Eastman-kodak Company

Thomas Joseph Dannhauser

Pranab Bagchi

Tienteh M Chen

John D Lewis

Mark A Whitson

Douglas E Bugner

Mark Edward Irving

David Daniel Putnam

Brian L Lindstrom

Hwei-Ling Yau

Raouf Botros

Sharon R Girolmo

Wayne Thomas Ferrar

Thomas R Welter

Sang H Kim

Arlyce T Bowne

Gerald A Campbell

Peter G Bessey

Keath T Chen

Phillip D Knight

Yang Xiang

Douglas Eugene Bugner

Peter Gerard Bessey

Brian L Lindstom

Inkjet printed articles can be made by providing an inkjet receiving medium comprising a substrate and a topcoat layer, and inkjet printing an aqueous pigment-based ink onto the topcoat layer. The topcoat layer has: (a) one or more water-soluble salts of a multivalent metal cation; and (b) composite particles having a Rockwell Hardness of &#x2264;R90 and each of the composite particles comprising domains of a (i) first organic polymer and domains of a (ii) second organic polymer. The domains of the (ii) second organic polymer are dispersed within the domains of the (i) first organic polymer. The melting point of the (i) first organic polymer is lower than the melting point of the (ii) second organic polymer. The weight ratio of the (i) first organic polymer to the (ii) second organic polymer is chosen such that the (b) composite particles have a density of 1.0-1.5 g/ml.

Method for inkjet printing and printed article

An aqueous composition can be used for pre-treating a substrate prior to inkjet printing. This composition includes: (a) one or more water-soluble salts of a multivalent metal cation; and (b) composite particles having a Rockwell Hardness of less than or equal to R90 and each of the composite particles comprising domains of a (i) first organic polymer and domains of a (ii) second organic polymer. The domains of the (ii) second organic polymer are dispersed within the domains of the (i) first organic polymer. Moreover, the melting point of the (i) first organic polymer is lower than the melting point of the (ii) second organic polymer. The weight ratio of the (i) first organic polymer to the (ii) second organic polymer is chosen such that the (b) composite particles have a density of 1.0-1.5 g/ml.

Aqueous pre-treatment compositions for inkjet printing

An inkjet receiving medium having enhanced surface properties has a substrate and a topcoat layer disposed thereon. The topcoat layer has: (a) one or more water-soluble salts of a multivalent metal cation; and (b) composite particles having a Rockwell Hardness of less than or equal to R90 and each of the composite particles comprising domains of a (i) first organic polymer and domains of a (ii) second organic polymer. The domains of the (ii) second organic polymer are dispersed within the domains of the (i) first organic polymer. The melting point of the (i) first organic polymer is lower than the melting point of the (ii) second organic polymer. The weight ratio of the (i) first organic polymer to the (ii) second organic polymer is chosen such that the (b) composite particles have a density of 1.0-1.5 g/ml.

Inkjet receiving media

Inkjet receiving medium are prepared by disposing an aqueous composition onto at least one surface of a substrate to provide a topcoat layer. The aqueous composition has: (a) one or more water-soluble salts of a multivalent metal cation; and (b) composite particles having a Rockwell Hardness of less than or equal to R90 and each of the composite particles comprising domains of a (i) first organic polymer and domains of a (ii) second organic polymer. The domains of the (ii) second organic polymer are dispersed within the domains of the (i) first organic polymer. The melting point of the (i) first organic polymer is lower than the melting point of the (ii) second organic polymer. The weight ratio of the (i) first organic polymer to the (ii) second organic polymer is chosen such that the (b) composite particles have a density of 1.0-1.5 g/ml.

Method for providing inkjet receiving media

In accordance with the present invention, there is provided a multi-layered structure includes:

Multilayered structure with water-impermeable substrate

An inkjet receiving medium including a substrate and having a topmost layer coated thereon at solid content of from 0.1 to 25 g/m, wherein the topmost layer comprises from 30-70 wt % of one or more aqueous soluble salts of multivalent metal cations and at least 0.05 g/mof a cross-linked hydrophilic polymer binder. Improved optical density, reduced mottle and improved wet abrasion resistance are provided when the receiver is printed with an aqueous pigment-based ink. In further embodiments, the topmost layer may further comprise a latex dispersion for improved image durability.

