Linde Aktiengesellschaft

Thomas Bartesch

Helmut Fritz

Andreas Peschel

Johannes Fendt

Harald Klein

Clara Delhomme

A process is proposed for production of dimethyl ether (DME) from synthesis gas (SG), in which at least one feed stream formed from synthesis gas (SG) is subjected to at least one synthesis step, in which components present in the feed stream are at least in part converted to dimethyl ether (DME), wherein at least one crude product stream is obtained which contains at least dimethyl ether (DME) and the unreacted components of the feed stream. The feed stream contains at least hydrogen, carbon monoxide and carbon dioxide, and has a stoichiometric number of 2.0 to 5.0. The feed stream further contains 4 to 20 mol percent carbon dioxide, and the ratio of carbon dioxide to carbon monoxide in the feed stream is in a range from 0.5 to 4. The at least one synthesis step is carried out under isothermal conditions. A system for production of dimethyl ether (DME) from synthesis gas (SG) is likewise subject matter of the present invention.

Method and system for obtaining dimethyl ether from syngas

A process for preparing one or more reaction products, in which a first methane-rich feed stream is subjected to a partial oxidation process and/or an autothermal reforming process and a second methane-rich feed stream is subjected to a steam reforming process, in which a first synthesis gas-containing output stream is formed from the first methane-rich feed stream and a second synthesis gas-containing output stream is formed from the second methane-rich feed stream and these synthesis gas streams are used to form a collective synthesis gas stream and fluid from the collective synthesis gas stream is subjected to a molecular weight-increasing reaction in a synthesis feed stream to obtain a synthesis output stream comprising carbon dioxide and the reaction product(s). At least one carbon dioxide-rich first recycle stream is formed from fluid from the synthesis output stream and fluid from the first recycle stream is subjected to the steam reforming process.

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Glonn, Germany

Thomas Bartesch