The Dow Chemical Company

Dow Global Technolgoies LLC

Other

Thomas H Newman

Karen K Borodychuk

Peter N Nickias

Maurice J Marks

Alan K Schrock

Jerzy Klosin

Eric P Wasserman

Cynthia L Rand

David E Henton

Kenneth A Burdett

Michael T Malanga

Donald Lee Morrison

Jerry L Hahnfeld

Bob R Maughon

Avani Maulik Patel

Yi-Bin Huang

Mark S Chahl

Silvia A Evans

Donald L Morrison

An olefin metathesis process involving contacting an unsaturated fatty acid ester or unsaturated fatty acid, such as methyloleate or oleic acid, with a lower olefin, preferably ethylene, in the presence of a metathesis catalyst so as to prepare a first product olefin, preferably, a reduced chain &#x3b1;-olefin, such as methyl-9-decenoate or 9-decenoic acid, respectively. The metathesis catalyst contains ruthenium or osmium and a chelating ligand, preferably, a chelating ligand containing a carbene moiety and a second donor moiety of a Group 15 or 16 element Optionally, the catalyst can be supported on a catalyst support, such as, a cross-linked polymeric resin.

Metathesis of unsaturated fatty acid esters or unsaturated fatty acids with lower olefins

The present invention is directed to a process for producing a hydrogenated polymer or copolymer by hydrogenating prior to polymer isolation or finishing.

Process for preparing hydrogenated aromatic polymers

A longitudinal gage fixture extends the entire length of the cutting blade and provides positively locked, parallel surfaces that uniformly and reliably set the proper height of the gage blade along its length while in a blade holder, In use, the device requires no frictional movement of the gage along the length of the blade, and adjustment of the blade may be achieved in an accurate, single-step process. The entire blade and holder assembly is positioned within the gage fixture and adjusting screwy at the base of the holder are accessed through apertures in a base plate of the gage fixture so that all necessary adjustments of the blade may be made with the holder insitu without any movement of the holder. Only movement of the blade within the holder is required during adjustment. Once properly adjusted, the tightening down of the blade may also be accomplished with the blade and holder still within the gage fixture.

Method and apparatus for rotary cutter blade adjustment

A process for preparing syndiotactic vinylidene aromatic polymers comprising contacting one or more vinylidene aromatic monomers with a concentrated catalyst premix composition comprising a Group 4 metal complex and an activating cocatalyst.

Syndiotactic vinylidene aromatic polymerization process

A process for preparing syndiotactic monovinylidene aromatic polymers comprising contacting one or more monovinylidene aromatic monomers with a catalyst composition comprising a Group 4 metal complex and an activating cocatalyst composition comprising an aluminoxane and an electrophilic borane compound.

Syndiotactic monovinylidene aromatic polymerization process

A process for preparing syndiotactic vinylidene aromatic polymers comprising contacting one or more vinylidene aromatic monomers with a hydrocarbylsilane or di(hydrocarbyl)silane adjuvant to form a monomer/silane mixture and contacting the monomer/silane mixture with a catalyst composition comprising a Group 4 metal complex and an activating cocatalyst.

Long chain branched syndiotactic vinyl aromatic polymers can be obtained by polymerizing the vinyl aromatic monomer in the presence of a small amount of a multifunctional monomer under conditions such that a syndiotactic vinyl aromatic polymer is produced.

Long chain branched syndiotactic vinyl aromatic polymers

Octahydrofluorenyl metal complexes, such as octahydrofluorenyltitanium trichloride, or ring substituted octahydrofluorenyl metal complexes wherein the metal is in the +2, +3 or +4 formal oxidation state are prepared by reduction of tetra- or hexa-hydrofluorenyl metal complexes. The reduction reaction may be carried out at ambient pressure and temperature in the presence of a catalyst. The process of the present invention permits preparation of octahydrofluorenyltitanium metal complexes from a series of high yield reactions starting with fluorene.

Method for producing octahydrofluorenyl metal complexes

A process for preparing titanium or zirconium hydrocarbyloxide complexes in a reduced oxidation state comprising contacting the corresponding complex in an elevated oxidation state with lithium alkyl reducing agent and recovering the resulting product.

Process for preparation of reduced metal titanium complexes

Octahydrofluorenyltitanium metal complexes or ring substituted octahydrofluorenyltitanium metal complexes wherein the metal is in the +2, +3 or +4 formal oxidation state and activating cocatalysts or activating techniques are used to produce catalysts useful for polymerizing prochiral olefins to form highly syndiotactic polymers.

Syndiotactic prochiral olefin polymerization process

A process for preparing syndiotactic vinylidene aromatic polymers comprising contacting one or more vinylidene aromatic monomers with a catalyst comprising a Group 4 metal complex in the +3 oxidation state and a polyalkylaluminoxane cocatalyst.

Process for preparation of syndiocatic vinylidene aromatic polymers

A process for preparing syndiotactic polymers of vinylaromatic monomers comprising contacting one or more vinylaromatic monomers with a catalyst system comprising a pentamethylcyclopentadienyltitanium based metal complex capable of preparing syndiotactic vinylaromatic polymers under coordination polymerization conditions in the presence of hydrogen gas at a hydrogen partial pressure from 10 to 45 kPa and maintaining said partial pressure of hydrogen continuously throughout the polymerization.

Syndiotactic vinylaromatic polymerization process using low hydrogen

A process for preparing syndiotactic vinylidene aromatic polymers comprising contacting one or more vinylidene aromatic monomers with a catalyst comprising a cationic Group 4 metal complex wherein the metal is in the +3 oxidation state formed from the corresponding metal hydrocarbyloxy containing complex in the presence of a hydrocarbylation agent.

Process for preparation of syndiotactic vinylidene aromatic polymers

A process for preparing syndiotactic vinylidene aromatic polymers comprising contacting one or more vinylidene aromatic monomers with tri n-propyl aluminum chain transfer agent under Ziegler-Natta polymerization conditions.

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Midland, MI, United States of America

Thomas H Newman