Astro-valcour, Incorporated

E.i. Dupont De Nemours and Company

Thomas M Pontiff

Timothy H Walter

Joseph P Rapp

Method and apparatus for producing a molded article of a foamed thermoplastic resin and articles produced thereby. A molten mass of an expandable thermoplastic resin is accumulated in an accumulator while it is prevented from foaming. A quantity of the accumulated formable melt is extruded through a die orifice having a shape adapted to reflect the shape of the desire finished product. The extruded foamable melt commences foaming as it comes in contact with the atmosphere. As the extruded thermoplastic resin foams, it is pulled vertically downward from the die orifice by gravity. The downward-hanging, foamed, thermoplastic material is captured between the halves of a vertically-oriented mold before the foaming expansion of the foamable melt has been completed. The foamed thermoplastic material is compressed by the vertically-oriented mold into the desired shape. The foamed thermoplastic material may be formed into intricate articulations within the female mold portion by gases emitted from jets in the male mold portion or by venting or drawing off gases disposed in the female mold portion. The mold halves may also be configured to confine any foamed resin flash to the bottom portion of the molded article.

Apparatus for producing foamed, molded thermoplastic articles and

Method and apparatus for producing a molded article of a foamed thermoplastic resin and articles produced thereby. A molten mass of an expandable thermoplastic resin is accumulated in an accumulator while it is prevented from foaming. A quantity of the accumulated foamable melt is extruded through a die orifice having a shape adapted to reflect the shape of the desire finished product. The extruded foamable melt commences foaming as it comes in contact with the atmosphere. As the extruded thermoplastic resin foams, it is pulled vertically downward from the die orifice by gravity. The downward-hanging, foamed, thermoplastic material is captured between the halves of a vertically-oriented mold before the foaming expansion of the foamable melt has been completed. The foamed thermoplastic material is compressed by the vertically-oriented mold into the desired shape. The foamed thermoplastic material may be formed into intricate articulations within the female mold portion by gases emitted from jets in the male mold portion or by venting or drawing off gases disposed in the female mold portion. The mold halves may also be configured to confine any foamed resin flash to the bottom portion of the molded article.

Objects of thermoplastic polymer foam such as, e.g., sheeting of polyolefins such as polyethylene, are treated at elevated temperatures effective to rapidly purge the foam of a substantial portion of the residual blowing agent. Significant economies are achieved by reducing the amounts of residual blowing agents (such as flammable, toxic or environmentally hazardous gases) to levels presenting no fire hazard or other safety hazards in times substantially less than required in conventional aging under ambient conditions. The processes can be carried out in ovens or other heating zones which form continuations of the basic production line, with the extracted blowing agents recycled or disposed of by combustion.

Methods for rapid purging of blowing agents from foamed polymer products

Moldable shrunken foam beads comprising a foamable thermoplastic polymer, preferably a silane-crosslinked polyolefin foam, are produced by mixing a composition comprising a silane-modified polyolefin (such as a silane-grafted polyethylene) and a silanol condensation catalyst in an extruder to produce a melt, then projecting a blowing agent into the melt at a rate effective to produce a desired foam density in the extrudate; extruding and cutting the melt to form foam beads; allowing the beads to shrink; and exposing the foam beads to moisture to produce silane crosslinking of the polyolefin foam. In certain other embodiments the crosslinking of the thermoplastic polymer can be omitted, and/or shrinkage of the beads produced by vacuum treatment.

Moldable shrunken thermoplastic polymer foam beads

A foamed thermoplastic elastomer having a substantially uniform closed cell structure and having a specific gravity of less than about 0l.40, an energy return ratio greater than about 0.50 when compressed and released said foam being prepared from a thermoplastic multi-block copolymer elastomer having a Shore D hardness of 25-75.

Low density foamed thermoplastic elastomers

A flexible innersole, or component thereof, for footwear of a foamed thermoplastic multi-block copolymer elastomer having a substantially uniform closed cell structure and having a specific gravity of less than about 0.35, an energy return ratio greater than about 0.55 when compressed and released said foam being prepared from a thermoplastic multi-block copolymer elastomer having a Shore D hardness of 25-45.

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Gansevoort, NY, United States of America

Thomas M Pontiff