Colorado State University Research Foundation

Other

Chevron U.s.a. Inc.

Chevron Limited

Arcadis Corporate Services, Inc.

Gsi Environmental, Inc.

S3nse Technologies Inc.

Thomas C Sale

Mark Lyverse

Kayvan Karimi Askarani

Julio Zimbron

David Mark Gilbert

William Samuel Gallo

Scott R Burge

Charles J Newell

Richard L Johnson

Poonam R Kulkarni

Jay M Ham

Timothy J Smith

Saeed Kiaalhosseini

Geoffrey R Taylor

Richard C Rogers

Matthew J Biondolillo

Zachary Scott Ferrie

Philip H Batten

Joseph Scalia, Iv

Marc Chalfant

Emily B Stockwell

Julio A Zimbron

A subsurface monitoring system and method is provided for measuring a rate of change in an amount of a reactive material within a subsurface formation using measurements of thermal parameters at one or more positions within the subsurface without the need for background correction which may lead erroneous calculations and require additional monitoring equipment. The measured thermal parameters may be used to determine the heat generated by the degradation of the reactive material. The method may include measuring a first temperature near the surface of a subsurface region and a second temperature further from the surface. In some instances, an estimated location of a planar subsurface heat source/sink due to exothermic degradation reactions within the subsurface may be selected. With the derived thermal parameters and the estimated location of the subsurface heat source/sink, change rates for the reactive materials in the subsurface region may be determined or estimated.

Devices and methods for measuring natural source zone depletion rates

A subsurface monitoring system and method is provided that includes a sensor array and a monitoring system in communication with the array. The sensor array may include several sensors, such as subsurface temperature sensors, water-level sensors, and oxidation reduction potential sensors may be disposed in a vertical and/or horizontal fence through the subsurface of the monitored site. The sensor array may measure, collect, and analyze the subsurface conditions and provide the measurements to a monitoring system. The monitoring system may provide access the measurements via a user interface for analysis of the measurements. In addition, the monitoring system may process the measurements to generate one or more graphs of information for better understanding of the conditions of the subsurface of the monitored site.

Devices and methods for measuring temperature, oxidation reduction potential, and water-level within a subsurface formation

A system and method for collecting a core sample. The system includes an outer cylindrical tube, a drive head, a drive shoe, a cooling chamber housed inside the outer cylindrical tube, insulation, a core sample liner, an inlet tube, and outlet tube. The drive shoe further comprises a first, second, and third step, the first step configured to receive the insulation, the second step configured to receive the cooling chamber, the third step configured to receive the core sample liner, wherein the first step has a diameter larger than the second step and the second step has a diameter larger than the third step. The method includes drilling a hole in the ground with a drilling tool, enclosing a core sample by a core sample liner, freezing the core sample via a cooling liquid, retrieving the drilling tool at a surface of the ground, and removing the core sample encased in the core sample liner from the cooling chamber.

Cryogenic core collection

A method for controlling petroleum hydrocarbon (NAPL) sheen releases resulting from seeps, ebullition and erosion, on water surfaces, is described. An oleophilic bio-Barrier (OBBs), which may include a composite of hydrocarbon sorptive materials through which water is readily conducted, is placed at a groundwater/surface water interface (GSI) for promoting natural aerobic degradation of the intercepted/adsorbed NAPL through natural cycling of aerobic surface water and/or atmospheric oxygen. OBBs may be protected by structural covers (i.e., sand and rock gabions, as examples).

Oleophilic bio-barrier for controlling NAPL migration

Devices and methods for measuring subsurface thermal fluxes and for estimating a rate of change in the amount of a reactive material within a subsurface formation using the measured thermal fluxes are described herein. The methods of measuring subsurface thermal fluxes may use at least one array of temperature sensors distributed along a vertical transect projecting from the surface and into the subsurface of a region of interest. Methods of estimating a rate of change in the amount of a reactive material within a portion of the region of interest based on perturbations of the thermal profile within the subsurface due to an endothermic or exothermic degradation of the reactive material within the portion of the region of interest are also described herein.

Devices and methods for measuring thermal flux and estimating rate of change of reactive material within a subsurface formation

A passive sampling apparatus and method for measuring the cumulative mass of a selected gas being transported through a known cross-sectional area, for example, a soil surface, during a chosen period of time, using absorbent material, are described. Two quantities of absorbent material are disposed in a hollow container, such as a pipe section, and spaced apart such that they may be readily separated for analysis. The absorbent material closest to the soil captures the gas leaving the soil. Under reversed flow conditions, for example when the ambient air enters the ground because of fluctuations in atmospheric pressure, the upper absorbent material captures the component of interest entering the apparatus, thereby preventing this gas from entering the lower material and disturbing the measurement. The apparatus can therefore sequester the component of interest without being affected by the direction of gas transport.

Gas flux measurement using traps

A natural gradient, single well, tracer dilution non-continuous mixing apparatus and method for measuring flow of liquids through porous media are described. The method has been applied to concentrations of Light Nonaqueous Phase Liquid (LNAPL) in monitoring wells to measure the rate of LNAPL flow through the wells and through the adjacent formation. Similar measurements were made for concentrations of water in other formations. A LNAPL-soluble fluorescing tracer was added to LNAPL in the wells, and a water-soluble fluorescing tracer was added to water in the wells. The tracer is initially uniformly-mixed into the LNAPL or water in the well, and the tracer concentration is measured using a fiber optic cable and a spectrometer. The LNAPL or water with dissolved tracer is then allowed to flow from the well without any mixing. At a later time, the LNAPL or water and tracer in the well are mixed to a uniform tracer concentration, and the tracer concentration is remeasured. Using the initial tracer concentration, the subsequently mixed tracer concentration, the elapsed time, and the well diameter, a LNAPL flow rate is calculated.

Measurement of liquid flow in porous media by tracer dilution without continuous mixing

A method and apparatus for measuring in situ flow of non-aqueous phase liquids (NAPLs) through a porous medium is described. A tracer is introduced into a well or boring located in the medium and the tracer concentration in the well kept uniform by mixing. The rate at which the tracer is depleted from the well has been determined to be proportional to the flow rate of the NAPL through the well or boring and surrounding formation.

Measurement of non-aqueous phase liquid flow in porous media by tracer dilution

An apparatus for treating a flow of water containing contaminants includes first and second permeable electrodes and a power supply is coupled to each of the first and second permeable electrodes to create an electrical potential therebetween. The first and second permeable electrodes are disposed within the flow of water containing contaminants with the first permeable electrode upstream from the second permeable electrode and the water containing contaminants flowing through and between the permeable electrodes. The permeable electrodes are spaced a select distance to promote an electric current in the water containing contaminants between the electrodes sufficient to sustain oxidation or reduction of the contaminants in the vicinity of the electrodes. The electrodes are preferably substantially planar plates disposed in parallel and substantially normal to the direction of water flow. The distance between the plates is between about 0.001 and 1 meter. The electrodes are preferably made of a conductive material selected from the group including carbon black, vitreous carbon, graphite, stainless steel, aluminum, copper, gold and gold plated stainless steel.

REDOX water treatment system

Redox water treatment system

Growing community of inventors

Bellvue, CO, United States of America

Thomas C Sale