Roquette Freres

Thierry Feron

Boris Breitscheidel

Patrick M Fuertes

Herve Wyart

Jochen Wagner

Hervé Wyart

Arnaud Verraes

Didier Lagneaux

Henri Sautel

Jerome Gimenez

Catherine Baurain

Juliette Brocard

Monique Sobocinski

Rene Saint Loup

René Saint Loup

A method for producing a composition of diesters, includes a step including the esterification of 1,4:3,6-dianhydrohexitol by a composition of carboxylic acids, the composition including: at least an acid having formula C7H15COOH (X) and an acid having formula C9H19COOH (Y), the mass ratio (X)/(Y) varying between 10/90 and 90/10.

Compositions of mixed diesters of 1,4: 3,6-dianhydrohexitol

Disclosed is a composition that can rapidly plasticize polymers, including, in relation to the total mass of (A) and (B): between 0.1 and 99 mass-% of at least one ester of 1,4:3,6-dianhydrohexitol (A), having a molar mass varying between 255 and 345 g&#xb7;moland selected from among monoesters and diesters of isosorbide, isomannide and isoidide; and between 1 and 99.9 mass-% of at least one compound (B) having a molar mass greater than 345 g&#xb7;moland selected from among the esters of 1,4:3,6-dianhydrohexitol, the esters of cyclohexane polycarboxylic acid, the esters of phthalic acid, and glycerol esters. Also disclosed is a method for the production of a plasticized object using constituents (A) and (B), as well as to the use of the ester compound (A) as a polymer gelification accelerator.

Plasticiser compositions comprising gelification accelerators based on ester(s) of 1,4 : 3,6-dianhydrohexitol having low molar weight

Process for preparing a composition based on a synthetic polymer includes: introducing, into a reactor containing a softened or molten synthetic polymer, a non-plasticized starchy component and a plasticizer of the latter; and kneading the mixture obtained under conditions sufficient to obtain the plasticization of the starchy component by the plasticizer, and a homogeneous mixture of the synthetic polymer and of the plasticized starchy component. The reactor may especially be a co-rotating or counter-rotating single-screw or twin-screw extruder, for example a co-rotating twin-screw extruder. The synthetic polymer may advantageously be chosen from the group including polyethylenes (PE) and polypropylenes (PP), which are functionalized or unfunctionalized, polyamides (PA), thermoplastic polyurethanes (TPU), styrene-ethylene-butylene-styrene (SEBS) copolymers, preferably that are functionalized, amorphous polyethylene terephthalates (PETG) and blends thereof. The resulting compositions have improved characteristics, especially in terms of coloration and of mechanical properties, for example in terms of elongation at break.

Process for preparing compositions based on a starchy component and on a synthetic polymer

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Fouquieres les Bethune, France

Thierry Feron