Fmc Corporation

Bayer Cropscience Ag

Cullen, Thomas G.

Martinez, Anthony J.

Thomas G Cullen

Clinton J Peake

Robert N Henrie, Ii

Walter H Yeager

Ian R Silverman

Daniel H Cohen

Albert C Lew

Partha S Ray

Munirathnam K Chaguturu

John W Lyga

Syed F Ali

Brian D Bennett

George Theodoridis

Anthony J Martinez

John W Buser

John F Engel

Ariamala Gopalsamy

Inna Shulman

Paul E Rensner

Stephen F Donovan

Ping Ding

Y Larry Zhang

David Rosen

Guozhi Wang

Steven W Szczepanski

Seong Jae Yu

Gary A Meier

Dennis L Warkentin

Qun Zhang

Hongyan Qi

Edward J Barron

John A Dixson

Scott McN Sieburth

Elizabeth Gerig Rowley

Steven Shunxiang Zhang

James J Fiordeliso

Mary E Brown

Ellen M Crawford

Christina B Duggan

Philip A Cruickshank

Alan W Fritz

Kirk A Simmons

Scott M Sieburth

Jane A Dybas

Robert N Henrie Ii

Jacob J Vukich

Stephen Shunxiang Zhang

Leslie W Stratton

It has now been found that certain novel N-(substituted aryl)-4-(disubstituted methyl)piperidine and pyridine derivatives have provided unexpected insecticidal activity. These compounds are represented by formula (I): wherein m, n, q, r, and s are independently selected from 0 or 1; and p is 0, 1, 2, or 3; A is C or CH; and B, D, E, R, R, R, R, R, R, R, Rand Rare fully described herein. In addition, compositions comprising an insecticidally effective amount of at least one compound of formula I, and optionally, an effective amount of at least one of a second compound, with at least one insecticidally compatible carrier are also disclosed; along with methods of controlling insects comprising applying said compositions to a locus where insects are present or are expected to be present.

N-(substituted arylmethyl)-4-(disubstituted methyl) piperidines and pyridines

It has now been found that certain novel N-(substituted aryl)-4-(disubstituted methyl)piperidine and pyridine derivatives have provided unexpected insecticidal activity. These compounds are represented by formula (I): wherein m, n, q, r, and s are independently selected from 0 or 1; and p is 0, 1, 2, or 3; A is CH or N; and B, D, E, R, R, R, R, R, R, R, Rand Rare fully described herein. In addition, compositions comprising an insecticidally effective amount of at least one compound of formula I, and optionally, an effective amount of at least one of a second compound, with at least one insecticidally compatible carrier are also disclosed; along with methods of controlling insects comprising applying said compositions to a locus where insects are present or are expected to be present.

N-(substituted arylmethyl)-4-(disubstituted methyl)piperidines and piperazines

It has now been found that certain novel N-(substituted aryl)-4(disubstituted methyl)piperidine and pyridine derivatives have provided unexpected insecticidal activity. These compounds are represented by formula (I): wherein m, n, q, r, and s are independently selected from 0 or 1; and p is 0, 1, 2, or 3; A is C or CH; and B, D, E, R, R, R, R, R, R, R, Rand Rare fully described herein. In addition, compositions comprising an insecticidally effective amount of at least one compound of formula I, and optionally, an effective amount of at least one of a second compound, with at least one insecticidally compatible carrier are also disclosed; along with methods of controlling insects comprising applying said compositions to a locus where insects are present or are expected to be present 

Compounds of formula I: wherein A, B, D, and R are as defined herein and their agriculturally acceptable salts are disclosed as effective insecticides. In addition, compositions comprising an insecticidally effective amount of a compound of Formula I in admixture with at least one agriculturally acceptable extender or adjuvant and methods of controlling insects comprising applying the compositions to locus on crops where control is desired are disclosed.

