Commissariat &#xc0; L'&#xc9;nergie Atomique Et Aux &#xc9;nergies Alternatives

Centre National De La Recherche Scientifique

Nantes Université

Thibaut Gutel

Jean-Marie Basset

Simon Deleonibus

Gilles Marchand

Catherine Santini

Paul-Henri Haumesser

Lionel Picard

Yvan Reynier

Philippe Poizot

David Peralta

Jean-François Colin

Daniel Tomasi

Yann Kervella

Willy Porcher

Paul Campbell

Lionel Dubois

Laura Boutafa

Adriana Iordache

Florence Masse

Jean-Benoit Denis

Vincent Cadiou

Lorraine Raboin

Mathieu Lions

Jean-Benoît Denis

The present invention relates to a method for using a battery which has an electrode that functions according to a mechanism of complexation of anions and within which the electrode active material is a polyviologen, characterized in that said polyviologen is a material that is insoluble in the electrolyte of said battery and in that the electrochemical conditions for use of said battery are adjusted so that its charge/discharge cycling process is established on the basis of the 1-electron redox reaction between the 1-electron oxidized form of the viologen units of said polyviologen, termed cation radical, and their totally reduced form, termed neutral form of the polyviologen.

Use of a battery with polyviologen active material

The present invention concerns the use, as an active electrode material, of compounds comprising at least one entity of formula (I): in which the phenyl group is substituted with one to four identical or different substituent(s) R, chosen from a hydrogen atom, a halogen atom chosen from fluorine, chlorine, bromine or iodine, a &#x2014;C(&#x2550;S)&#x2014;S&#x2014;C+ group, an &#x2014;O&#x2014;C+ group, an &#x2014;S&#x2014;C+ group, C+ being an alkali cation chosen from Li+, Na+ and K+, a (C1-C12) alkyl radical, a (C2-C12) alkenyl radical, a (C6-C14) aryl or heteroaryl radical; or two vicinal substituents R that can, if appropriate, be linked to each other to together form a 3- to 7-membered ring optionally including another heteroatom chosen from N, O or S; in the base or salt form; and the tautomeric forms of same. It also concerns an electrode material, an electrode and a lithium, sodium or potassium secondary battery, obtained from these compounds.

Material for an electrode of an organic battery comprising benzene-bis(dithioic) acid derivatives

The present invention relates to a polymer possessing a linear backbone selected from the homopolymers belonging to the family of polyfluorenes, polycarbazoles, polyanilines, polyphenylenes, polyisothionaphthenes, polyacetylenes, polyphenylene vinylenes, and copolymers thereof, said backbone bearing at least one side group possessing at least one nitroxide function. It also relates to an electrode material, an electrode and a lithium secondary battery obtained from such a polymer.

Polymer serving as an electrode material for lithium secondary batteries

A method for making electrical interconnections of carbon nanotubes, including a) depositing an ionic liquid including nanoparticles of at least one suspended electrically conducting material, covering at least one surface of an element configured to be used as a support for carbon nanotubes, b) forming a deposit of the nanoparticles at least against the surface of the element, c) removing the remaining ionic liquid, d) growing carbon nanotubes from the deposited nanoparticles, and further including between the c) removing the remaining ionic liquid and the d) growing carbon nanotubes, passivating the deposited nanoparticles not found against the surface of the element.

Method for making electrical interconnections with carbon nanotubes

A method for producing a memory device with nanoparticles, including steps of: a) forming, in a substrate based on at least one semi-conductor, source and drain regions, and at least one first dielectric on at least one zone of the substrate arranged between the source and drain regions and intended to form a channel of the memory device, b) depositing of at least one ionic liquid that is an organic salt or mixture of organic salts in a liquid state, wherein nanoparticles of at least one electrically conductive material are suspended in the ionic liquid, said ionic liquid covering at least said first dielectric, c) forming a deposition of said nanoparticles at least on said first dielectric, d) removing the ionic liquid remaining on the first dielectric, and e) forming at least one second dielectric and at least one control gate on at least one part of the nanoparticles deposited on the first dielectric.

Method for producing a conductive nanoparticle memory device

Growing community of inventors

Veurey-Voroize, France

Thibaut Gutel