Uop Lcc

Thomas J Traynor

Timothy A Brandvold

Vladislav Ivanov Kanazirev

Stanley Joseph Frey

Dante A Simonetti

Stephen R Caskey

Vasken Abrahamian

Richard E Marinangeli

Mark B Koch

Mark Van Wees

Ping Sun

Grant H Yokomizo

Hans G Lefebvre

Jeffrey A Noga

Recycle of slurry hydrocracked product to a subsequent slurry hydrocracking reactor downstream of a lead slurry hydrocracking reactor produces reduced mesophase and provides better reactor stability as opposed to recycle to the lead slurry hydrocracking reactor. The recycle stream may be a vacuum bottoms stream and/or a slop wax stream from a fractionation column.

Process and apparatus for recycling slurry hydrocracked product

The present subject matter relates generally to a method for the removal of oxygen from hydrogen using a manganese, iron, nickel or cobalt based adsorbent. More specifically, the present subject matter relates to the methods for the removal of oxygen from hydrogen using a manganese based adsorbent without the generation of water or other oxides.

Method for oxygen removal from hydrogen using adsorbent

Methods for producing low oxygen biomass-derived pyrolysis oil are provided. Starting biomass-derived pyrolysis oil is deoxygenated by exposing the biomass-derived oil to a first catalyst in the presence of hydrogen-containing gas at first hydroprocessing conditions to produce a partially deoxygenated biomass-derived pyrolysis oil. The first catalyst has a neutral catalyst support. The partially deoxygenated biomass-derived pyrolysis oil is exposed to a second catalyst in the presence of additional hydrogen-containing gas at second hydroprocessing conditions to produce a hydrocarbon product. The biomass-derived pyrolysis oil may be esterified prior to deoxygenation. A portion of the low oxygen biomass-derived pyrolysis oil is recycled.

Methods for producing low oxygen biomass-derived pyrolysis oils

A method of removing heterocyclic sulfide impurities from a fluid stream is presented. The method comprises contacting the fluid stream with a sorbent comprising metallic copper.

Method for removal of heterocyclic sulfur using metallic copper

A method of removing mercury from a fluid stream comprising contacting the fluid stream with a sorbent comprising cupric sulfide. The cupric sulfide is formed from direct sulfidation of copper carbonate, without thermal decomposition of the copper carbonate to an oxide, at a temperature less than about 150&#xb0; C.

Method of removing mercury from a fluid stream using high capacity copper adsorbents

Methods for regenerating acidic ion-exchange resins and reusing regenerants in such methods are provided. A spent ion-exchange resin is contacted with an alcohol ion-exchange regenerant. The spent ion-exchange resin is thereafter contacted with an acidic ion-exchange regenerant to recharge the acidic ion-exchange resin to produce a regenerated acidic ion-exchange resin. Metal- and water-containing biomass-derived pyrolysis oil is then contacted with the regenerated acidic ion-exchange resin to produce low metal, water-containing biomass-derived pyrolysis oil. The regenerated acidic ion-exchange resin may be recycled. The spent alcohol and acid ion-exchange regenerants may be recovered and recycled.

Methods for regenerating acidic ion-exchange resins and reusing regenerants in such methods

Low metal, low water biomass-derived pyrolysis oils and methods for producing the same are provided. Metal- and water-containing biomass-derived pyrolysis oil is contacted with an acidic ion-exchange resin having sulfonic acid groups to produce a low metal, water-containing biomass-derived pyrolysis oil. The low metal, water-containing biomass-derived pyrolysis oil is removed from the spent ion-exchange resin after ion-exchange. The low metal, water-containing biomass-derived pyrolysis oil is distilled to produce a low metal, low water biomass-derived pyrolysis oil and a distillation product. The distillation product comprises one or both of an alcohol ion-exchange regenerant and an acidic ion-exchange regenerant which may be used to regenerate the spent ion-exchange resin. The regenerated acidic ion-exchange resin may be recycled. The spent alcohol and acid ion-exchange regenerants may be recovered and recycled.

Growing community of inventors

Vernon Hills, IL, United States of America

Thomas J Traynor