having a pH ranging between about 5.5 and 10.0. By employing this invention, long lasting permanently waved hair is attained with substantially less malodor being produced, thereby providing increased comfort to the stylist and the person who undergoes permanent waving.

Permanent waving lotion and method of use

An improved, highly effective permanent waving lotion is attained by employing a reducing agent which consists of a lower alkyl ester of cysteine in combination with a thiol compound selected from the group consisting of ammonium salts and glyceryl esters of thioglycolic acid, thiolactic acid and thiopropionic acid. By employing the reducing agent of this invention, the pH level at which the permanent wave is performed can be substantially reduced, thereby improving comfort and reducing adverse reactions. The reducing agent of this invention is employed either as an aqueous solution of the two components or in association with desired additives for imparting additional benefits to the permanently waved hair. Preferably, the reducing agents of the present invention are employed in a permanent waving lotion having a pH ranging between about 5.0 and 9.5.

Reducing agents for permanent waving of hair

A highly effective permanent waving lotion is attained by employing one compound selected from the group consisting of glyceryl monothiopropionate, glyceryl thiolactate, and combinations of glyceryl monothiopropionate and glyceryl thiolactate as the sole reducing agent. In accordance with this invention, the reducing agent is employed either independently in an aqueous solution or in association with desired additives for imparting additional benefits to the permanently waved hair. Preferably, the reducing agents of the present invention are employed in a permanent waving lotion having a pH ranging between about 6.0 and 9.5. In this way, processing time is reduced and long lasting permanently waved hair is attained with substantially less malodor being produced.

A process for preparing dye compositions which comprises hydrolyzing an O-protected 5,6-dihydroxyindole with an alkaline material under anaerobic condition and the products made by such process.

Process for preparing dye compositions containing 5,6-dihydroxyindole

A process for preparing dye compositions which comprises hydrolyzing an O-protected 5,6-dihydroxyindole with an alkaline material under substantially anaerobic condition and the products made by such process.

Dye compositions containing 5,6-dihydroxy indoles and a foam generator

By intermixing a gelling agent, water, a mercaptan-based reducing agent, and a certified dye designated as an F,D&C dye and/or a D&C dye, a highly effective, easily employed permanent dye/gel composition is obtained which imparts a desired color into both natural and synthetic fibers. In the preferred embodiment, the mercaptan-based reducing agent is added to the composition immediately prior to applying the permanent dye/gel composition to the fibers. By merely rubbing, or embrocating the permanent dye/gel composition into the natural or synthetic fibers, the desired color is permanently embedded into the fibers in a long-lasting durable manner. In view of the constituents employed in this permanent dye/gel composition, use as a permanent hair dye is highly effective.

Non-oxidative permanent dye formulation for hair and synthetic fibers

An improved permanent waving lotion is attained by incorporating into an otherwise conventional composition an organic compound having at least one function position definable as an alpha, beta-unsaturated ketone in conjunction with a carbon-carbon double bond. By employing the present invention, improved curl formation is attained and the malodor typically associated with permanently waved hair is substantially eliminated. Compounds incorporating the desired alpha, beta-unsaturated ketone can be used directly, in the permanent waving lotion, or chemical precursors can be employed to produce the desired alpha, beta-unsaturated ketone when exposed to oxidation or to alkaline materials.

Permanent waving composition

Process for dyeing human hair by the sequential treatment of the hair with a metal ion and particularly transition metal ion containing composition and with a dye composition containing 5,6-dihydroxyindole-2-carboxylic acid.

Process for dyeing hair by the sequential treatment of hair with metal

By incorporating an alkyl polyol and a water soluble or emulsifiable silicone based compound into a moderately viscous gel-type hair conditioning composition, a hair conditioning gel formulation is attained which is able to be delivered in a spray mist pattern using conventional small diametered pump spray nozzles. Preferably, the alkyl polyol has a carbon content ranging between 2 and 8, and the hydroxyl ion content ranges between 2 and 7 and are not spaced apart by more than 4 carbon atoms. It has been found that by employing this invention, the resulting gel formulation is able to be dispensed consistently, repeatedly and easily in a liquified spray mist through a pump nozzle having apertures ranging between about 0.010 and 0.030 mm.

Dispensing system for sprayable gel-type hair conditioner

Simultaneous permanent waving and dyeing of hair fibers is attained by incorporating a silk amino acid and a water soluble or emulsifiable silicone based compound in the permanent waving lotion and intermixing the dyestuff with the oxidizing or neutralizing composition. Preferably, the combined dyeing and neutralizing composition is adjusted to have a pH ranging between about 7 and 9. In this preferred embodiment, the hair is warmed after receiving the combined dyeing and neutralizing composition with said composition preferably being processed on the hair at a temperature ranging between 40.degree. C. and 65.degree. C. In addition, further enhanced coloring and permanent waving is attained by incorporating a lipotropic material into the dye additive composition.

Permanent waving and color enhancing composition and method

An easily employed, effective and predictable hair dye composition is obtained by combining aryl amines with aryl aldehydes along with an inorganic metal salt having a valence between +1 and +3. By employing this formulation, a permanent, long-lasting, non-fading hair coloring is achieved. In the preferred embodiment, the inorganic metal salt is selected from the group consisting of aluminum chloride, ferric chloride, lithium bromide, manganese chloride, copper chloride, and manganese nitrate. In carrying out the teaching of the present invention, the aryl amine and aryl aldehyde may be applied to the hair separately or in combination, along with the inorganic metal salt. In addition, this inorganic metal salt can be applied after the application and removal of the aryl amine and aryl aldehyde.

Hair coloring dyes incorporating aryl amines and aryl aldehydes

By combining a fluoroscein-based dye with a mercaptan based permanent waving composition and maintaining the pH of the resulting composition between about 2.5 and 4.5, a composition is achieved which simultaneously colors and permanently waves the hair. In addition, even if no coloring or dying of the hair is desired, the use of a colorless or complimentary fluoroscein-based dye with the mercaptan based permanent waving composition achieves a composition which imparts a substantially improved curl configuration to the hair as well as substantially longer lasting curls. Preferably, the mercaptan based permanent waving composition employed comprises an ester of either thioglycolic acid, thiolactic acid, or the amide of 2-aminoethanethiol.

Product for improved permanent waving of hair and simultaneously

By combining a fluoroscein-based dye with a mercaptan based permanent waving composition and maintaining the pH of the resulting composition between about 2.5 and 4.5, a composition is achieved which simultaneously colors and permanently waves the hair. In addition, even if no coloring or dyeing of the hair is desired, the use of a colorless or complimentary fluoroscein-based dye with the mercaptan based permanent waving composition achieves a composition which imparts a substantially improved curl configuration to the hair as well as substantially longer lasting curls. Preferably, the mercaptan based permanent waving composition employed comprises an ester of either thioglycolic acid, thiolactic acid, or the amide of 2-aminoethanethiol.

By combining an aqueous chlorite solution with an organic or inorganic buffer salt and a divalent metal ion, a stable aqueous chlorite solution is attained for use in substantially improving the durability and resulting visual appearance of permanently waved hair. In addition, the present invention is equally effective as a post treatment for freshly permanently waved hair or as the oxidizer in the permanent waving process. Furthermore, this aqueous chlorite solution can be intermixed with conventional oxidizers to attain the desirable beneficial results.

Oxidizing mixtures for hair care use

Compositions containing certain indoles and quaternary ammonium salts are useful for imparting a tan to skin without prolonged exposure to the sun.

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Highland Mills, NY, United States of America

Thomas M Schultz