Arkema France

Centre National De La Recherche Scientifique

Universitè De Montpellier

Institut National Des Sciences Appliquees De Lyon

Ecole Nationale Superieure De Chimie De Montpellier

Thierry Lannuzel

Fabrice Domingues Dos Santos

Bruno Ameduri

Thibaut Soulestin

Vincent Ladmiral

Ramin Amin-Sanayei

Gilles Hochstetter

Serge Hub

Dominique Garrait

Barbara Ramfel

Philippe Leduc

Emmanuel Guiraud

Pierre-Jean Cottinet

Jeremy Galineau

Lionel Hugon

Jean-Fabien Capsal

Minh-Quyen Le

Thomas Labour

Barbara Wiegert

Jérémy Galineau

Shihai Zhang

A process for preparing a crosslinked fluoropolymer film, including the successive steps of: (1) formulating an ink containing: (a) the product of the reaction of triethylamine with at least one fluorinated copolymer obtained by radical copolymerization of monomers including: (i) vinylidene fluoride (VDF), (ii) trifluoroethylene (TrFE), (iii) at least one chlorinated monomer of formula &#x2014;CXCl&#x2550;CXXwhere X, Xand Xindependently denote H, F or CF, wherein at most one of X, Xand Xdenotes CF; (b) at least one crosslinking agent; (c) at least one photoinitiator; and (d) at least one organic solvent; (2) applying said ink in film form to a substrate; and (3) UV-irradiating said film. Also, the film capable of being obtained according to this process, and also to the uses thereof, in particular in the manufacture of (opto)electronic devices and more particularly in the manufacture of a gate dielectric layer in a field-effect transistor.

Method for preparing a cross-linked fluorinated polymer film

The present invention relates to the use of a fluorinated copolymer in the manufacture of a solid polymer film, to give said film properties of adhesion to a metal surface or to glass. It also relates to a process for improving the adhesion of a fluoropolymer to a metal, polymer or glassy substrate, and also to a composite part comprising a solid polymer film in direct contact with at least one metal or glassy element.

Use of a vinylidene fluoride copolymer for providing a film with properties of adhesion

The invention relates to a fluorinated copolymers which are particularly based on vinylidene fluoride (VDF) or trifluoroethylene (TrFE) and particularly functionalized by functional and/or functionizable vinyl ethers. The invention also relates to methods for producing said copolymers, and to the applications thereof.

Functionalised fluorinated copolymers

The invention relates to a composition comprising at least one electroactive fluorinated terpolymer, and at least one second polymer compatible with the electroactive fluorinated terpolymer and having a glass transition temperature lower than that of the electroactive fluorinated terpolymer. The invention also relates to a method for producing said composition, and to a device such as an actuator comprising a substrate and a film of the above-mentioned composition.

Composition based on electroactive terpolymer

The invention relates to a composition comprising: a homopolymer polyvinylidene fluoride; a copolymer of vinylidene fluoride and of at least one other fluorinated comonomer copolymerizable with vinylidene fluoride (VDF), the weight proportion of the copolymer in the composition being between 10 to 35%; and a plasticizer, the weight proportion of the plasticizer in the composition being between 1 and 5%. The invention also relates to a method for producing the composition and the use thereof for producing various items.

Polyvinylidene fluoride composition

The invention relates to a ferroelectric memory device comprising at least one layer comprising a ferroelectric polymer, and at least two electrodes either side thereof, the ferroelectric polymer being of general formula P(VDF-X-Y), wherein VDF is vinylidene fluoride motifs, X is trifluoroethylene or tetrafluoroethylene motifs, and Y is motifs from a third monomer, the molar proportion of Y motifs in the polymer being less than or equal to 6.5%.

Ferroelectric memory device

The invention relates to a method for preparation of a polymer from monomers comprising polyvinylidene fluoride, trifluoroethylene and a third monomer, the method successively comprising: injection of all the monomers to react into a reactor; initiation of a polymerization of the monomers; a continuation step (a) of the polymerization of the monomers, during which a drop in pressure in the reactor is compensated.

Method for preparation of derivatives of polyvinylidene fluoride

The present invention relates to the preparation of trifluoroethylene (VFor TrFE) by hydrogenolyzis of chlorotrifluoroethylene (CTFE) in the gaseous phase over a group VIII metal catalyst deposited on a support. This method can be used to obtain VFin an economical manner in conditions which minimize the risk of explosion of this molecule. Using a catalyst containing a group VIII metal and, more specifically, containing Pd deposited on a support and a specific series of steps of separation and purification makes it possible to obtain excellent CTFE conversion rates and high selectivity in VFat atmospheric pressure and at low temperatures.

Method for synthesising trifluoroethylene from chlorotrifluoroethylene

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Villeurbanne, France

Thierry Lannuzel