Harvard College

Theresa M Kay

Joanna Aizenberg

Elijah Shirman

Tanya Shirman

Katherine Reece Phillips

Ian Burgess

Nicolas Vogel

Calvin Russell

Grant England

Disclosed herein is an inverse photonic structure comprising a first component comprising air holes or colloidal particles; and a metal oxide matrix comprising metal oxide nanocrystals, wherein the metal oxide nanocrystals comprise at least one of: a transition metal, titania, zirconia, alumina, iron oxide, zinc oxide, tin oxide, beryllia, a noble metal oxide, platinum group metal oxides, hafnia, molybdenum oxide, tungsten oxide, rhenium oxide, tantalum oxide, niobium oxide, vanadium oxide, chromium oxide, scandium oxide, yttria, lanthanum oxide, ceria, a rare earth oxide, thorium oxide, uranium oxide, other rare earth oxides, or a combination thereof, wherein the inverse photonics structure is crack-free for at least 10,000 repeat units of the first component.

Formation of high quality titania, alumina and other metal oxide templated materials through coassembly

A co-assembly method for synthesizing inverse photonic structures is described. The method includes combining an onium compound with a sol-gel precursor to form metal oxide (MO) nanocrystals, where each MO nanocrystal has crystalline and amorphous content. The MO nanocrystals are combined with templating particles to form a suspension. A solvent is evaporated from the suspension to form an intermediate or compound product, which then undergoes calcination to produce an inverse structure.

A method of making a multi-layered film includes depositing thin film layers onto a first side of a double-sided transparent substrate. The thin film layers are transparent, and two adjacent layers of said plurality of thin film layers have different refractive indices. One or more absorbers are deposited at an interface formed between two of the thin film layers that are adjacent to one another, or formed by the first side of the substrate and one of the thin film layers. The absorbers absorb selected wavelengths of incident light and reflect part of the incident light after inducing a phase shift. The location of the interface is selected to provide desired wavelengths of absorbed and reflected light. The multi-layered film has a first appearance when viewed from the first side of the substrate and a second appearance when viewed from the second side of the substrate.

Modifying optical properties of thin film structures using an absorbing element

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South Stoney Creek, Canada

Theresa M Kay