1,4-disubstituted benzenes as insecticides

Compounds of the following structure are disclosed as effective insecticides:

Insecticidal N-heterocyclylalkyl-or N-&lsqb;(polycyclyl)alkyl&rsqb;-N&prime;substituted piperazines

It has now been found that certain novel photostable agriculturally acceptable organic or inorganic salts of formula I are useful as insecticides:

Insecticidal photostable acid salt derivatives of N-benzyl-4-benzhydrolpiperidines

Compounds of the following structure, the corresponding N-oxides and agriculturally acceptable salts, are disclosed as effective insecticides:

Insecticidal N-(substituted arylmethyl)-4&lsqb;bis(substituted phenyl or pyridyl)methyl&rsqb; piperidines

Compounds of the following structure, the corresponding N-oxides and agriculturally acceptable salts thereof, are disclosed as effective insecticides:

Insecticidal N-(substituted arylmethyl)-4-&lsqb;bis(substituted phenyl or pyridyl)methyl&rsqb;piperidines

Insecticidal N-(substituted arylmethyl)-4-[bis(substituted phenyl or

Compounds for control of insects and arcarids are disclosed and exemplified which are N-(arylalkyl)-4-[bis(substituted aryl)hydroxymethyl]azabicyclo[3.3. 1 .]nonanes and [3.2.1.]octanes, including N-oxides thereof, N-(substituted-oxy) derivatives thereof, and agriculturally acceptable salts thereof, having the formula: ##STR1## Certain novel intermediates for these pesticidal compounds are also disclosed.

Insecticidal N-(arylalkyl)-4-[Bis(substituted

It has now been found that certain novel oximino and hydrazono derivatives of N-benzyl-4-benzhydryl- and 4-benhydrolpiperidines, and their corresponding N-oxides and agriculturally acceptable salts are useful as insecticides. These compounds are represented by Formula I: where R is hydrogen, halogen, alkyl, alkoxy, dialkylamino; R.sup.1 is hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkylcarbonyl and alkylaminocarbonyl; X is oxygen, or NR.sup.2, Q is fluoro and hydroxy; Z is halogen, haloalkyl, haloalkoxy, pentahalothio, haloalkylthio, haloalkylsulfinyl, haloalkylsulfonyl, and --OCF.sub.2 O-- attached to two adjacent carbon atoms of the phenyl ring; n is 0 or 1; and, when X is NR.sup.2, R.sup.2 is hydrogen, alkyl, alkylcarbonyl, alkoxycarbonyl, or R.sup.1 and R.sup.2 taken together may be --C.sub.m H.sub.2.spsb.m, or --C.sub.2 H.sub.4 OC.sub.2 H.sub.4 --, where m is 3-9. Preferred compounds include those where R is hydrogen; R.sup.1 is alkyl; Q is hydroxy; X is oxygen; and Z is trifluoromethyl or trifluoromethoxy.

Insecticidal oximino and hydrazono derivatives of

An insecticidal composition comprising, in admixture with an agriculturally acceptable carrier, an insecticidally effective amount of a 2,4-diaminoquinazoline compound of the formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.6, R.sup.7, W, X, Y, and Z are as defined herein; methods of using the same; novel 2,4-diaminoquinazolines per se; and intermediates in the preparation thereof.

Insecticidal substituted-2.4-diaminoquinazolines related applications

There is provided an insecticidal composition comprising, in admixture with an agriculturally acceptable carrier, an insecticidally effective amount of a tetrahydroquinazoline compound of the formula ##STR1## wherein R, R.sup.1, R.sup.2, R.sup.3, R.sup.5, R.sup.6, R.sup.7, R.sup.8, and R.sup.9 are as defined herein, and methods of using the same. Certain novel substituted-phenyl tetrahydroquinazoline compounds per se are also identified.

Insecticidal substituted-2,4-diamino-5,6,7,8-tetrahydroquinazolines

An insecticidal composition comprising, in admixture with an agriculturally acceptable carrier, an insecticidally effective amount of a 5-deazapteridine compound of the formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, U, V, and W are as defined herein; agriculturally acceptable salts thereof; methods for using the same; and certain novel 5-deazapteridine per se.

2,4-diamino-5,6-disubstituted-and 5,6,7-trisubstituted-5-deazapteridines

Growing community of inventors

Milltown, NJ, United States of America

Thomas G Cullen