Inkjet recording medium and methods therefor

A method for improving durability of aqueous ink deposited on a substrate having multivalent metal salt present at the surface of the substrate is disclosed. The method includes depositing aqueous ink on the surface of the substrate, wherein the aqueous ink is an anionically stabilized pigment ink, drying the substrate to substantially remove the water from the deposited aqueous ink, applying substantially pure water and heat to the dried substrate with deposited aqueous ink, and removing the applied water and heat to return the dried substrate to an ambient temperature and moisture content. The applied substantially pure water and heat are sufficient to cause a significant improvement of the durability of the deposited ink on the substrate.

Aqueous ink durability deposited on substrate

An inkjet receiving media comprising a substrate having a transparent topmost layer coated thereon at solid content of from 0.3 to 2.5 g/m, wherein the topmost layer includes from 30-70 wt % of one or more aqueous soluble salts of multivalent metal cations, 5 to 20 wt % of a cross-linked hydrophilic polymer binder, 4 to 12 wt % of a cationic polymer to stabilize 10 to 40 wt % silica that is less than 200 nm is size. Improved optical density, reduced mottle and improved wet abrasion resistance are provided when the receiver is printed with an aqueous pigment-based ink. In further embodiments, the topmost layer can further include high levels of silica that makes the layer porous.

Inkjet receiver precoats incorporating silica

A method of printing with water-based inkjet inks on a water-impermeable, low-surface-energy substrate, includes:

Printing on water-impermeable substrates with water-based inks

A coating composition for pre-treating a substrate prior to inkjet printing thereon, and an inkjet receiving medium including a substrate and having a topmost layer coated thereon, where the coating composition has a solids content which includes at least 30 wt % of one or more aqueous soluble salts of multivalent metal cations, and particles had primarily of polymer having a Rockwell Hardness of less than R90 and having a mode equivalent spherical diameter of at least about 2 micrometers. When coated, the composition provides at least 0.01 g/mof particles included primarily of polymer having a Rockwell Hardness of less than R90 and which have an equivalent spherical diameter of i) at least about 2 micrometers and ii) at least 0.1 micrometer greater than the minimum coated thickness of the topmost layer.

Pre-treatment composition for inkjet printing

A manufacturing an ink-receiving medium comprising the steps of providing a support, treating the support with a salt of a multivalent metal cation, and coating upon one or each side of the support at least one porous ink-receiving top layer from an aqueous coating composition consisting of non-cationic components, wherein the non-cationic components comprise a binder and anionic particles of average particle size less than 2.5 microns, wherein the ink-receiving top layer comprises at least 50% of the total solids by weight, such that the water-soluble salt of a multivalent metal cation is able to diffuse into the ink-receiving top layer, the method further comprising drying the coating and optionally calendering the coating. Also disclosed is inkjet media made from such method and a method of printing using such inkjet media.

Glossy inkjet recording medium and methods therefor

A method of manufacturing an ink-receiving medium comprising the steps of providing a support, treating the support with a salt of a multivalent metal cation, and coating upon one or each side of the support at least one porous ink-receiving top layer from an aqueous coating composition consisting of non-cationic components, wherein the non-cationic components comprise a binder and anionic particles of average particle size less than 2.5 microns, wherein the ink-receiving top layer comprises at least 50% of the total solids by weight, such that the water-soluble salt of a multivalent metal cation is able to diffuse into the ink-receiving top layer, the method further comprising drying the coating and optionally calendering the coating. Also disclosed is inkjet media made from such method and a method of printing using such inkjet media.

A reversal photographic element comprising a support and, coated on said support, at least one image recording emulsion layer comprised of: a) a light sensitive silver halide imaging emulsion; and b) a non-image forming silver halide emulsion having an average grain size less than 0.3 &mgr;m and which comprises at least 13 percent of the total silver in the image recording layer, wherein the non-image forming silver halide emulsion comprises at least 1 mole percent iodide, and the iodide mole percentage of the non-image forming silver halide emulsion is equal to or higher than that of the imaging emulsion. The combination of the imaging emulsion and a higher iodide concentration non-imaging emulsion in an imaging layer gives an increase in interlayer interimage effects, increasing the color of the film.

Reversal photographic element comprising an imaging layer containing imaging and non-image forming emulsions

Image modification in color reversal photographic elements

The invention describes silver halide packet emulsion grains or crystals that are conventionally precipitated using gelatin of a given isoelectric pH, surrounded by a layer of gelatin-grafted-polymer particles wherein the grafted gelatin has a different isoelectric pH and the said gelatin-grafted-polymer particles are optionally chemically bonded to the gelatin surrounding the silver halide microcrystals. Such packet emulsions can form the basis for a mixed-packet color photographic system.

Growing community of inventors

Pittsford, NY, United States of America

Thomas Joseph Dannhauser