Apple Inc.

Crucible Intellectual Property, LLC

Other

Theodore Andrew Waniuk

Christopher D Prest

Joseph C Poole

Joseph W Stevick

Sean Timothy O'Keeffe

Matthew S Scott

Dermot J Stratton

Quoc Tran Pham

Naoto Matsuyuki

Dale N Memering

Kazuya Takagi

Colin M Ely

Jeffrey Lee Mattlin

Michael S Nashner

Michael Deming

Tran Quoc Pham

Stephen Paul Zadesky

Yoshihiko Yokoyama

Douglas Joseph Weber

Matthew S Rogers

Lucy Elizabeth Browning

Michael Kane Pilliod

James A Yurko

Zechariah D Feinberg

Hoishun Li

Choongnyun Paul Kim

Edgar E Vidal

Sungwon Bae

Nicholas W Hutchinson

John Kang

Dennis Ogawa

This application relates to a portable electronic device. The portable electronic device includes an enclosure having a metal oxide coating, the metal oxide coating including a metal alloy substrate that is doped with a dopant, and a metal oxide layer overlaying and formed from the metal alloy substrate so that the metal oxide layer includes the dopant.

Doped metal oxide coating having increased color durability

A multilayer composite is provided. The composite may include a plurality of metallic glass layers interleaved with a plurality of polymer layers. The composite may have a thickness of up to 100 microns. The composite may have a fatigue strength of at least 1.5 times of the fatigue strength of a monolithic metallic glass having the same thickness as the composite and the same chemical composition as the metallic glass layer.

Multilayer composite including metallic glass and polymer with reduced fatigue

A method of manufacturing a housing of an electronic device includes applying a mask to a portion of a ceramic green body to define a masked portion and an unmasked portion, applying a pigment to the ceramic green body to color the unmasked portion, and sintering the ceramic green body to remove the mask and form a ceramic housing. The ceramic housing may comprise a first portion corresponding to the masked portion and having a first color, and a second portion corresponding to the unmasked portion and having a second color different from the first color.

Multi-colored ceramic housings for an electronic device

A housing for a portable electronic device is disclosed. The housing is composed of yttria-sensitized zirconia. Yttria-sensitized zirconia has from about 1.5 to about 2.5 mole percent yttria, and more typically about 2 mole percent yttria, and most typically 2 mole percent yttria, in zirconia. Yttria-sensitized zirconia is both tough and able to limit the formation and propagation of micro-cracks. Methods for manufacturing yttria-sensitized zirconia composed housings are also disclosed.

Yttria-sensitized zirconia

A method of manufacturing a housing of an electronic device includes determining a sintering profile configured to produce a selected color at a selected depth within a wall of the housing, sintering a ceramic housing precursor in accordance with the determined sintering profile, thereby forming the housing, and removing material from the housing up to the selected depth.

Ceramic sintering for uniform color for a housing of an electronic device

Methods of forming a bulk metallic glass disclosed. The methods include packing a metallic glass-forming alloy powder to form a green body; heating the green body to a temperature between the glass transition temperature and the melting point of the metallic glass-forming alloy to form a heated green body; and cooling the heated green body to a temperature below the glass transition temperature of the metallic glass-forming alloy to form the bulk metallic glass. The methods of forming a bulk metallic glass also include packing one or more layers of an amorphous foil to form a green body; heating the green body to a temperature between the glass transition temperature and the melting point of the metallic glass-forming alloy to form a heated green body; and cooling the heated green body to a temperature below the glass transition temperature of the metallic glass-forming alloy to form the bulk metallic glass.

Methods of making bulk metallic glass from powder and foils

Embodiments herein relate to a heat sink having nano- and/or micro-replication directly embossed in a bulk solidifying amorphous alloy comprising a metal alloy, wherein the heat sink is configured to transfer heat out of the heat sink by natural convection by air or forced convection by air, or by fluid phase change of a fluid and/or liquid cooling by a liquid. Other embodiments relate apparatus having the heat sink. Yet other embodiments relate to methods of manufacturing the heat sink and apparatus having the heat sink.

Bulk amorphous alloy heat sink

The disclosure is directed to Zr and Hf bearing alloys that are capable of forming a metallic glass, and more particularly metallic glass rods with diameters at least 1 mm and as large as 5 mm or larger. The disclosure is further directed to Zr and Hf bearing alloys that demonstrate a favorable combination of glass forming ability, strength, toughness, bending ductility, and/or corrosion resistance.

Zirconium (Zr) and Hafnium (Hf) based BMG alloys

Described herein is a feedstock comprising BMG. The feedstock has a surface with an average roughness of at least 200 microns. Also described herein is a feedstock comprising BMG. The feedstock, when supported on a support during a melting process of the feedstock, has a contact area between the feedstock and the support up to 50% of a total area of the support. These feedstocks can be made by molding ingots of BMG into a mole with surface patterns, enclosing one or more cores into a sheath with a roughened surface, chemical etching, laser ablating, machining, grinding, sandblasting, or shot peening. The feedstocks can be used as starting materials in an injection molding process.

Manipulating surface topology of BMG feedstock

Radiation shielding structures comprising bulk-solidifying amorphous alloys and methods of making radiation shielding structures and components in near-to-net shaped forms are provided.

Radiation shielding structures

Various embodiments provide apparatus and methods for melting materials and for containing the molten materials within melt zone during melting. Exemplary apparatus may include a vessel configured to receive a material for melting therein; a load induction coil positioned adjacent to the vessel to melt the material therein; and a containment induction coil positioned in line with the load induction coil. The material in the vessel can be heated by operating the load induction coil at a first RF frequency to form a molten material. The containment induction coil can be operated at a second RF frequency to contain the molten material within the load induction coil. Once the desired temperature is achieved and maintained for the molten material, operation of the containment induction coil can be stopped and the molten material can be ejected from the vessel into a mold through an ejection path.

Inline melt control via RF power

Described herein are methods of constructing a part having improved properties using metallic glass alloys, layer by layer. In accordance with certain aspects, a layer of metallic glass-forming powder is deposited to selected positions and then fused to a surface layer (i.e. layer below) by suitable methods such as laser heating or electron beam heating. The deposition and fusing are then repeated as need to construct the part, layer by layer. In certain embodiments, one or more sections or layers of non-metallic glass-forming material can be included as needed to form a composite final part. In certain aspects, the metallic glass-forming powder may be crystalized during depositing and fusing, or may be recrystallized during subsequent processing to provide selectively crystalized sections or layers, e.g., to impart desired functionality. In other aspects, non-metallic glass-forming materials may be deposited and fused at selected positions, e.g., to provide selective shear banding to impart improved ductile properties and plasticity. In yet other aspects, the metallic glass-forming powder or metallic glass material and non-metallic glass-forming material are deposited and fused to form a foam-like, bellow or similar structure, which is able to crumple under high stress to absorb energy under impact.

Methods for constructing parts with improved properties using metallic glass alloys

Embodiments relates to a hook side fastener having hooks and a loop side fastener having loops. The hooks and/or loops are made of bulk solidifying amorphous metal alloy. Other embodiments relate to methods of making and using the hook side and loop side fasteners.

Growing community of inventors

Lake Forest, CA, United States of America

Theodore Andrew Waniuk