E.i. Dupont De Nemours and Company

Theodor Arthur Liss

Edward James Greenwood

Kimberly Gheysen Raiford

Jack R Kirchner

Leonard H Beck

Fluorinated diester melt additives for thermoplastic polymers

Fluorinated imides useful for imparting repellency of low surface tension fluids to thermoplastic polymers of formulae ##STR1## wherein R.sub.1 is F(CF.sub.2).sub.x --(CH.sub.2).sub.m, or F(CF.sub.2).sub.x SO.sub.2 N(R.sub.5) (CH.sub.2)p wherein x is from about 4 to about 20, m is from about 2 to about 6, p is from 1 to about 12, and R.sub.5 is an alkyl radical of from 1 to about 4 carbons;

Fluorinated melt additives for thermoplastic polymers

A composition having repellency to low surface tension fluids comprising a material prepared by forming a mixture of a polymer selected from the group consisting of polyolefin, polyamide, polyester, polyacrylate, and blends and copolymers thereof, and a fluorochemical compound comprising a fluorocarbon/hydrocarbon ester of the formulae:

Fluorinated ester melt additives for thermoplastic fibers

Fluorinated diesters useful for imparting repellency of low surface tension fluids to thermoplastic polymers of formulae

Fluorinated melt ester additives for thermoplastic fibers

Fluorinated imides useful for imparting repellency of low surface tension fluids to thermoplastic polymers of formulae ##STR1## wherein R.sub.1 is F(CF.sub.2).sub.x --(CH.sub.2).sub.m, or F(CF.sub.2).sub.x SO.sub.2 N(R.sub.5)(CH.sub.2)p wherein x is from about 4 to about 20, m is from about 2 to about 6, p is from 1 to about 12, and R.sub.5 is an alkyl radical of from 1 to about 4 carbons;

Fluorinated imides useful for imparting repellency of low surface tension fluids to thermoplastic polymers of formulae ##STR1## wherein R.sub.1 is F(CF.sub.2).sub.x --(CH.sub.2).sub.m, or F(CF.sub.2).sub.x SO.sub.2 N(R.sub.5) (CH.sub.2) .sub.p wherein x is from about 4 to about 20, m is from about 2 to about 6, p is from 1 to about 12, and R.sub.5 is an alkyl radical of from 1 to about 4 carbons;

Synthetic polyamide textile substrate having deposited thereon a modified polymeric sulfonated phenol-formaldehyde condensation product comprising one (a) in which 10 to 25% of the polymer units contain SO.sub.3 (-) radicals and about 90 to 75% of the polymer units contain sulfone radicals and (b) in which a portion of the free hydroxyl groups thereof has been acylated or etherified, the number of said hydroxyl groups which has been acylated or etherified being sufficient to inhibit yellowing of said condensation product but insufficient to reduce materially the capacity of said condensation product to impart stain resistance to said synthetic polyamide textile substrate.

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Wilmington, DE, United States of America

Theodor Arthur Liss