E.i. Dupont De Nemours and Company

Invista North America S.a.r.l.

Chronopol, Inc.

Dximaging

Thomas M Ford

Debora Flanagan Massouda

Dimitri Peter Zafiroglu

Stephan James McLain

Geoffrey David Hietpas

Neville Everton Drysdale

Hyunkook Shin

Vishal Bansal

Kenneth George Sharp

Edgar N Rudisill

Gregory Paul Weeks

Harry Vaughn Samuelson

Michael C Davis

Maria Spinu

Irene Greenwald Plotzker

Antonio Vidal

William E Kelly, Jr

Samuel Tacitus D'Arcangelis

Enio Kumpinsky

Thomas C Felder

James V Hockessin

Patricia A Ford, Legal Representative

A method for preparing stretchable bonded nonwoven fabrics which involves forming a substantially nonbonded nonwoven web of multiple-component continuous filaments or staple fibers which are capable of developing three-dimensional spiral crimp, activating the spiral crimp by heating substantially nonbonded web under free shrinkage conditions during which the nonwoven remains substantially nonbonded, followed by bonding the crimped nonwoven web using an array of discrete mechanical, chemical, or thermal bonds. Nonwoven fabrics prepared according to the method of the current invention have an improved combination of stretch-recovery properties, textile hand and drape compared to multiple-component nonwoven fabrics known in the art.

Stretchable multiple component nonwoven fabrics and methods for preparing

The invention relates to nonwoven fabrics containing polymeric multiple component fibers which include a core component and a plurality of wing components attached to the core. The polymeric core component has an elasticity that is greater than the elasticity of at least one of the wing polymeric components. The fibers assume a spiral twist configuration in which the plurality of wings substantially spiral about the core. In a preferred embodiment, the nonwoven fabrics have elastic stretch and recovery properties with a textile-like hand.

Stretchable nonwoven web and method therefor

Stretchable multiple-component nonwoven fabrics and methods for preparing

This invention relates to an improved method for preparing stretchable multiple-component bonded composite sheets which involves bonding a fibrous layer of spirally-crimpable multiple-component continuous filaments or staple fibers to one or more non-spirally-crimpable layers using an array of intermittent mechanical, chemical, or thermal bonds, and heating the bonded composite to activate the spiral crimp of the fibers in the spirally-crimpable layer. Multi-layer nonwoven fabrics prepared according to the method of the current invention have an improved combination of strength, aesthetics, stretch-recovery properties, and textile hand and drape compared to multiple-component nonwoven fabrics known in the art.

Stretchable composite sheets and processes for making

A polymer composition and method for reducing the permeability of gases through molded polymeric containers and films by incorporating into the polymer from which the container or film is formed an effective amount of a barrier-enhancing additive, such as monoesters of hydroxybenzoic acid and hydroxynaphthoic acid.

Method and composition for improving gas barrier properties of polymeric containers and films

An antibacterial composition and method for use of such composition in packaging of moisture-containing foodstuffs in a manner to extend the shelf life of the foods comprises placing the foodstuff in intimate contact with the composition which comprises 5-40% wt. of a lactic acid-based compound and optionally a liquid organic plasticizer dispersed in a solid matrix of poly(lactic acid) or lactic acid copolymer having a number average molecular weight of 3,000 to 200,000.

Method for packaging foodstuffs

Star-block copolymers containing polycaprolactone and polylactide blocks of limited molecular weight are tough, easily degradable polymers. Such copolymers, which are noncrystalline and have glass transition temperatures near or below room temperature, are useful in many packaging and other applications.

Easily degradable star-block copolymers

A improved process for depolymerizing a poly(alpha-hydroxycarboxylic acid) to its corresponding dimeric cyclic ester is disclosed. The process comprises:

Recovery of hydroxycarboxylic acid values from poly(hydroxycarboxylic

A method providing a catalyzed ring opening polyester polymerization at a high reaction rate wherein the amount of organic acid in the reaction medium is maintained at an acid: catalyst ratio below 6:1.

Method for making polymers of alpha-hydroxy acids

A process for polymerizing lactide and up to 20 mole percent of another lactone is disclosed. The cayalysts used have the formula MZ.sub.3 wherein M is scandium, yttrium, bismuth, a lanthanide series rare earth metal or a mixture thereof and the Zs are independently the same or different highly coordinating ligands. The preferred metals M are lanthanum, cerium, praseodymium and neodymium with lanthanum being especially preferred. The preferred ligands are betadiketones, betaketoesters and malonate anions with the betadiketones such as 2,2,6,6-tetramethyl-3,5-heptanedionates being especially preferred.

Rare earth metal coordination compounds as lactone polymerization

A process for polymerizing lactide and up to 20 mole percent of another lactone in the absence of solvent at 100.degree. to 220.degree. C. using an yttrium or lanthanide series rare earth metal catalyst.

Polymerization of lactide

Environmentally benign closed cell compositions made by foaming star-shaped polymers with a plurality of poly(hydroxy acid) chains attached to a central polyfunctional compound having a plurality of hydroxyl and/or amino groups.

Degradable foam materials

Electrostatic liquid developer consisting essentially of

Degradable resins for electrostatic liquid developers

A process for polymerizing lactide and up to 20 mole percent of another lactone is disclosed. The cayalysts used have the formula MZ.sub.3 wherein M is scandium, yttrium, bismuth, a lanthanide series rare earth metal or a mixture thereof and the Zs are independantly the same or different highly coordinating ligands. The preferred metals M are lanthanum, cerium, praseodymium and neodymium with lanthanum being especially preferred. The preferred ligands are betadiketones, betaketoesters and malonate anions with the beta diketones such as 2,2,6,6-tetramethyl-3,5-heptanedionates being especially preferred.

A process for manufacturing 1,4-bis(4-phenoxybenzoyl)benzene, wehrein diphenyl ether is contacted for about 30-360 minutes at 130.degree.-200.degree. C. with 1,4-benzenedicarbonyl chloride in respective mole ratios of about 15-80:1 in the presence of a fluorocarbon resin carrying pendant sulfonic acid groups, the weight ratio of the resin to 1,4-benzenedicarbonyl chloride being 3:1-1:2; the hot solution is separated from the resin, and the crystalline product is recovered from the solution on cooling. The so obtained 1,4-bis(4-phenoxybenzoyl)-benzene is a high purity material free of ortho-isomer and catalyst contamination and can be used without further purification as one of the starting materials in the preparation of polyetherketones, which are important engineering resins.

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Greenville, DE, United States of America

Thomas M Ford